A kind of functional salix regenerated cellulose fiber and its preparation method

A regenerated cellulose, functional technology, applied in the field of natural polymers and textiles, can solve unseen problems, and achieve the effects of increasing functionality, preventing agglomeration and improving utilization.

Inactive Publication Date: 2015-12-09
青岛豪门实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is no literature that uses the extracted salix cellulose for spinning to prepare salix regenerated cellulose fiber, nor does it add nanocomposite powder to the spinning solution to prepare functional salix regenerated cellulose fiber

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Preparation of Salix wood powder: Peel the Salix, crush it, pass a 100-mesh sieve, dry at 80°C, cool, and put it in a desiccator for later use;

[0023] (2) Extracting Salix cellulose: Add the Salix wood powder in step (1) to the autoclave, and add anhydrous ethanol-nitric acid mixture, where the addition amount of nitric acid is 3%wt, and the solid-liquid ratio is 1: 10. After heating to 120°C, stir for 3h, cool, filter, wash with absolute ethanol 5 times, rinse with deionized water repeatedly, and dry;

[0024] (3) Preparation of Salix Pulp: Use 10%wt NaOH to cook, bath ratio is 1:10, cooking temperature 200℃, time 3h, then 20%wt hydrogen peroxide bleaching, bleaching temperature 100℃, bleaching time 2h;

[0025] (4) Preparation of nano-composite powder-Salixo spinning solution: According to the volume ratio of 1:10, slowly add 1%wt nano-composite powder to the 10%wt salix cellulose solution, and add titanium Ester coupling agent, stirring at 80°C for 10 hours, the nan...

Embodiment 2

[0029] (1) Preparation of Salix wood powder: Peel the Salix, crush, pass through an 80-mesh sieve, dry at 90°C, cool, and put it in a desiccator for later use;

[0030] (2) Extracting Salix cellulose: Add the Salix wood powder in step (1) to the autoclave, and add anhydrous ethanol-sulfuric acid mixture, where the sulfuric acid addition amount is 4%wt, and the solid-liquid ratio is 1: 5. After heating to 120℃, stirring for 2h, cooling, filtering, washing with absolute ethanol 3 times, then repeatedly washing with deionized water and drying;

[0031] (3) Preparation of Salix Pulp: Use 5%wt NaOH for cooking, bath ratio of 1:5, cooking temperature 250℃, time 4h, then use 25%wt hydrogen peroxide to bleach, bleaching temperature 80℃, bleaching time 1h;

[0032] (4) Preparation of nano-composite powder-Salixo spinning solution: according to the volume ratio of 1:50, slowly drop 0.5%wt nano-composite powder into 15%wt salix cellulose solution, and add silane Coupling agent, stirring at 80...

Embodiment 3

[0035] (1) Preparation of Salix wood powder: Peel the Salix, crush, pass through a 60-mesh sieve, dry at 80°C, cool, and put it in a desiccator for later use;

[0036] (2) Extracting Salix cellulose: Add the Salix wood powder in step (1) to the autoclave, add anhydrous ethanol-hydrochloric acid mixed liquid, solid-liquid ratio 1:15, heat to 140 ℃, stir 3h, cooling, filtering, washing twice with absolute ethanol, then repeatedly washing with deionized water, and drying;

[0037] (3) Preparation of Salix Pulp: 15%wt NaOH cooking, bath ratio 1:10, cooking temperature 220℃, time 3h, then 20%wt hydrogen peroxide bleaching, bleaching temperature 80℃, bleaching time 2h;

[0038] (4) Preparation of nanocomposite powder-Salixo spinning solution: According to the volume ratio of 1:100, slowly add 0.1%wt nanocomposite powder to the 20%wt salix cellulose solution, and add silane Coupling agent, stirring at 80°C for 7 hours, where the nano composite powder is a mixture of nano titanium dioxide,...

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Abstract

The invention discloses functional salix psammophila regenerated cellulose fiber and a preparation method thereof. Salix psammophila is peeled, ground, sieved, dried and cooled to prepare salix psammophila wood meal; salix psammophila cellulose is extracted by an ethanol-acid mixed solution; the salix psammophila cellulose is subjected to technical processes such as cooking, bleaching and the like to prepare salix psammophila pulp; nano titanium dioxide, nano zinc oxide and nano zirconium dioxide in the mass ratio of 1:1:1 and the salix psammophila cellulose are filtered and subjected to pressure reduction deaeration to obtain a uniformly mixed spinning solution; and the spinning solution is subjected to coagulating bath spinning, drafting forming, refining and the drying to obtain the functional salix psammophila regenerated cellulose fiber. Nano composite powder and salix psammophila regenerated cellulose are taken as the raw materials, and the regenerated cellulose fiber with multiple functions such as anti-bacteria, ultraviolet and far infrared resistance and the like is prepared through efficient blending and wet spinning technologies.

Description

Technical field [0001] The invention relates to a functional salix regenerated cellulose fiber and a preparation method thereof, belonging to the field of natural polymers and textiles. Background technique [0002] For a long time, cellulose has been the main industrial raw material for textile and papermaking. It has received increasing attention due to its renewability, biodegradability and cost advantages. It has been used in drug control, release technology, immobilization technology, biosensor, and membrane materials. , Functional chemicals and additives have shown good development prospects. Due to the reduction of arable land and the increasing depletion of fossil resources such as oil and natural gas, the output of natural fibers and synthetic fibers will be more and more restricted. As a green, environmentally friendly, and renewable resource, regenerated cellulose has obtained an unprecedented development opportunity. [0003] Salix is ​​one of the few desert plants th...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): D01F2/00D01F1/10
Inventor钱景赵兵
Owner青岛豪门实业有限公司