Method for controlling stickies deposition in pulp and papermaking process

A sticky matter, pulping technology, applied in the direction of preventing corrosion/deposit formation of pulping equipment, textiles and papermaking, pulping with organic compounds, etc., can solve problems such as limited types

Active Publication Date: 2022-01-11
NOPCO PAPER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These changes may also limit the types of techniques available to overcome problems caused by stickies deposition

Method used

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  • Method for controlling stickies deposition in pulp and papermaking process
  • Method for controlling stickies deposition in pulp and papermaking process
  • Method for controlling stickies deposition in pulp and papermaking process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Example 1 - "Mill A"

[0057] Mill A is an integrated paper machine for the production of printing grade paper using recycled grade paper as furnish.

[0058] Deinked pulp (DIP) for newsprint is produced using a common dual loop RCF (Regenerated Fiber) unit.

[0059] Raw materials consisted of standard household quality ONP and OMG (old newsprint and magazine grade, respectively). The treatment temperature is 40-50°C, the water hardness is 10-30odH, and the pH is 7-9.

[0060] In the DIP unit, use NaOH (caustic soda), water glass (silicate) and H 2 o 2(peroxide) for ink detachment and to prevent ink redeposition and yellowing. In addition, sodium soap is added in the pre-flotation circuit and post-flotation circuit for ink removal. Due to the hardness of the water, the soap is at least partially converted to calcium soap. Soap was incorporated in an amount of 2-3 kg / ton (calculated as fatty acid per ton dry discharge from pulper / drum).

[0061] The amount of hy...

Embodiment 2

[0069] Example 2 - "Mill B"

[0070] Mill B is a dual loop RCF unit to produce DIP for newsprint production. The composition of ingredients included standard household quality ONP and OMG.

[0071] Again the same chemical mixture containing caustic, silicate and peroxide is used for ink stripping and to prevent ink redeposition and yellowing.

[0072] Again, in addition to this chemical mixture, sodium soaps that convert to calcium soaps due to water hardness are added for ink removal in the pre and post flotation circuits.

[0073] The treatment temperature is 45-50°C, the water hardness is 10-30odH, and the pH value is 7-9.

[0074] To assess the presence of sticky-forming deposits on surfaces in processing systems by studying the amount of hydrophobic micro-stickies present in RCF units and at various locations in the wet end of a paper machine by flow cytometry possibility.

[0075] During the reference period, 1.5 kg sodium soap / ton (as fatty acid) was added to the ...

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PUM

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Abstract

The present invention relates to a method for controlling stickies deposition in pulping and papermaking processes, the method comprising adding to fibrous pulp or paper stock an additive comprising an organomodified siloxane, the organomodified siloxane Oxanes contain units of the formula: [R 1 a Z b SiO (4‑a‑b) / 2 ] n ; where each R 1 independently selected from a hydrogen atom, an alkyl group, an aryl group, an alkenyl group, an aralkyl group, an alkaryl group, an alkoxy group, an alkanoyloxy group, a hydroxyl group, an ester group or an ether group; each Z is independently selected from an amino group , amide, carboxyl, ester or epoxy substituted alkyl, or preferably at least one or more groups-R 2 -(OC p h 2p ) q (OC r h 2r ) s -R 3 ; wherein n is an integer greater than 1; a and b are independently 0, 1, 2 or 3; R 2 is an alkylene group or a direct bond; R 3 is the above for R 1 Or the group defined by Z; p and r are independently an integer of 1 to 6; q and s are independently 0 or 1 <q+s<400成立的整数;并且其中所述有机改性硅氧烷的各个分子含有至少一个基团z。所述有机改性硅氧烷优选是被羟基或烷基封端的线性聚二甲基硅氧烷,其中5~18摩尔%的硅原子被式‑r2‑(OC p h 2p ) q (OC r h 2r ) s -R 3 Z group substitution, wherein p is 2, r is 3, q ​​and s are independently 10 to 20, R 2 is an alkylene group or a direct bond having 1 to 6 carbon atoms, and R 3 It is a hydrogen atom or a hydroxyl group, an alkoxy group, an ester group or an ether group.

Description

technical field [0001] The present invention relates to a method for controlling sticky deposition in pulp and papermaking processes. Background technique [0002] The problems associated with the formation of sticky deposits (comprising both inorganic and organic components) in pulp and papermaking processes are well known. "Pitch", "stickies" and "white-pitch" are terms commonly used for the sticky hydrophobic material produced in these processes that mechanically adheres to surfaces and forms aggregates body. [0003] In pulping processes using virgin fibers, "bitumen" generally refers to a natural resinous hydrophobic material comprising fatty acids, esters and sterols derived from natural raw materials, most often wood. Bitumen is particularly prevalent in the mechanical grade pulps commonly used for recycled paper, where it undergoes hydrolytic degradation and saponification to a lesser extent than the alkaline kraft process used to make chemical pulps. [0004] Pap...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21C3/00D21C5/02D21C9/08D21H17/13D21H17/59
CPCD21C3/003D21C5/022D21C9/08D21H17/13D21H17/59Y02W30/64D21C9/008
Inventor B·布拉辛格S·弗里德里斯查克B·内勒森A·申克尔
Owner NOPCO PAPER TECH
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