An ultraviolet fluorescence three-signal water quality sensor with a single uv-led as the light source and its application
A water quality sensor, UV-LED technology, applied in the direction of fluorescence/phosphorescence, color/spectral characteristic measurement, material excitation analysis, etc., can solve the problems of inconvenient to carry, multi-light source error, high cost, etc., achieve simple structure, no need for heat dissipation, low cost effect
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Embodiment 1
[0044] A kind of UV-fluorescent three-signal water quality sensor with a single UV-LED as the light source in this embodiment can simultaneously monitor the three signals of UV absorbance UV280, protein fluorescence and humic substance fluorescence, such as figure 1 As shown, including the optical path part and the signal control processing part, such as Figure 5 As shown, the optical path part includes UV-LED 51, sample cell 52, ultraviolet detector, fluorescence detector A and fluorescence detector B; the UV-LED selects a deep ultraviolet LED with a wavelength of 280±15nm, is packaged in a TO39 bracket, and has a luminous angle of Less than 30 degrees. The ultraviolet detector adopts a photodiode 55 with enhanced ultraviolet response. Fluorescent detectors include silicon photodiodes 55 and band-pass filters, and band-pass filters A 53 with a wavelength of 330-360 nm are used for monitoring protein fluorescence; at the same time, band-pass filters with a wavelength of 410-...
Embodiment 2
[0057] The specific structure of the ultraviolet fluorescent three-signal water quality sensor using a single UV-LED as a light source in this embodiment is the same as that in Embodiment 1, and can be applied to the prediction of the generation potential of disinfection by-products in drinking water.
[0058] The disinfection generation potential experiment was carried out on drinking water source water and its water samples after enhanced coagulation and ion exchange treatment in 16 counties and cities in Jiangsu Province. Water quality sensors were used to test the UV280 ultraviolet absorbance, protein and humic substance fluorescence signals of each water sample. The disinfection by-product indicators trihalomethanes (THMs) and haloacetic acids (HAAs) were detected by gas chromatography and gas chromatography mass spectrometry. Such as Figure 9 As shown, by fitting the spectral signal and the generation amount of disinfection by-products, the results show that all three s...
Embodiment 3
[0060] The ultraviolet fluorescent three-signal water quality sensor using a single UV-LED as a light source in this embodiment can be applied to predict the degradation degree of micro-pollutants in the advanced ozone oxidation process.
[0061] The ultraviolet fluorescent three-signal water quality sensor of the present embodiment monitors the water quality change curve in the process of ozone oxidation online, such as Figure 10As shown, it is divided into pure water zero calibration stage 101 , water inflow stage 102 , stabilization stage 103 and ozone degradation stage 104 . The inventor of the present application has studied the relationship between the degree of degradation of 14 kinds of micropollutants in the ozone oxidation process and the removal rate of ultraviolet absorbance UV280 or protein fluorescent signal or humic substance fluorescent signal. These 14 kinds of micropollutants include: bisphenol A ( CAS: 80-05-7), Carbamazepine (CAS: 298-46-4), Diclofenac Sod...
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