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Preparation method of conductive polymer film with inverse opal structure

An inverse opal structure, conductive polymer technology, applied in the electrolytic process, electrolytic components, electrolytic organic production, etc., to achieve the effect of neat morphology, increase specific surface area, and improve color conversion speed

Active Publication Date: 2017-01-25
ZHEJIANG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] The non-template method does not require any template, and the preparation process is relatively simple and convenient, but it is relatively targeted, and only limited substances and materials can use this method

Method used

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  • Preparation method of conductive polymer film with inverse opal structure
  • Preparation method of conductive polymer film with inverse opal structure
  • Preparation method of conductive polymer film with inverse opal structure

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] The monomer is 1,4-bis(2-thiophene)benzene (BTB), and its structure is as follows:

[0057]

[0058] Operation process:

[0059] (1) Preparation of polystyrene microsphere monolayer template: ITO glass with an area of ​​2 cm × 4 cm was ultrasonically cleaned and dried, and a small amount of polystyrene microspheres (2.5% w / v, microsphere pore size 600 nm ) evenly spread a layer on the ITO glass (reserve the area for clamping the clip in the subsequent test), then place it horizontally for 30-40s, then slowly tilt it to a vertical state, and then place it on the bottom of the ITO glass for 10-20s Put it into a petri dish filled with deionized water, and the excess polystyrene microspheres will quickly disperse in the deionized water, and finally pull it out of the water surface to dry vertically to obtain a single self-assembled polystyrene microsphere. Layer template, and its scanning electron microscope (SEM) test ( figure 1 , as shown in 2).

[0060] (2) Prepara...

Embodiment 2

[0062] The monomer is 1,4-bis(3-thiophene)benzene, and its structure is as follows:

[0063]

[0064] The electrolyte solution and the blank solution are the same as in Example 1, and the polymerization electric quantity becomes 0.035C.

[0065] Operation process:

[0066] (1) Preparation of polystyrene microsphere monolayer template: ITO glass with an area of ​​2 cm × 4 cm was ultrasonically cleaned and dried, and a small amount of polystyrene microspheres (2.5% w / v, microsphere pore size 600 nm ) evenly spread on the ITO glass (reserve the area used for clamping the clip in the subsequent test), then place it horizontally for 30-40s, then slowly tilt it to a vertical state, and then put the bottom of the ITO glass into it after 10-20s In the petri dish filled with deionized water, the excess polystyrene microspheres will be quickly dispersed in deionized water, and finally pulled out of the water surface to dry vertically to obtain a single-layer template composed of pol...

Embodiment 3

[0069] The monomer is (three (4-(2-thiophene)) triphenylamine), and its structure is as follows:

[0070]

[0071] The electrolyte solution and the blank solution are the same as in Example 1, except that the microspheres are changed to amino polystyrene microspheres (600-1000nm2.5% w / v).

[0072] Operation process:

[0073] (1) Preparation of aminopolystyrene microsphere monolayer template: ultrasonically clean the ITO glass with an area of ​​2cm×4cm and dry it, and take a small amount of aminopolystyrene microspheres (2.5% w / v, 600nm) with a dropper Spread it evenly on the ITO glass (reserve the area for clamping the clip in the subsequent test), then place it horizontally for 30-40 seconds, then slowly tilt it to a vertical state, and then put the bottom of the ITO glass into the container after 10-20 seconds. In the petri dish with deionized water, the excess aminopolystyrene microspheres will be quickly dispersed in deionized water, and finally pulled out of the water...

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Abstract

The invention discloses a preparation method of a conductive polymer film having an inverse opal structure. The preparation method comprises that an electrochemical polymerization reaction occurs based on polymeric microspheres (comprising polystyrene microspheres or amino-polystyrene microspheres) as templates, and then the conductive polymer film having an inverse opal structure is obtained by impurity removal treatment and polymeric microsphere removal treatment. The preparation method has simple processes, utilizes the polymeric microspheres as hard templates, and can be carried out at a room temperature without harsh reaction conditions. The prepared conductive polymer film having an inverse opal structure has tidy morphology and good structural environment stability.

Description

[0001] (1) Technical field [0002] The invention relates to a preparation method of a conductive polymer nanometer material, in particular to a preparation method of a conductive polymer electrochromic film with an inverse opal structure. [0003] (2) Background technology [0004] With the development of science and technology, the development of materials tends to the nanometer field. Nano science and technology are showing broad application prospects in information, energy, environment, chemistry, microelectronics, micromanufacturing, biology, medicine and national defense. In the past few decades, the development of inorganic nanomaterials has received widespread attention, especially in terms of preparation methods and shape control, and researchers have carried out a series of in-depth studies. In recent years, the preparation and application of polymeric nanomaterials has attracted interest. Polymer nanomaterials have the advantages of unique optoelectronic properties...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G61/12C08J5/18C08J9/26C08L65/00C25B3/00
Inventor 张诚黄森彪吕晓静欧阳密戴玉玉杨媛
Owner ZHEJIANG UNIV OF TECH
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