Coating composition for waterproofing and moistureproofing
A composition and coating technology, applied in coatings, semiconductor/solid-state device parts, electric solid-state devices, etc., can solve problems such as unusable
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manufacture example 1
[0115] Manufacturing example 1 (Rf (C6) methacrylate / isobornyl methacrylate = 100 / 2.70 weight ratio) copolymer)
[0116] Add 34.08g perfluorohexylethyl methacrylate (CH 2 =C(CH 3 ) COOCH 2 CH 2 C 6 f 13 : hereinafter sometimes abbreviated as "Rf(C6) methacrylate"), 0.92g of isobornyl methacrylate (hereinafter abbreviated as "iBMA") and 66g of perfluorobutyl ethyl ether (C 4 f 9 OC 2 h 5 : sometimes abbreviated as "HFE7200"), nitrogen purge was performed for 10 minutes, and heated to 70°C. 0.136 g of azobisisobutyronitrile (hereinafter sometimes abbreviated as "AIBN") was added thereto, and reacted for 6 hours.
[0117] After cooling to room temperature, the fluoropolymer was precipitated with methanol and dried under reduced pressure. This was diluted with HFE7200 to prepare a solution of a predetermined concentration used in Examples described later.
[0118] The molecular weight of the fluoropolymer obtained by the above method was measured by GPC using a fluori...
manufacture example 2
[0119] Manufacturing example 2 (Rf(C6) methacrylate / iBMA=100 / 5.26 (weight ratio) copolymer)
[0120] Fluoropolymer was synthesized in the same manner as in Production Example 1, except that the amount of Rf(C6) methacrylate used was changed to 33.25 g, the amount of iBMA used was changed to 1.75 g, and the amount of AIBN used was changed to 0.139 g , to prepare the HFE7200 solution of the specified concentration used in the examples described later. The weight average molecular weight of the obtained polymer was 299,400.
manufacture example 3
[0121] Manufacturing example 3 (Rf(C6) methacrylate / iBMA=100 / 8.11 (weight ratio) copolymer)
[0122] A fluoropolymer was synthesized in the same manner as in Production Example 1, except that the amount of Rf(C6) methacrylate used was changed to 32.375 g, the amount of iBMA used was changed to 2.625 g, and the amount of AIBN used was changed to 0.142 g , to prepare the HFE7200 solution of the specified concentration used in the examples described later. The weight average molecular weight of the obtained polymer was 210,200.
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