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Natural rubber composite material and preparation method thereof

A technology of natural rubber and composite materials, applied in the field of rubber reinforcement, can solve problems such as the decline of wear resistance of rubber materials

Active Publication Date: 2016-05-11
AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, a large filling of silica will lead to a decrease in the wear resistance of the compound

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0064] The present invention also provides a kind of preparation method (A+B method) of natural rubber composite material, comprises the following steps:

[0065] mixing the white carbon black dispersion with the first natural rubber to obtain a mixed material containing white carbon black;

[0066] Mixing the mixed material containing white carbon black with the first coagulant to obtain a white carbon black masterbatch after solidification;

[0067] mixing the silica dispersion with the second natural rubber to obtain a mixed material containing silica;

[0068] Mixing the mixed material containing silica with a second coagulant to obtain a silica masterbatch after solidification;

[0069] After mixing and vulcanizing the silica masterbatch, silica masterbatch, carbon black, coupling agent, softener, antioxidant, active agent, accelerator and vulcanizing agent, a natural rubber composite material is obtained;

[0070] Described white carbon black, the first natural rubber,...

Embodiment 1

[0105] Add 45g of white carbon black powder to 360g of water, use a high-shear homogenizer, disperse the resulting mixed material at 10,000rpm for 30min, add it to 400g of fresh latex with a dry content of 20%, and mechanically stir at 500rpm for 30min , add 32g of acetic acid solution with a mass fraction of 5% to solidify for 10min, dehydrate and dry at 100°C for 4h to obtain a white carbon black masterbatch; add 5g of silica to 50g of water, and use a high-shear homogenizer at 10,000rpm The obtained mixed material was dispersed for 30 minutes, added to 100 g of fresh latex with a dry content of 20%, mechanically stirred at 500 rpm for 30 minutes, and 8 g of acetic acid solution with a mass fraction of 5% was added to solidify for 10 minutes, dehydrated and dried at 100 ° C. After 4 hours, the white carbon black masterbatch was obtained. Then the silica masterbatch of 125g preparation and the silica masterbatch of 25g preparation, with 5g carbon black N330, 4g bis(triethoxyp...

Embodiment 2

[0107] Add 45g of white carbon black powder and 5g of silica to 360g of water, use a micro-jet homogenizer to disperse the obtained mixed material at 200MPa, the number of cycles is 5 times, and add it to 500g of 20% dry In fresh latex, mechanically stir at 500rpm for 30min, add 40g of formic acid solution with a mass fraction of 2% for coagulation for 30min, dehydrate and dry at 100°C for 4h to obtain a silica / silica masterbatch. Then the white carbon black / silica masterbatch of 150g preparation, with 5g carbon black N330, 4g bis(triethoxypropylsilane) tetrasulfide, 1g antioxidant RD, 4gTDAE oil, 1g stearic acid, 3gZnO , 1.5g of CZ, 2g of D and 1.5g of sulfur were mixed and vulcanized according to a conventional mixing process to obtain a rubber composite material.

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PUM

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Abstract

The invention provides a natural rubber composite material and a preparation method thereof. According to the natural rubber composite material, silicon earth replaces some white carbon black to be used as a filling material, and the characteristics of low filling and high reinforcing are achieved; themogenesis of the rubber material can be obviously lowered through a small amount of silicon earth, the fatigue life is prolonged, and the tear strength and wear-resisting property of the rubber material are improved. Compared with a natural rubber material with no silicon earth, the heating-up value is lowered by 37%, the flex fatigue life is prolonged by 167%, the tear strength is improved by 32%, and abrasion amount is lowered by 51%. The A+B method and the one-pot method are used for preparing the natural rubber composite material, and the preparation method is easy, convenient, practical and applicable to large-scale industrial production.

Description

technical field [0001] The invention relates to the technical field of rubber reinforcement, in particular to a natural rubber composite material and a preparation method thereof. Background technique [0002] Rubber is widely used in the preparation of automobile tires, conveyor belts, and various sealing devices due to its good elasticity, insulation, and air tightness. However, with the development of science and technology and the continuous expansion of the application field of rubber, people have put forward higher and more requirements for the strength and functionality of rubber. Since many rubber materials are used under dynamic conditions, such as automobile tires, transport conveyor belts, dynamic sealing rings, etc., rubber products will generate heat due to hysteresis loss during dynamic use, which will lead to product fatigue failure and reduced service life. Therefore, reducing the heat generation of rubber will help to improve the service life of rubber prod...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08K13/02C08K3/36C08K3/04C08K5/09C08K3/22
CPCC08K3/04C08K3/22C08K3/36C08K5/09C08K13/02C08K2003/2296C08K2201/005C08K2201/014C08L7/00
Inventor 彭政廖禄生钟杰平许逵张福全汪月琼王兵兵李一民
Owner AGRI PRODS PROCESSING RES INST CHINESE ACAD OF TROPICAL AGRI SCI