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Desulfurization and slag adjustment agent for vanadium-containing titanium molten iron, its preparation method and desulfurization and slag adjustment method

A technology of slag adjusting agent and vanadium-titanium iron, which is applied in the field of hot metal desulfurization, can solve the problems that it is difficult to apply vanadium-titanium-containing hot metal, etc., and achieve the effects of reducing iron loss during slag removal, improving desulfurization efficiency, and reducing the amount of sulfur returned

Active Publication Date: 2015-08-26
PANGANG GROUP RESEARCH INSTITUTE CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the above-mentioned slagging agents are difficult to apply to molten iron containing vanadium and titanium

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0013] According to one aspect of the present invention, the preparation method of vanadium-titanium-containing molten iron with desulfurization and slagging agent comprises the following steps: 30 to 40 parts by weight of quartz sand, 5 to 10 parts of fluorite, 5 to 10 parts of soda ash, 30 parts by weight -40 parts of active lime and 10-20 parts of alumina (for example, aluminum ash, alumina powder, etc.) are ground into powder and mixed uniformly to obtain a desulfurization and slagging agent for vanadium-titanium molten iron. That is to say, the desulfurization and slagging agent for vanadium-titanium molten iron can be composed of 30-40 parts by weight of quartz sand powder, 5-10 parts of fluorite powder, 5-10 parts of soda ash powder, and 30-40 parts of active lime powder. It is evenly mixed with 10-20 parts of alumina powder. The preferred ratio can be 32-38 parts of quartz sand powder, 6-9 parts of fluorite powder, 6-9 parts of soda ash powder, 32-38 parts of active li...

example 1

[0023] Grind 38 parts of quartz sand, 6 parts of fluorite, 8 parts of soda ash, 32 parts of active lime and 16 parts of alumina powder by weight into fine powder, mix evenly, and control the particle size to ≤3mm. The composition of the obtained desulfurization and slagging agent is: S0.04%, P0.06%, SiO 2 37.6%, CaF 2 5.5%, Na 2 CO 3 8%, CaO31%, Al 2 o 3 17.8%.

[0024] Smelting vanadium-titanium-iron concentrate in a blast furnace yields vanadium-titanium-containing molten iron, in which the S content is 0.083% and the temperature is 1316°C. After the molten iron enters the desulfurization station, first add 3.5kg / tFe of the above-mentioned desulfurization and slagging agent to the vanadium-containing molten iron, stir with a slag rake for 20 seconds, and then spray passivated magnesium powder for desulfurization. The treatment time is 20 minutes. After the desulfurization is completed, the slag removal operation is carried out, and the amount of slag removal is 41kg / tF...

example 2

[0027] Grind 35 parts of quartz sand, 9 parts of fluorite, 6 parts of soda ash, 35 parts of active lime and 15 parts of aluminum ash by weight into fine powder, mix evenly, and control the particle size to ≤3mm. The composition of the obtained desulfurization and slagging agent is: S0.05%, P0.05%, SiO 2 34.8%, CaF 2 8.4%, Na 2 CO 3 5.5%, CaO34%, Al 2 o 3 17.2%.

[0028] Smelting vanadium-titanium-iron concentrate in a blast furnace yields vanadium-titanium-containing molten iron, in which the S content is 0.095% and the temperature is 1308°C. After the molten iron enters the desulfurization station, first add 4.5kg / tFe of the above-mentioned desulfurization and slagging agent to the vanadium-containing molten iron, stir with a slag rake for 20 seconds, and then spray passivated magnesium powder for desulfurization. The treatment time is 24 minutes. After the desulfurization is completed, the slag removal operation is carried out, and the amount of slag removal is 43kg / tF...

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Abstract

The invention provides a desulphurization slag modifier for molten iron containing vanadium and titanium, a preparation method of the desulphurization slag modifier and a desulphurization slag modifying method. The preparation method comprises the step of uniformly mixing 30-40 parts of quartz sand powder, 5-10 parts of fluorite powder, 5-10 parts of soda powder, 30-40 parts of active lime powder and 10-20 parts of aluminum oxide powder by weight to obtain the desulphurization slag modifier. The desulphurization slag modifier comprises the following components in percentage by weight: not more than 0.080% of S, not more than 0.080% of P, 30-40% of SiO2, 4-8% of CaF2, 4-9% of Na2CO3, 30-40% of CaO and 8-16% of Al2O3. The desulphurization slag modifying method comprises the following steps: adding the desulphurization slag modifier into the molten iron containing vanadium and titanium and performing desulphurization slag modification on the molten iron containing vanadium and titanium. The desulphurization slag modifier disclosed by the invention has the beneficial effects that the desulphurization efficiency of the molten iron containing vanadium and titanium can be improved, the sulfur return quantity after desulphurization of the molten iron can be reduced, and the slagging iron loss can be reduced.

Description

technical field [0001] The invention relates to the technical field of molten iron desulfurization, more specifically, to a desulfurization and slag adjustment agent for vanadium-titanium molten iron and a preparation method thereof, and a method for applying the desulfurization and slag adjustment agent to desulfurize and slag-adjust the vanadium-titanium molten iron method. Background technique [0002] Generally, for iron and steel enterprises using vanadium-containing ilmenite as raw materials, vanadium-containing ilmenite (for example, vanadium-titanium magnetite) will produce vanadium-titanium-containing molten iron after blast furnace ironmaking. When desulfurizing molten iron containing vanadium and titanium, there will be the following situations: because the blast furnace slag carried by the molten iron containing vanadium and titanium is blast furnace slag containing vanadium and titanium, the blast furnace slag has a high melting point and poor fluidity, resultin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/064C21C1/02
Inventor 蒋龙奎戈文荪陈永杜丽华陈炼王建黄正华董克平施敏张家利
Owner PANGANG GROUP RESEARCH INSTITUTE CO LTD