Application of terpolymer nanosphere loaded Ni-B catalyst to sodium borohydride catalysis and hydrolysis hydrogen generation reaction

Abstract

The invention provides application of a terpolymer nanosphere loaded Ni-B catalyst to sodium borohydride catalysis and hydrolysis hydrogen generation reaction. According to the catalyst, N-isopropylacrylamide, 2-acrylamido-2-methylpropane sulfonic acid and N-tert-butyl acrylamide serve as comonomers, N,N'-methylene bisacrylamide serves as the cross-linking agent, potassium persulfate serves as an initiator, and the materials are synthesized into terpolymer nanospheres through the soap-free emulsion polymerization method; the nanospheres are dispersed in a nickel sulfate solution to adsorb nickel ions, and the adsorbed nickel ions are reduced into nickel metal after centrifugation; the terpolymer nanospheres containing a small amount of nickel metal are dispersed into a nickel plating solution for chemical nickel plating, and the terpolymer nanosphere loaded Ni-B catalyst is obtained. According to the catalyst, raw materials are easy to obtain, the synthesis method is simple, catalysis efficiency is high, reaction operation is easy, and the catalyst can be repeatedly used and suitable for sodium borohydride catalysis and hydrolysis hydrogen generation reaction.

Description

[0001] The patent application of the present invention is a divisional application of a Chinese patent application with the filing date of May 30, 2014, the application number of 201410240494.0, and the name of Ni-B catalyst supported by terpolymer nanospheres, its preparation method and application. technical field [0002] The invention belongs to the technical field of material science, and in particular relates to a polymer composite material, in particular to the application of a Ni-B catalyst supported by a terpolymer in catalyzing the hydrolysis reaction of sodium borohydride to produce hydrogen. Background technique [0003] In order to overcome the problems of future energy shortage and environmental pollution, the search for renewable green energy is an important issue that needs to be solved urgently in the world. At present, hydrogen energy is considered to be one of the most ideal clean energy sources in the future energy structure. Hydrogen has a high energy den...

AI Technical Summary

Problems solved by technology

[0005] Chinese patent application 201010134982.5 reported a Ru / C catalyst using a porous carbon material as a carrier. This catalyst has a large surface area, high activity, and long life. However, the precious metal Ru has limited reserves and is expensive, so it is not widely used in practice.

However, this unsupported catalyst is prone to agglomeration, resulting in a sharp drop in catalytic activity and poor reusability.

[0007] At present, sodium borohydride hydrolysis catalysts have defects such as high price or low catalytic activity, poor performance, poor catalyst reuse and regeneration performance, etc.

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