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Silicon-based desulfurization slag-adjusting agent for vanadium and titanium containing molten iron and preparation method and desulfurization slag-adjusting method thereof

A technology of slagging agent and molten iron, which is applied in the field of silicon-based desulfurization slag adjusting agent for vanadium-titanium molten iron and its preparation, can solve the problems that it is difficult to apply vanadium-titanium molten iron, and achieve reduction of slagging iron loss and reduction of sulfur return Effect

Active Publication Date: 2015-07-08
PANGANG GROUP RESEARCH INSTITUTE CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the above-mentioned slagging agents are difficult to apply to molten iron containing vanadium and titanium

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0013] According to one aspect of the present invention, the preparation method of silicon-based desulfurization and slagging agent for vanadium-titanium-containing molten iron comprises the following steps: 60-80 parts by weight of quartz sand, 2-8 parts of fluorite, and 5-10 parts of soda ash and 10-20 parts of alumina (for example, aluminum ash) are ground into powder, and mixed evenly to obtain a silicon-based desulfurization and slagging agent for vanadium-titanium molten iron. That is to say, the silicon-based desulfurization and slagging agent for vanadium-titanium molten iron can be composed of 60-80 parts by weight of quartz sand powder, 2-8 parts of fluorite powder, 5-10 parts of soda ash powder and 10-20 parts of oxidized Aluminum powder is evenly mixed. The preferred ratio can be 65-75 parts of quartz sand powder, 4-6 parts of fluorite powder, 6-9 parts of soda ash powder and 12-17 parts of alumina powder. In addition, the particle size of quartz sand powder, fluo...

example 1

[0024] Grind 68 parts of quartz sand, 6 parts of fluorite, 8 parts of soda ash and 18 parts of aluminum ash by weight into fine powder, mix well, and control the particle size to ≤3mm. The obtained silicon-based desulfurization and slagging agent composition is: S0.09%, P0.09%, SiO 2 66.91%, CaF 2 5.6%, Na 2 CO 3 7.24%, CaO2.8%, Al 2 o 3 17.27%.

[0025] Smelting vanadium-titanium-iron concentrate in a blast furnace yields vanadium-titanium-containing molten iron, in which the S content is 0.092% and the temperature is 1305°C. After the molten iron enters the desulfurization station, it first sprays passivated magnesium powder for desulfurization, and the treatment time is 25 minutes. After the desulfurization is completed, 2.8kg / tFe of the above-mentioned silicon-based desulfurization slagging agent is added to the vanadium-containing iron water for slag adjustment. After stirring with a slag rake for 20 seconds, the slag removal operation is carried out, and the amoun...

example 2

[0028] Grind 75 parts of quartz sand, 5 parts of fluorite, 5 parts of soda ash and 15 parts of aluminum ash into fine powder, mix well, and control the particle size to ≤3mm. The obtained silicon-based desulfurization and slagging agent composition is: S0.04%, P0.06%, SiO 2 74%, CaF 2 5.2%, Na 2 CO 3 4.7%, CaO2.6%, Al 2 o 3 13.4%.

[0029] Smelting vanadium-titanium-iron concentrate in a blast furnace yields vanadium-titanium-containing molten iron, in which the S content is 0.095% and the temperature is 1310°C. After the molten iron enters the desulfurization station, it first sprays passivated magnesium powder for desulfurization, and the treatment time is 25 minutes. After the desulfurization is completed, add 3.2kg / tFe of the above-mentioned silicon-based desulfurization slagging agent to the vanadium-containing iron water for slag adjustment. After stirring with a slag rake for 20 seconds, the slag removal operation is carried out, and the amount of slag removal is...

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Abstract

The invention provides a silicon-based desulfurization slag-adjusting agent for vanadium and titanium containing molten iron and a preparation method and a desulfurization slag-adjusting method thereof. The preparation method comprises the following step of: uniformly mixing 60-80 parts by weight of quartz sand powder, 2-8 parts by weight of fluorite powder, 5-10 parts by weight of soda ash and 10-20 parts by weight of alumina powder to obtain the silicon-based desulfurization slag-adjusting agent. The silicon-based desulfurization slag-adjusting agent comprises the following components in percentage by weight: less than or equal to 0.10% of S, less than or equal to 0.10% of P, 60%-80% of SiO2, 1.5%-6% of CaF2, 5%-9% of Na2CO3, 0%-3% of CaO and 8%-18% of Al2O3. The desulfurization slag-adjusting method comprises the following steps of: adding the silicon-based desulfurization slag-adjusting agent to the vanadium and titanium containing molten iron; carrying out slag adjustment and desulfurization on the vanadium and titanium containing molten iron. The silicon-based desulfurization slag-adjusting agent provided by the invention can reduce the resulfurization amount after the molten iron is desulfurized and reduce the deslagging iron loss.

Description

technical field [0001] The invention relates to the technical field of molten iron desulfurization, more specifically, to a silicon-based desulfurization and slagging agent for molten iron containing vanadium and titanium and a preparation method thereof, and a method for applying the silicon-based desulfurization and slagging agent to the molten iron containing vanadium and titanium. The method of desulfurization and slag adjustment. Background technique [0002] Generally, for iron and steel enterprises using vanadium-containing ilmenite as raw materials, vanadium-containing ilmenite (for example, vanadium-titanium magnetite) will produce vanadium-titanium-containing molten iron after blast furnace ironmaking. When desulfurizing molten iron containing vanadium and titanium, there will be the following situations: because the blast furnace slag carried by the molten iron containing vanadium and titanium is blast furnace slag containing vanadium and titanium, the blast furna...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C1/02
Inventor 蒋龙奎戈文荪陈永杜丽华陈炼王建黄正华董克平施敏张家利
Owner PANGANG GROUP RESEARCH INSTITUTE CO LTD