The present invention relates to an additive product suitable for coal-fired boilers of electric power, thermal power, petroleum, chemical and metallurgical and other industries, and particularly relates to a chromium-based boiler slag-removing coal-saving composition used for a coal fired boiler, and the chromium-based boiler slag-removing coal-saving composition consists of the following components in parts by weight: 50 to 65 parts of chromium oxide, 8 to 15 parts of copper sulfate, 5 to 9 parts of cerium oxide, 5 to 9 parts of barium molybdate, 7 to 14 parts of cobalt carbonate, 12 to 17 parts of potassium permanganate, 10 to 16 parts of manganese oxide, 12 to 17 parts of potassium carbonate, 8 to 15 parts of titanium dioxide, zinc oxide, 15 to 20 parts of zinc oxide, 6 to 10 parts of potassium chlorate, 6 to 10 parts of potassium perchlorate, 20 to 28 parts of sodium carbonate, 25 to 35 parts of active attapulgite carclazyte and 0.1 to 0.3 part of lignonaphthalenesulfonate. The chromium-based boiler slag-removing coal-saving composition is a high-tech energy-saving environmentally-friendly product which is efficient, combustion-helping, and high in coal saving ratio, and can reduce pollution, improve combustion efficiency, and extend the boiler service life; fuel gas spray old coke body on and around furnace water cooling wall tube can be cleanly removed in 3 to 5 days; and new generated coke residue body can be automatically and periodically shed off.