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A kind of pretreatment method of long glass fiber yarn

A technology of long glass fiber and glass fiber yarn, applied in the field of pretreatment, can solve the problem of inability to prepare long glass fiber reinforced PA10T material with high content of glass fiber, etc., and achieve the effects of low cost, simple processing and stable quality

Active Publication Date: 2016-08-17
贵州凯科特材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a pretreatment method for long glass fiber yarns for the long glass fiber reinforced PA10T material that cannot be prepared with high glass fiber content in the existing melt impregnation process

Method used

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  • A kind of pretreatment method of long glass fiber yarn

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Put the grade ER4301 alkali-free glass fiber yarn (2400 tex) into an oven that has been heated to 160±10°C, and the glass fiber is pressed in the oven. figure 1 Arrange the structure as shown, hold for 10 minutes, take it out and cool it to room temperature, and then immerse it in 50L concentrated sulfuric acid containing PA10T. The concentration of PA10T in concentrated sulfuric acid is 0.04g / ml, take it out after soaking for 10 minutes, then use Ionized water is sprayed and the residence time is 10 minutes. Then spray with deionized water until the surface pH is greater than 6.5, and finally put it in a drying box at 100°C for 60 minutes, take it out and wind it into a roll to get the product. After testing, the content of PA10T in the product is 1.53% ( quality score).

Embodiment 2

[0017] Put the grade ER4301 alkali-free glass fiber yarn (2400 tex) into an oven that has been heated to 170±10°C, and the glass fiber is pressed in the oven figure 1 Arrange the structure as shown, keep warm for 8 minutes, take it out and cool it to room temperature, then immerse it in 50L, PA10T in concentrated sulfuric acid concentration of 0.04g / ml, take it out after soaking for 8 minutes, and then spray it with deionized water, stay Time 8 minutes. Then spray with deionized water until the surface pH is greater than 6.5, and finally put it in a drying box at 100°C for 50 minutes, take it out and wind it into a roll to get the product. After testing, the content of PA10T in the product is 1.13% ( quality score).

Embodiment 3

[0019] Put the brand ER4301 alkali-free glass fiber yarn (2400 tex) into the oven that has been heated to 180±10°C, and the glass fiber is pressed in the oven. figure 1 Arrange the structure as shown, hold for 7 minutes, take it out and cool it to room temperature, then immerse it in 50L, PA10T in concentrated sulfuric acid concentration of 0.04g / ml, take it out after soaking for 7 minutes, and then spray it with deionized water, stay Time 7 minutes. Then spray with deionized water until the surface pH is greater than 6.5, and finally put it in a drying box at 100°C for 40 minutes, take it out and wind it into a roll to get the product. After testing, the content of PA10T in the product is 0.73% ( quality score).

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Abstract

The invention provides a pre-treatment method of a long glass fiber yarn. The pre-treatment method comprises the following steps: step 1, carrying out heat preservation for 5-10 minutes on the glass fiber yarn at a temperature of 150-200 DEG C; step 2, soaking for 5-10 minutes in a concentrated sulfuric acid solution containing PA10T; step 3, atomizing with deionized water and staying for 5-10 minutes; step 4, spraying with deionized water till the PH on the surface is higher than or equal to 6.5 and removing redundant sulfuric acid; step 5, drying for 30-60 minutes at a temperature of 100 DEG C. The pre-treatment method solves the problem that a long glass fiber reinforced PA10T material with high glass fiber content cannot be prepared according to the conventional melt impregnation process. The invention belongs to the field of pre-treatment of glass fiber yarns.

Description

technical field [0001] The invention relates to a pretreatment method, in particular to a pretreatment method for grafting PA10T on the surface of glass fiber yarns. Background technique [0002] Nylon 10T (PA10T) is a high-temperature-resistant semi-aromatic nylon, which is obtained by polycondensation of aliphatic diamine or diacid and diacid or diamine with aromatic ring. It is a kind of aromatic nylon. Due to the introduction of aromatic rings into the main chain segment of nylon molecules, the heat resistance and mechanical properties are improved, water absorption is reduced, and it has better cost performance. It is between general engineering plastic nylon and high temperature resistant engineering plastic PEEK. Resins with high heat resistance between them are mainly used in the automotive and electrical and electronic industries. Since the processing temperature of PA10T is close to the decomposition temperature, the material will decompose while processing PA10T ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M15/59
Inventor 郭建兵何敏秦舒浩刘渝张道海张翔明星星张峰雷振刚刘一春杨荣强粟多文高京吴俊张家宝刘小柱杨廷国
Owner 贵州凯科特材料有限公司