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A high-performance thermoplastic elastomer capable of bonding nylon and its preparation method

A thermoplastic elastomer and thermoplastic elasticity technology, which is applied in the field of polymer materials, can solve the problems of reducing the mechanical properties of thermoplastic elastomer compositions, reducing the adhesion between TPE alloy and nylon skeleton, and reducing mechanical properties and adhesion effects, and achieves bonding properties. Enhanced, inexpensive, and polarity-enhancing effects

Active Publication Date: 2019-02-15
NINGBO QINGHU ELASTOMER SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, Chinese patent application (publication number: CN103897321A) discloses a thermoplastic elastomer composition that can be used for coating nylon at low temperature. The composition of the patent application contains more plasticizers and fillers, which not only increases the production cost, but also greatly reduces the mechanical properties of the thermoplastic elastomer composition, and the application range is limited.
Another example is that the Chinese patent application (publication number: CN103554819A) discloses a TPE alloy used for nylon bonding and encapsulation. Although the elastomer component has good mechanical properties, in the actual application process, due to the plasticization of the component When the injection molding encapsulation, the small molecular plasticizer quickly enters the bonding interface layer, which reduces the bonding between the TPE alloy and the nylon skeleton to a certain extent; at the same time, the TPE alloy contains thermoplastic polyurethane material, which is resistant to Poor heat resistance, and the elastomer contains nylon components, which need to be molded at a higher temperature, which will cause the degradation of thermoplastic polyurethane materials, resulting in a decrease in mechanical properties and bonding effects
[0003] At present, there are many nylon-coated TPEs on the market, but they often have a good coating and bonding effect for a small number of nylon products, and rarely can achieve a good coating and bonding effect with most nylon products.

Method used

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  • A high-performance thermoplastic elastomer capable of bonding nylon and its preparation method
  • A high-performance thermoplastic elastomer capable of bonding nylon and its preparation method
  • A high-performance thermoplastic elastomer capable of bonding nylon and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Weigh the raw materials according to the components and weight percentages of the high-performance thermoplastic elastomers that can bond nylon described in Example 1 in Table 1, mix the raw materials in a high mixer, discharge and pour them into the feeder, and The feeder is fed into the twin-screw extruder, the screw speed of the twin-screw extruder is 200 rpm, the temperature is 240°C, extruded and granulated, and the granulated is dried at 90°C for 4 hours to remove thermoplastic elastomer particles The moisture in it can be made into high-performance thermoplastic elastomers by injection molding.

Embodiment 2

[0060] Weigh the raw materials according to the components and weight percentages of the high-performance thermoplastic elastomers that can bond nylon described in Example 2 in Table 1, mix the raw materials in a high-mixer, discharge and pour them into the feeder, and The feeder is fed into the twin-screw extruder, the screw speed of the twin-screw extruder is 300 rpm, the temperature is 180°C, extruded and granulated, and the granulated is dried at 100°C for 5 hours to remove thermoplastic elastomer particles The moisture in it can be made into high-performance thermoplastic elastomers by injection molding.

Embodiment 3

[0062] Weigh the raw materials according to the components and weight percentages of the high-performance thermoplastic elastomers that can bond nylon described in Example 3 in Table 1, mix the raw materials in a high mixer, discharge and pour them into the feeder, and The feeder is fed into the twin-screw extruder, the screw speed of the twin-screw extruder is 400 rpm, the temperature is 220°C, extruded and granulated, and the granulated is dried at 90°C for 6 hours to remove thermoplastic elastomer particles The moisture in it can be made into high-performance thermoplastic elastomers by injection molding.

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Abstract

The invention relates to high-performance thermoplastic elastomer composition for bonding nylon and a preparation method of the high-performance thermoplastic elastomer composition, and belongs to the technical field of high polymer materials. The high-performance thermoplastic elastomer composition is prepared from, by weight, 20%-60% of hydrogenated styrene type thermoplastic elastomer, 0%-20% of polyolefin elastomer, 10%-40% of polar resin, 5%-35% of a compatilizer, 5%-20% of a tackifier, 0%-10% of mineral filler and 0.1%-1% of an anti-aging agent. The invention further discloses the preparation method of the high-performance thermoplastic elastomer composition. According to the thermoplastic elastomer, by means of reasonable compatibility of the polar resin, the compatilizer, the tackifier and the like, usage of a plasticizer component which has great influences on the mechanical properties and the bonding effect of the material is avoided, the mechanical properties of the thermoplastic elastomer and the bonding effect of the thermoplastic elastomer and nylon can be effectively improved, and the thermoplastic elastomer has the good bonding effect on different types of nylon.

Description

technical field [0001] The invention relates to a high-performance thermoplastic elastomer composition for bonding nylon and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] Nylon (PA) is widely used in daily life due to its light weight, excellent mechanical properties and weather resistance. However, nylon is relatively hard and has a smooth surface. In some applications such as toys, kitchen utensils or handles of various tools, it will give Inconveniencing the user and reducing the comfort of the user. Thermoplastic elastomer (TPE) is a polymer material between rubber and thermoplastic. Noise, anti-slip, heat insulation and comfort improvement, so it is widely used in the coating of various plastics, such as PP, ABS, PC, PA and so on. For example, Chinese patent application (publication number: CN103897321A) discloses a thermoplastic elastomer composition that can be used for coating nylon at low tempera...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L53/02C08L23/08C08L23/10C08L77/00C08L67/00C08L51/00C08L51/06C08L77/02C08K13/02C08K3/26C08K3/34C08K3/36C08K5/134C08K5/526
CPCC08L53/025C08L2205/02C08L2205/035C08L23/0815C08L23/0869C08L23/10C08L77/00C08L67/00C08L51/006C08L51/06C08L77/02C08K13/02C08K2003/265C08K3/34C08K3/346C08K3/36C08K5/1345C08K5/526
Inventor 伍清浴史伟才
Owner NINGBO QINGHU ELASTOMER SCI & TECH