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Method for simultaneously dephosphorizing and extracting vanadium through converter

A converter and dephosphorization agent technology, applied in the manufacture of converters, etc., can solve problems such as poor preparation, low vanadium extraction rate, complex composition, etc., and achieve simple operation, high vanadium extraction rate, and environmental friendliness

Inactive Publication Date: 2014-01-29
PANGANG GROUP RESEARCH INSTITUTE CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a method for simultaneous dephosphorization and vanadium extraction in a converter in order to overcome the above-mentioned problems of low vanadium extraction rate, complex composition and poor preparation. The method has high vanadium extraction rate, high dephosphorization rate, and simple operation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] This example is used to illustrate the method for simultaneously dephosphorizing and extracting vanadium in a converter provided by the present invention.

[0041]120 tons of vanadium extracting converter, 140t of vanadium-containing molten iron in the molten iron tank, containing 4.5 wt% of C, 0.3 wt% of Mn, 0.09 wt% of P, 0.16 wt% of Si, and 0.3 wt% of V , 0.2% by weight of Ti, and the rest is Fe. The temperature of vanadium-containing molten iron entering the furnace is 1300°C. Oxygen is blown into the converter through an oxygen lance for blowing, the total amount of oxygen blowing is 11.43 standard cubic meters / t of vanadium-containing molten iron, and the blowing time is 6 minutes, (the flow rate of oxygen is 16,000 standard cubic meters / hour). Add lime (CaO content: 92% by weight, loss on ignition: 8% by weight, particle size: 40mm) when blowing for 0.5min, and the amount added is 12.5kg / t of vanadium-containing molten iron. Add pig iron (containing 4.52% by we...

Embodiment 2

[0043] This example is used to illustrate the method for simultaneously dephosphorizing and extracting vanadium in a converter provided by the present invention.

[0044] 120 tons of vanadium-extracting converter, the molten iron tank is filled with 145t of vanadium-containing molten iron, which contains 4.7% by weight of C, 0.5% by weight of Mn, 0.1% by weight of P, 1.0% by weight of Si, and 0.4% by weight of V , 0.2% by weight of Ti, and the rest is Fe. The temperature of vanadium-containing molten iron entering the furnace is 1285°C. Oxygen is blown into the converter through an oxygen lance for blowing. The total amount of oxygen blowing is 8.02 standard cubic meters / t of vanadium-containing molten iron, and the blowing time is 4.5 minutes (the flow rate of oxygen is 15,500 standard cubic meters / hour). After the vanadium-containing molten iron is put into the furnace, lime is added (the CaO content is 95% by weight, the burning loss is 5% by weight, and the particle size ...

Embodiment 3

[0046] This example is used to illustrate the method for simultaneously dephosphorizing and extracting vanadium in a converter provided by the present invention.

[0047] 120 tons of vanadium extracting converter, 138t of vanadium-containing molten iron in the molten iron tank, containing 4.25% by weight of C, 0.21% by weight of Mn, 0.07% by weight of P, 0.21% by weight of Si, and 0.25% by weight of V , 0.25% by weight of Ti, and the rest is Fe. The temperature of vanadium-containing molten iron entering the furnace is 1350°C. Oxygen is blown into the converter through an oxygen lance for blowing. The total amount of oxygen blowing is 13.95 standard cubic meters / t of vanadium-containing molten iron, and the blowing time is 7 minutes (the flow rate of oxygen is 16,500 standard cubic meters / hour). Add lime (CaO content: 90% by weight, loss on ignition: 10% by weight, particle size: 48mm) when blowing for 1 minute, and the amount added is 10.71kg / t of vanadium-containing molten ...

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Abstract

The invention discloses a method for simultaneously dephosphorizing and extracting vanadium through a converter. The method comprises the step of adding vanadium-containing molten iron into the converter to carry out converter vanadium extraction. The method is characterized in that a dephosphorizing agent is added in the vanadium-containing molten iron in the converter vanadium extraction process, and the heating speed of the vanadium-containing molten iron is controlled at 10-20 DEG C / min in the converter vanadium extraction process, wherein the dephosphorizing agent is lime. The method for simultaneously dephosphorizing and extracting vanadium through the converter, disclosed by the invention, is high in vanadium extraction efficiency and dephosphorizing efficiency, simple in operation and friendly to the environment and can be widely applied to industrial production.

Description

technical field [0001] The invention relates to the field of vanadium extraction in a converter, in particular to a method for simultaneous dephosphorization and vanadium extraction in a converter. Background technique [0002] Phosphorus is a harmful element in most steel grades. In recent years, with the rapid development of science and technology, low-temperature steel, marine steel, hydrogen-induced cracking-resistant steel and steel for some thick plates must not only have extremely low sulfur content, but also require the P content in the steel to be less than 0.01% by weight. Or P content<0.005% by weight. [0003] Since 1980, various treatment methods have been developed for the pre-dephosphorization of molten iron. The dephosphorization pretreatment of molten iron is carried out in-house, and both methods have been applied industrially. Dephosphorization of ladles or torpedo tanks mainly has problems such as large temperature drop, severe splashing during oxyg...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/28C21C5/36
Inventor 陈永梁新腾曾建华戈文荪李桂军杨森祥黄正华张龙超杨晓东何为
Owner PANGANG GROUP RESEARCH INSTITUTE CO LTD