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A kind of modified hydroxyethyl cellulose tackifier for drilling and preparation method thereof

A technology of hydroxyethyl cellulose and thickening agent, which is applied in the field of polymers, can solve the problems of loss of thickening effect and poor salt resistance, and achieve the effect of simple preparation method, thickening effect and strong salt resistance

Inactive Publication Date: 2017-11-24
SOUTHWEST PETROLEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a modified hydroxyethyl cellulose viscosifier for drilling. Within a reasonable dosage range, the viscosifier can effectively increase the viscosity of the drilling fluid, improve the flow state of the fluid, and increase the viscosity of the drilling fluid. The comprehensive performance of the slurry overcomes the defects of ordinary tackifiers such as the breakage of the molecular chain structure at high temperature and the loss of the thickening effect, poor salt resistance, etc., and makes up for the technical gap

Method used

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  • A kind of modified hydroxyethyl cellulose tackifier for drilling and preparation method thereof
  • A kind of modified hydroxyethyl cellulose tackifier for drilling and preparation method thereof
  • A kind of modified hydroxyethyl cellulose tackifier for drilling and preparation method thereof

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Embodiment 1

[0030] In a 500ml three-neck flask, 30g of hydroxyethylcellulose and 10g of sodium p-styrenesulfonate were fully dissolved in 300ml of deionized water to obtain a reaction solution. Accurately weigh 0.2 g of ammonium persulfate, fully dissolve it with 20 ml of deionized water and transfer the solution to a constant pressure separatory funnel. Nitrogen was blown into the reaction flask to remove air, and the temperature of the system was raised to 50°C. The ammonium persulfate solution was added dropwise through a constant pressure separatory funnel for reaction. After 8 hours, the reacted mixed solution was immersed in sufficient acetone for precipitation to obtain a polymer. Dry and grind into powder to obtain the graft copolymer of hydroxyethyl cellulose / sodium p-styrene sulfonate.

[0031] 2. Infrared Spectrum Test and Analysis of Modified Hydroxyethyl Cellulose Viscosifier for Well Drilling

[0032] figure 1 It is the Fourier transform infrared spectrum test of the tack...

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Abstract

The invention discloses modified hydroxyethyl cellulose tackifier for well drilling and a preparation method thereof. The tackifier is prepared by performing graft copolymerization modification on hydroxyethyl cellulose and sodium p-styrene sulfonate. A preparation process is as follows: (1), hydroxyethyl cellulose and sodium p-styrene sulfonate are dissolved with deionized water respectively and mixed, a mixed solution is obtained, and an initiating agent is added; (2), the mixed solution is heated to 40 DEG C-60 DEG C to have a polymerization reaction for 6-8 hours in the nitrogen environment, and a graft copolymerization product solution of hydroxyethyl cellulose and sodium p-styrene sulfonate is obtained; (3), the graft copolymerization product solution is extracted with acetone or absolute ethyl alcohol, dried and ground into powder, and then modified hydroxyethyl cellulose tackifier for well drilling is obtained. The tackifier can effectively improve the viscosity of a working fluid for well drilling, improve the flowing state of the fluid and improve the comprehensive performance of slurry and can be compatible with various additives; the principle of the preparation method is reliable, the operation is easy and convenient, raw materials are easy to obtain and low in price, and environment protection is facilitated.

Description

technical field [0001] The invention relates to the technical field of macromolecules, in particular to a modified hydroxyethyl cellulose thickener for well drilling and a preparation method thereof. Background technique [0002] In drilling engineering, in order to ensure that various working fluids such as drilling fluid and spacer fluid have high viscosity and good rheology, it is usually necessary to add an appropriate amount of viscosifier. Water-soluble polymer viscosifiers, through the bridging, adsorption, and entanglement between molecular chains or between molecular chains and other particles, can increase the viscosity of the working fluid system and improve the flow state of the slurry. Therefore, the use of viscosifiers is beneficial to the stability of well walls and the safety of construction operations. Common tackifier materials include the following categories: cellulose, biological glue (such as guar gum, xanthan gum, etc.), and synthetic acrylamide polym...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/035C09K8/40C08F251/02C08F212/14
CPCC08F251/02C09K8/035C09K8/40C08F212/14
Inventor 张洪旭庄稼程小伟黄盛辜涛梁秋梅
Owner SOUTHWEST PETROLEUM UNIV
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