A preparation method of polymer composite fiber containing ultrafine metal fiber and polymer composite fiber prepared therefrom
A composite fiber and metal fiber technology, which is applied in the field of polymer composite fiber preparation, can solve the problems of increasing the proportion of metal in the core layer and increasing production costs, and achieve the effects of low equipment cost, improved production efficiency, and simple equipment
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Embodiment 1
[0028] Melt-processable polyvinyl alcohol (Kuraray Company, brand CP-1000, melting point 174°C) and tin-lead-silver alloy powder (melting point 180°C, particle size 24-45 μm, Beijing Sanhe Dingxin High-tech Development Co., Ltd. ) mixed uniformly in a high-speed mixer; the volume fraction of the tin-lead-silver alloy is 5%vol, and then melted and blended by the PolymLab twin-screw extruder of the German HAAKE company. The temperature of each section of the extruder is 140°C, 170°C, 170°C, 175°C, 175°C, 180°C (head die temperature). After the blend melt is extruded from the die, it is directly stretched at a high speed with a draw ratio of 310 and wound up to obtain polyvinyl alcohol / metal composite fibers. According to the observation of Nano-CT photographs, the ultrafine metal fibers contained in the obtained polymer composite fibers have a diameter of 0.5-10 μm and a length of 100-3000 μm.
Embodiment 2
[0030] Except that the die temperature of the twin-screw extruder was set at 185° C., the rest were the same as in Example 1. According to the observation of Nano-CT photographs, the ultrafine metal fibers contained in the obtained polymer composite fibers have a diameter of 0.5-10 μm and a length of 100-5000 μm.
Embodiment 3
[0032] Except that the particle size of the tin-lead-silver alloy powder is changed to 15-25 μm (Beijing Sanhe Dingxin High-tech Development Co., Ltd.), and the draw ratio of the polyvinyl alcohol / metal composite fiber is 350, other conditions are the same as in Example 1 . According to the observation of Nano-CT photographs, the ultrafine metal fibers contained in the obtained polymer composite fibers have a diameter of 0.2-6 μm and a length of 30-700 μm.
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