Lithium ion battery and anode plate thereof

A lithium-ion battery and anode sheet technology, which is applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of increased side reactions at the interface between electrodes and electrolytes, reduced anode electrode potential, and poor operability. Effects of irreversible capacity loss, improved energy density, and improved cycle performance

Inactive Publication Date: 2017-05-24
NINGDE AMPEREX TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although this method improves the first-week efficiency of lithium-ion batteries, it is easy to generate dust during the production process by using this method, which will cause harm to the human body, and adding lithium metal to the anode sheet of the lithium-ion battery reduces the electrode potential of the anode. Causes increased side reactions at the electrode-electrolyte interface, reducing efficiency and capacity during cycling
The Chin

Method used

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  • Lithium ion battery and anode plate thereof
  • Lithium ion battery and anode plate thereof

Examples

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preparation example Construction

[0023] The preparation method of the first lithium-ion battery anode sheet includes the steps of: dissolving the anode active material, a conductive agent, a binder, and a lithium-containing compound in a solvent, stirring to obtain an anode slurry, and then uniformly coating the anode slurry on On the anode current collector, the lithium ion battery anode sheet is obtained after drying; wherein, the anode slurry is dried to form an anode active material layer. At this time, the lithium-containing compound may exist anywhere on the outer surface and inside of the anode active material layer.

[0024]In the first preparation method of lithium ion battery anode sheet, the solvent may be 1-methyl-2-pyrrolidone.

[0025] The preparation method of the second lithium-ion battery anode sheet includes the steps of: dissolving the anode active material, the conductive agent, and the binder in a solvent, stirring to obtain the anode slurry, and then uniformly coating the anode slurry on...

Embodiment 1

[0041] (1) Lithium nitride, graphite, acetylene black, sodium carboxymethyl cellulose, and styrene-butadiene rubber emulsion are dissolved in solvent 1-methyl-2-pyrrolidone in a weight ratio of 0.5:93.5:2:2:2. A uniform anode slurry is obtained by stirring, and then the anode slurry is evenly coated on the copper foil of the anode current collector, and the anode sheet of the lithium ion battery is obtained after drying, cold pressing, and slitting.

[0042] (2) Lithium manganate, acetylene black, and polyvinylidene fluoride are dissolved in the solvent 1-methyl-2-pyrrolidone in a weight ratio of 96:2:2, and a uniform cathode slurry is obtained by stirring, and then the cathode slurry is The material is evenly coated on the aluminum foil of the cathode current collector, and the cathode sheet of the lithium ion battery is obtained after drying, cold pressing and slitting.

[0043] (3) The lithium-ion battery anode sheet, lithium-ion battery cathode sheet, and PP / PE / PP three-la...

Embodiment 2

[0045] Lithium-ion batteries were made according to the method of Example 1, except for the following differences:

[0046] In step (1), the weight ratio of lithium nitride, graphite, acetylene black, sodium carboxymethyl cellulose, and styrene-butadiene rubber is 5:89:2:2:2.

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Abstract

The invention provides a lithium ion battery and an anode plate thereof. The anode plate of the lithium ion battery comprises an anode current collector and an anode active substance layer applied on the anode current collector, wherein the anode active substance layer comprises an anode active material, a conducting agent and a bonding agent; the anode active substance layer also comprises a lithium-containing compound; the general formula of the lithium-containing compound is Li<3-x>AxN<1-y>Dy; before the formation of the lithium ion battery prepared by using the anode plate of the lithium ion battery, the lithium ion battery is firstly subjected to precharging so as to decompose the lithium-containing compound. The anode plate of the lithium ion battery can reduce the inreversible volume loss of the first cycle circulation of the lithium ion battery; the energy density of the lithium ion battery is improved; the side reaction in the charging and discharging process is reduced; the circulation performance of the lithium ion battery is improved.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a lithium ion battery and its anode sheet. Background technique [0002] Lithium-ion batteries are widely used in portable devices such as notebooks and mobile phones, and are also considered to be the key technology for next-generation vehicles. Almost all car manufacturers have launched one or more electric drive vehicles. Although lithium-ion batteries have many advantages, such as high voltage and long life, and have broad prospects in the automotive field, the energy density of lithium-ion batteries cannot meet the requirements of electric vehicles for lithium-ion batteries. [0003] Lithium-ion batteries usually use graphite, silicon, etc. as the anode active material. During the first charging process of lithium-ion batteries, when the electrode potential (vs. Li / Li+) of the anode is lower than 0.8V, the lithium ions released from the cathode will be consumed...

Claims

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Application Information

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IPC IPC(8): H01M4/485H01M4/505H01M4/525H01M4/58H01M10/0525
CPCH01M4/485H01M4/505H01M4/525H01M4/58H01M4/581H01M4/582H01M4/5825H01M10/0525Y02E60/10
Inventor 唐代春闫传苗钟开富
Owner NINGDE AMPEREX TECH
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