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Method for preparing printing ink thickener

A technology of thickener and ink, applied in the field of preparation of liquid ink thickener, can solve the problems such as the influence of the ink particles on the ink performance, the pollution of the environment by alcohol organics, and the excessive thickening, and achieve good stability, water resistance, The effect of avoiding color change and simple preparation method

Active Publication Date: 2014-12-03
浙江省中明化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing thickener needs to be pre-diluted with a solvent during use, and it cannot be carried out at high temperature. It is necessary to lower the system temperature below 150°C and add the thickener to disperse evenly, and then raise the temperature to above 170°C, otherwise Adding it directly at 170°C will cause excessive local thickening, and the crazy line particles will affect the performance of the ink
The production is time-consuming and wastes energy. In addition, the alcoholic organic compounds produced during the thickening reaction will pollute the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Add 204g of aluminum isopropoxide and 65g of mineral oil weighed into a 1000ml four-necked flask with a condensing device, stir, heat up to 80°C, and drop 144g of 2-ethylhexanoic acid to carry out the displacement reaction. The reaction time is 1h, after the replacement reaction, heat up to 140°C for another 1h, add dropwise 150g of isopropanol with a water content of 12% to carry out the hydrolysis reaction, the hydrolysis reaction time is 5h, then add 65g of mineral oil to quickly cool down to 60°C, and filter 316 g of a clear light yellow oily liquid with an aluminum content of 8.5% was obtained.

[0017] Mix and stir resin, linseed oil, and kerosene in a ratio of 2:1:2 by weight and raise the temperature to 210°C, keep it warm for 15 minutes, and then naturally cool to 25°C to obtain resin oil with a viscosity of 35Pa.s. Take 100g of resin oil, heat up to 170°C, add 1.48 g of thickener prepared above, stir and disperse evenly, heat up to 175°C, keep it warm for 30 m...

Embodiment 2

[0019] Add 102g of measured aluminum isopropoxide and 50g of mineral oil into a 1000ml four-necked flask with a condenser, stir, heat up to 95°C, add 72g of 2-ethylhexanoic acid dropwise for displacement reaction, and the reaction time is 1h After the replacement reaction, heat up to 190°C, add 14.2g of crystalline aluminum sulfate with a water content of 45.7%, and perform a hydrolysis reaction. The hydrolysis reaction time is 3 hours, and then add 25g of mineral oil to quickly cool down to 60°C, and filter to obtain aluminum 165g of a clear light yellow oily liquid with a content of 8.18%.

[0020] Add 1.54g of the thickener prepared above to 100g of the resin oil prepared in "Example 1", raise the temperature to 170°C, stir and disperse evenly, then raise the temperature to 175°C, keep it warm for 30 minutes, and naturally cool down to 25°C , Test its viscosity, resin oil viscosity increased to 136Pa.s.

Embodiment 3

[0022] Add 204g of aluminum isopropoxide and 50g of 2-ethylhexanoic acid-1-methylethyl ester into a 1000ml four-necked flask with a condenser, stir, heat up to 85°C, and dropwise add 144g of 2-ethylhexanoate Carry out the replacement reaction of hexylhexanoic acid, the reaction time is 1.5h, after the replacement reaction is completed, heat up to 190°C, add 28g of crystalline aluminum sulfate with a water content of 45.7%, carry out the hydrolysis reaction for 4 hours, and add 2-ethylhexyl Acid-1-methyl ethyl ester 101g, cooled to 60°C and filtered to obtain 336 g of a clear light yellow oily liquid with an aluminum content of 8.03%.

[0023] Add 1.58 g of the above-prepared gel to 100 g of the resin oil prepared in "Example 1", raise the temperature to 175°C, stir and disperse evenly, keep warm for 30 minutes, then cool down naturally to 25°C, and test its viscosity , the resin oil viscosity increased to 121Pa.s.

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Abstract

The invention discloses a method for preparing a printing ink thickener. The method comprises the following steps of: dissolving aluminum isopropoxide into an organic solvent, stirring and heating to 80-130 DEG C, dropwise adding an organic acid to the heated solution of aluminum isopropoxide and the organic solvent; heating to 140-190 DEG C, adding water to carry out hydrolysis reaction after heating for a period of time; at the end of the hydrolysis reaction, adding the organic solvent for aging and cooling, and filtering; and adding water to remove insoluble substances in the reaction system to obtain the organic solution with certain aluminum content. The preparation method of the printing ink thickener does not need pre-diluting; the materials are added at a high temperature; the prepared product does not generate organic matters such as alcohols in the using process; the preparation method is simple; and the thickening effect is significant.

Description

technical field [0001] The invention relates to the technical field of ink thickener preparation, in particular to a preparation method of a liquid ink thickener. Background technique [0002] Thickeners are very important additives in the production of offset printing inks, and are the key components of ink-making binders. By changing the viscosity of the binders, the rheology of the ink can be improved, thereby improving the ability of the ink to adapt to high-speed printing. At present, the thickener used in offset printing ink is generally an organoaluminum compound, which is added during the preparation of the binder, and cross-links with the hydroxyl group or carboxyl group in the resin and vegetable oil at a certain temperature to increase the viscosity. However, the existing thickener needs to be pre-diluted with a solvent during use, and it cannot be carried out at high temperature. It is necessary to lower the system temperature below 150°C and add the thickener to...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/03C07F5/06
Inventor 李齐春吴祖桑翁齐菲戴品中周若尘
Owner 浙江省中明化工科技有限公司