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Method for determination of metallic iron content in reduced pellets

A determination method and technology for iron content, which are used in chemical analysis by titration, measurement device, preparation of samples for testing, etc. Reduction of the content of metallic iron in pellets to achieve high accuracy

Active Publication Date: 2018-10-16
武汉钢铁有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the ore is reduced to metallic iron in the reduced pellets, there are many unreduced oxides accompanying the reduced pellets, and there are many larger metallic iron particles with a particle size between 0.2mm and 3.0mm when the sample is prepared. The metal iron particles are not easy to be crushed. If the original analysis method of metal iron in ore raw materials is used, that is, the method of ferric chloride solution leaching, the dissolved sample analysis cannot be carried out, and the content of metal iron in the reduced pellets cannot be accurately determined. Therefore, it is impossible to guide the feasibility and effect of process research

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The reduced pellet sample submitted for inspection was named No. 1, and the metal iron content of the No. 1 sample was determined;

[0034] 1) Determination of the quality of the sample: pulverize the No. 1 sample, and then pass through a 140-mesh sample sieve, wherein the part passing through the sample sieve is the under-sieve sample, with a total mass of m 2 =20.5g, the average particle size is 0.08mm, the part that has not passed through the sample sieve is the sample on the sieve, and the total mass is m 1 =35.2g, the average particle size is 2.5mm;

[0035] 2) Determination of the content of metallic iron in the sample on the sieve: take three parts of the sample on the sieve, and the quality is controlled at about 0.10g, respectively m a =0.1031g, m b =0.1025g, m c=0.1065g, carry out parallel determination experiment simultaneously, place the sample on the sieve in the conical flask of dry 250mL respectively, then add 2g sodium bicarbonate simultaneously in ea...

Embodiment 2

[0059] The reduced pellet sample submitted for inspection was named No. 2, and the iron content of the No. 2 sample was determined;

[0060] 1) Take the quality of the sample: pulverize the No. 2 sample, then pass through a 130-mesh sample sieve, the part that passes through the sample sieve is the under-sieve sample, and its total mass is m 2 =22.5g, the average particle size is 0.090mm, the part that has not passed through the sample sieve is the sample on the sieve, and its total mass is m 1 =46.0g, the average particle size is 2.1mm;

[0061] 2) Determination of the content of metallic iron in the sample on the sieve: take three parts of the sample on the sieve, and the quality is all controlled at about 0.20g, respectively m a =0.1998g, m b =0.2015g, m c =0.2004g, carry out parallel determination experiment simultaneously, three parts of samples on the sieve are respectively placed in the Erlenmeyer flask of dry 500mL, then add 4g sodium bicarbonate simultaneously in e...

Embodiment 3

[0084] The reduced pellet sample submitted for inspection was named No. 3, and the iron content of No. 3 sample was determined;

[0085] 1) Take the quality of the sample: pulverize the No. 3 sample, then pass through a 150-mesh sample sieve, the part that passes through the sample sieve is the under-sieve sample, and its total mass is m 2 =18.2g, the average particle size is 0.085mm, the part that does not pass through the sample sieve is the sample on the sieve, and its total mass is m 1 =50.6g, the average particle size is 2.74mm;

[0086] 2) Determination of the content of metallic iron in the sample on the sieve: take three parts of the sample on the sieve, and the quality is controlled at about 0.10g, respectively m a =0.0998g, m b =0.1012g, m c =0.1005g, carry out parallel determination experiment simultaneously, three parts of samples on the sieve are respectively placed in dry 250mL flasks, feed nitrogen continuously into the flasks, add 20mL of sodium fluoride sol...

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Abstract

The invention discloses a method for measuring metallic iron content of reduced pellets, and belongs to the technical field of metallurgical material analysis. The measurement method comprises the following steps: (1) taking reduced pellet samples, and sieving the reduced pellet samples through a sample sieve to obtain oversize samples and undersize samples; (2) measuring average mass fraction w1 of metallic iron in the oversize samples; (3) measuring average mass fraction w2 of metallic iron in the undersize samples; (4) calculating the average mass fraction w of the metallic iron in the reduced pellet samples. Submitted samples are partitioned into the oversize samples and undersize samples, the contents of the two parts of metallic iron are measured respectively, the contents of the metal iron in the two parts are measured separately, and the metallic iron content of the reduced pellet samples calculated by a weighted average value is proximate to an actual value, so that the defect that the metallic iron content of large-particle reduced pellets is difficult to measure accurately is overcome, and the method plays a role in guiding the feasibility and effect of subsequent process researches.

Description

technical field [0001] The invention belongs to the technical field of metallurgical material analysis, and in particular relates to a method for measuring the content of metallic iron in reduced pellets. Background technique [0002] Using the rotary hearth furnace to directly reduce the coal-based iron technology has less restrictions on the grade and mineral properties of iron-containing raw materials. It can make full use of the medium and low-grade iron ore that cannot be used in the blast furnace and many refractory iron ores. It can handle multi-element symbiotic mineral deposits, which is better adapted to and combined with the actual situation of my country's iron ore and coal resources. This process is one of the processes that can be considered for the development of my country's direct reduction technology. [0003] The total reserves of iron ore in western Hubei of my country are as high as 2.28 billion tons, but the ore in this place is oolitic hematite, which i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N31/16G01N5/00G01N1/28
CPCG01N1/286G01N5/00G01N31/16
Inventor 闻向东周郑夏念平张穗忠郑凤谢芬李江文李杰于录军潘菁杨艳
Owner 武汉钢铁有限公司