Method for treating high-iron red mud with high-temperature iron bath

A high-iron red mud and iron bath technology, applied in the field of metallurgical comprehensive utilization, can solve the problems of many process steps, low recovery rate, complicated process operation, etc., and achieve the effect of short process flow and lightening the environment

Active Publication Date: 2015-05-06
ANGANG STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Most of the current high iron red mud treatment methods need to add special devices or equipment, and there are many steps in the process, which complicates the process operation; or strict control conditions, high energy consumption, and low recovery rate lead to increased costs, making it difficult to achieve large-scale industrial production. application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The chemical composition of high-iron red mud is mainly: Fe 2 o 3 65.2 wt%, Al 2 o 3 8.1 wt%, Na 2 O is 2.4 wt%, the rest is SiO 2 , CaO and other impurities. The fixed carbon content of coal powder is 72.1 wt%, and the sulfur content is 0.8 wt%; the CaF of fluorite powder 2 The content is 85.9 wt%.

[0024] Use a mixer to mix high-iron red mud, coal powder, and fluorite powder evenly in proportion. The proportion of fluorite powder is 5.0 wt%, and the rest is high-iron red mud and coal powder. The fixed carbon content in coal powder is the same as that of high-iron red The molar ratio of the total oxygen content of iron oxides and sodium oxides in the mud is C / O=1.1. Then use a briquetting machine to make 20-40mm red mud lumps, and dry them for later use.

[0025] During the tapping process of the blast furnace, the dry red mud agglomerates are continuously and uniformly added into the molten iron ditch by using the chute, and the addition amount is 50kg / t. Th...

Embodiment 2

[0033] The chemical composition of high-iron red mud is mainly: Fe 2 o 3 51.5 wt%, Al 2 o 3 18.0 wt%, Na 2 O is 8.2 wt%, the rest is SiO 2 , CaO and other impurities; the fixed carbon content of coal powder is 71.6 wt%, and the sulfur content is 0.8 wt%; the CaF content of fluorite powder 2 The content is 90.2 wt%.

[0034] Use a mixer to mix the high-speed iron red mud, coal powder, and fluorite powder in proportion and stir evenly, then use a pelletizer to make 5-10mm red mud pellets, and dry them for later use. Among them, the proportion of fluorite powder is 6.5 wt%, and the rest is high-iron red mud and coal powder. The molar ratio of the fixed carbon content in coal powder to the total oxygen content of iron oxides and sodium oxides in high-iron red mud is C / O= 1.2.

[0035] Add 10t of red mud pellets in advance to the torpedo can (230t of molten iron) after the iron has been folded, and fill it with molten iron when the blast furnace is tapping. Under this condi...

Embodiment 3

[0038] The chemical composition of high-iron red mud is mainly: Fe 2 o 3 36.5 wt%, Al 2 o 3 is 25.5 wt%, Na 2 O is 9.3 wt%, the rest is SiO 2 , CaO and other impurities; the fixed carbon content of coke powder is 82.4 wt%, and the sulfur content is 0.6 wt%; the CaF content of fluorite powder 2 The content is 95.7 wt%.

[0039]Use a mixer to mix high-speed iron red mud, coke powder, and fluorite powder in proportion and stir evenly, then use a ball press machine to make 10-30mm red mud lumps, and dry them for later use. Among them, the proportion of fluorite powder is 9.5 wt%, and the rest is high-iron red mud and coke powder. The molar ratio of the fixed carbon content in coke powder to the total oxygen content of iron oxide and sodium oxide in high-iron red mud is C / O= 1.4.

[0040] The red mud agglomerate is added from the swing nozzle, and the added amount is 40kg / t. The red mud agglomerate falls into the molten iron tank together with the molten iron flow, and othe...

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Abstract

The invention provides a method for treating high-iron red mud with a high-temperature iron bath. The method comprises the following steps of mixing high-iron red mud, a carbon-containing raw material and an additive uniformly according to 4-10wt% of additive and a mole ratio of the content of fixed carbon in the carbon-containing raw material to the total content of oxygen elements in iron oxide and sodium oxide in the used high-iron red mud being C / O=1.1-1.4 to prepare red mud agglomerates; during blast-furnace tapping, adding the red mud agglomerates to molten iron according to the addition not more than 50kg / t and carrying out quick smelting reduction on metals in the red mud by utilizing the high-temperature iron bath environment and the impact and stirring actions of the molten iron, wherein iron is smelted in the high-temperature molten iron after reduction to be supplied for steelmaking; the alkali metals are discharged along with smoke after reduction; aluminium oxide and impurities are smelted in furnace slag and float on the surface of the molten iron. The method is simple, convenient and practicable, dispenses with adding special devices or equipment, can be used for efficiently separating iron, aluminium and alkali metals in the red mud, ensures that the iron recovery rate is more than 90%, not only achieves large-scale comprehensive utilization of the high-iron red mud but also reduces the environmental and safety problems caused by the red mud and obtains the double effects of energy conservation and emission reduction.

Description

technical field [0001] The invention belongs to the field of metallurgical comprehensive utilization, and in particular relates to a method for treating high-iron red mud by using a high-temperature iron bath. Background technique [0002] Red mud is the solid waste discharged during the alumina production process in the alumina plant. Generally, 0.8-1.8 tons of red mud is produced for every 1 ton of alumina produced. More than 100 million tons, not only occupy a large amount of land, but also cause environmental pollution and safety hazards. Red mud contains more valuable elements such as iron and aluminum, especially the red mud that is discharged after the Bayer method is used to produce alumina generally has a high iron content (Fe 2 o 3 content of 30% to 70%), so the recycling value of this kind of high-iron red mud is extremely high. The first choice is to recycle the iron in it. Effective treatment of high-iron red mud can not only reduce the pressure on environment...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21B13/00C22B1/245
CPCY02P10/20
Inventor 张伟王再义张立国任伟李金莲王相力邓伟韩子文王亮
Owner ANGANG STEEL CO LTD
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