Boiler chromium-based slag-removing coal-saving agent composition and preparation method thereof

A technology of coal-saving agent and composition, which is applied in the preparation field of boiler chromium-based slag-removing coal-saving agent composition, which can solve the problems of deterioration of heat transfer conditions, incomplete coal combustion, and reduced thermal efficiency of heat conduction boilers, so as to reduce reaction activation Energy, improve activity and effect, eliminate the effect of furnace tail coking

Active Publication Date: 2018-01-09
刘音希
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] (1) The thermal conductivity of the boiler heating surface is very small due to coking and slagging, which is only 1 / 400 of the metal on the heating surface, so that the thermal resistance increases significantly, the heat transfer condition deteriorates rapidly, the exhaust gas temperature rises, and the thermal efficiency of the heat conduction boiler Decrease, affect waste heat boiler output
[0004] (2) Serious slagging and coking will eventually cause the boiler to shut down and manual coke cleaning
For example, the data show that sulfur is easy to directly react with carbon steel at 350-400°C to form ferrous sulfate, forming high-temperature corrosion, and above 450°C, its damage to the furnace tube is more serious, and ferric sulfate is acidic and easily Moisture absorption, after the furnace is shut down to cool down, it begins to absorb moisture and deliquescence, forming a strongly acidic corrosive environment on the heating surface, causing the boiler heating surface to be damaged by dilute acid corrosion during the shutdown period
[0006] (4) Coking and slagging cause incomplete combustion of coal in the boiler, and CO and SO in the smoke 2 Elevated content, serious pollution to the environment
[0007] (5) Coking reduces the cross-sectional area of ​​the flue gas flow, increases the flow resistance, and significantly increases the positive pressure of the furnace
Some manufacturers have adopted this technology successively, which can reduce the amount of fly ash in the flue gas and improve the thermal efficiency of the boiler. However, the auxiliary system of the boiler needs to be transformed, which requires a large investment, but it cannot solve the coking problem. Recently, a sonic cleaner method has also appeared to deal with it. Coking problem, but the effect is not ideal
In order to remove the slagging in the furnace, special equipment such as a soot blower is used to blow the soot on a regular basis, which can remove the loosely deposited ash on the heating surface. However, the slagging of the fuel has both physical and chemical effects. High strength, with unlimited growth characteristics, difficult to remove by mechanical means
[0011] In recent years, in Hebei, Liaoning, Shaanxi and other regions, boiler slag remover and coal-saving agent products have been developed and tested in coal-fired boilers. Although some have effects, the effect is not obvious; some form glass bodies after being added to the furnace. Not only can't remove the coke, but make the coke more firmly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Embodiment 1, take raw material by following components and weight: Dichromium trioxide 60kg, copper sulfate 10kg, cerium oxide 9kg, barium molybdate 9kg, cobalt carbonate 8kg, potassium permanganate 13kg, manganese oxide 10kg, potassium carbonate 12kg, titanium dioxide 14kg, zinc oxide 18kg, potassium chlorate 10kg, potassium perchlorate 10kg, sodium carbonate 24kg, active attapulgite 30kg and woody naphthalenesulfonate 0.2kg. The raw materials of the above-mentioned parts by weight are prepared into boiler chromium-based slag-removing coal-saving agent composition according to the following method:

[0048] 1. Mix 60 kg of dichromium trioxide, 10 kg of copper sulfate, 9 kg of cerium oxide and 9 kg of barium molybdate in the above parts by weight, and crush with a grinder to pass through an 80-mesh sieve to obtain the first powder;

[0049] 2. After crushing 30 kg of the above-mentioned active attapulgite clay through a 20-mesh sieve, add it to the first powder, mix an...

Embodiment 2

[0052] Embodiment 2, take raw material by following component and weight: Dichromium trioxide 55kg, copper sulfate 8kg, cerium oxide 7kg, barium molybdate 6kg, cobalt carbonate 13kg, potassium permanganate 16kg, manganese oxide 14kg, salt of wormwood 15kg, titanium dioxide 15kg, zinc oxide 19kg, potassium chlorate 9kg, potassium perchlorate 8kg, sodium carbonate 20kg, activated attapulgite 25kg and woody naphthalenesulfonate 0.1kg. The method of preparing the boiler chromium-based slag-removing coal-saving agent composition from the above-mentioned raw materials in parts by weight is the same as that in Example 1.

Embodiment 3

[0053] Embodiment 3, take raw material by following component and weight: Dichromium trioxide 50kg, copper sulfate 13kg, cerium oxide 5kg, barium molybdate 8kg, cobalt carbonate 10kg, potassium permanganate 12kg, manganese oxide 13kg, salt of wormwood 17kg, titanium dioxide 10kg, zinc oxide 15kg, potassium chlorate 6kg, potassium perchlorate 9kg, sodium carbonate 26kg, activated attapulgite 29kg and woody naphthalenesulfonate 0.3kg. The method of preparing the boiler chromium-based slag-removing coal-saving agent composition from the above-mentioned raw materials in parts by weight is the same as that in Example 1.

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PUM

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Abstract

The invention relates to an additive product suitable for coal-fired boilers in industries such as electric power, thermoelectricity, petroleum, chemical industry and metallurgy; in particular, it is a boiler chromium-based slag-removing coal-saving agent composition used in coal-fired boilers, which consists of Composition of the following components and parts by weight: 50-65 parts of dichromium trioxide, 8-15 parts of copper sulfate, 5-9 parts of cerium oxide, 5-9 parts of barium molybdate, 7-14 parts of cobalt carbonate, high manganese 12-17 parts of potassium chloride, 10-16 parts of manganese oxide, 12-17 parts of potassium carbonate, 8-15 parts of titanium dioxide, 15-20 parts of zinc oxide, 6-10 parts of potassium chlorate, 6-10 parts of potassium perchlorate, 20 parts of sodium carbonate ~28 parts, 25~35 parts of activated attapulgite clay and 0.1~0.3 parts of lignonaphthalenesulfonate. It is a high-tech energy-saving and environmental protection product with high-efficiency combustion-supporting, high coal-saving rate, reduced pollution, improved combustion efficiency, and extended boiler service life; the water-cooled wall pipes of the furnace and the old coke body of the surrounding gas injection will be detached within 3 to 5 days; The newly generated coke slag will fall off automatically and periodically.

Description

technical field [0001] The invention relates to an additive product suitable for use in coal-fired boilers in industries such as electric power, thermoelectricity, petroleum, chemical industry and metallurgy; specifically, it is a boiler chromium-based slag-removing coal-saving agent composition used in coal-fired boilers. The present invention It also relates to a preparation method of the boiler chromium-based slag-removing coal-saving agent composition. Background technique [0002] With the rapid development of my country's socialist market economy, more and more boilers are produced and used. Industrial boilers are indispensable heat source equipment for the national economy and the people's livelihood. They are not only large coal consumers, but also a large source of air pollution. According to statistics, my country now has more than 500,000 boilers, and the types of coal used in boilers are also very complex, with a wide range of production areas and different advan...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L9/10
Inventor 刘音希赵丽萍刘志新
Owner 刘音希
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