Catalyst regeneration method capable of reducing carbon dioxide discharge and improving selectivity

A carbon dioxide and catalyst technology, which is applied in the field of regeneration of carbon-containing catalysts, can solve problems such as high coke and dry gas yields, and achieve the effects of reducing coke and dry gas yields, reducing investment, and improving use efficiency.

Active Publication Date: 2014-04-16
CHINA PETROLEUM & CHEM CORP +1
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  • Claims
  • Application Information

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Problems solved by technology

For example, the highest activity recovery of the regenerated catalyst can be achieved during regeneration, but when the regenerated catalyst participates in the reaction, it may cause high coke and dry gas yields due to its high activity, which is undesirable

Method used

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  • Catalyst regeneration method capable of reducing carbon dioxide discharge and improving selectivity

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Embodiment

[0036] The embodiment is carried out on a catalytic cracking demonstration unit, as shown in the accompanying drawing. The demonstration plant does not have a flue gas energy recovery system and a carbon dioxide separation system. Wherein the internal diameter of the charred tank is 20 cm, and the internal diameter of the dense phase bed is 50 cm. The catalyst is regenerated according to the regeneration method proposed by the present invention, and pure oxygen gas is fed into the coke pot and the dense-phase bed respectively, and at the same time, the flue gas from the cyclone separation system of the regenerator is returned to the bottom of the dense-phase bed. The temperature of the scorching pot is 580°C, and the temperature of the dense bed of the regenerator is 640°C. The residence time of the catalyst in the burnt pot was 45 seconds, and the average residence time in the dense bed was 110 seconds. The superficial linear velocity of gas in the charred tank is 1.51m / s, ...

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Abstract

The invention discloses a catalyst regeneration method capable of reducing carbon dioxide discharge and improving selectivity. The catalyst regeneration method is characterized in that a catalyst with coke is subjected to pure oxygen-based partial regeneration in a coke combustion tank, and the partially regenerated catalyst goes through a macroporous distribution plate, then is fed into a dense bed of a regenerator and then is subjected to residual coke burning; the dense bed is provided with a cooler for controlling a temperature of the dense bed; after cyclone separation, most of flue gas orderly enters into a flue gas energy recovery system and a carbon dioxide separation system, after carbon dioxide separation, a capturing process is carried out, and a small part of the flue gas is returned to the bottom of the coke combustion tank; and the regenerated catalyst is cooled and activated and then is fed into a reactor for recycle. The catalyst regeneration method realizes complete regeneration of a catalyst and uniform distribution of catalyst activity so that coke as a catalytic cracking by-product and a dry gas yield are reduced. The catalyst regeneration method greatly reduces carbon emission and even realizes zero emission of carbon.

Description

technical field [0001] The invention relates to a method for regenerating carbon-containing catalysts in hydrocarbon processing. More specifically, the present invention relates to a catalyst regeneration method for reducing carbon dioxide emissions and improving catalyst selectivity in the heavy oil catalytic cracking process. Background technique [0002] Today, the development of the global oil refining industry is facing many challenges such as oil price fluctuations, the trend of worsening crude oil quality, improved oil product quality specifications, stricter requirements for energy conservation and emission reduction, and the rapid development of biofuels. Reducing carbon dioxide emissions and mitigating climate change have become the key factors for the oil refining industry to transform the economy. The way of growth and the only way to maintain sustainable development. In October 2009, the country announced the action goal of controlling greenhouse gas emissions,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J38/20B01J29/90
Inventor 龚剑洪许友好李首先王新
Owner CHINA PETROLEUM & CHEM CORP
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