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A kind of graphene polysaccharide modified cigarette filter that selectively intercepts benzene ring harmful substances and preparation method thereof

A harmful substance and graphene technology, which is applied in the fields of e-liquid filter elements, tobacco, food science, etc., can solve the problems of affecting the adsorption performance of materials, poor water solubility, and easy aggregation of graphene/chitosan solutions

Active Publication Date: 2020-10-30
湖北特斯特乐新材料科技有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method disclosed in this patent is simple, but due to its special structure, graphene is directly dispersed in water and easily aggregates. At the same time, due to the influence of the degree of deacetylation, chitosan has poor water solubility, and acetic acid solution is used as a solvent during use. The resulting graphene / chitosan solution is prone to aggregation, which affects the selective adsorption performance of the material.

Method used

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  • A kind of graphene polysaccharide modified cigarette filter that selectively intercepts benzene ring harmful substances and preparation method thereof
  • A kind of graphene polysaccharide modified cigarette filter that selectively intercepts benzene ring harmful substances and preparation method thereof
  • A kind of graphene polysaccharide modified cigarette filter that selectively intercepts benzene ring harmful substances and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031]Graphene oxide: the first step pre-oxidation, take 30g of concentrated sulfuric acid and add it to a 500g three-necked flask, then weigh 5g of potassium persulfate and slowly add it to the concentrated sulfuric acid, then add 5g of phosphorus pentoxide, and heat up to 80°C , then add 3g of graphite powder, react for 6h, filter and wash to neutrality after the reaction, and then bake in a vacuum drying oven at 60 °C for 3h to obtain pre-oxidized graphene; for secondary oxidation, measure 200g of concentrated sulfuric acid and add it to In a 500ml three-necked flask, place it in an ice bath at 0°C, slowly add pre-oxidized graphene, then add 30g of potassium permanganate, heat up to 35°C for 3h, then slowly add 250g of distilled water, and finally heat up to 95 ℃ Stir for 15min, then add the reaction solution and transfer it to a 1000ml beaker, then add 600g of deionized water, then add 6g of 30% hydrogen peroxide, then filter, wash with 10% hydrochloric acid and deionized w...

Embodiment 2

[0038] The reduced graphene oxide and water-soluble polysaccharide were prepared according to the method of Example 1.

[0039] The reduced graphene oxide was dispersed in water by ultrasonic method, and the concentration of reduced graphene oxide was 3 mg / ml to form a uniform and stable aqueous dispersion, and then 1000 g of water-soluble polysaccharide was added to the aqueous solution of oxidized 200 g of graphene. , the concentration of water-soluble polysaccharide is 2mg / ml, and after ultrasonic for a period of time, a stable and uniform graphene / water-soluble polysaccharide dispersion is formed.

[0040] The filter fiber was pre-treated, and then the filter fiber was soaked in the graphene / water-soluble polysaccharide dispersion. The soaking temperature was maintained at 50 °C for 2 hours. After soaking, the soaked filter fiber was placed After drying in a vacuum oven at 80°C for 8 h, filter fibers modified by graphene / water-soluble polysaccharide complexes were prepared...

Embodiment 3

[0043] The reduced graphene oxide and water-soluble polysaccharide were prepared according to the method of Example 1.

[0044] Disperse the reduced graphene oxide in water by ultrasonic method, the concentration of the reduced graphene oxide is 1 mg / ml to form a uniform and stable aqueous dispersion, and then add 1000 g of water-soluble polysaccharide to the aqueous solution of 200 g of graphene oxide , the concentration of water-soluble polysaccharide is 1 mg / ml, and after ultrasonic for a period of time, a stable and uniform graphene / water-soluble polysaccharide dispersion is formed.

[0045] The filter fiber was pre-treated, and then the filter fiber was soaked in the graphene / water-soluble polysaccharide dispersion. The soaking temperature was maintained at 50 °C for 2 hours. After soaking, the soaked filter fiber was placed After drying in a vacuum oven at 80°C for 8 h, filter fibers modified by graphene / water-soluble polysaccharide complexes were prepared.

[0046] A c...

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Abstract

A preparation method of a graphene polysaccharide-modified cigarette filter capable of selectively intercepting benzene-ring harmful substances is characterized in that all agents used herein are by weight, and the method comprises the steps of (1) preparing graphene oxide; (2) reducing the graphene oxide; (3) preparing water-soluble polysaccharide; (4) preparing reduced graphene oxide / water-soluble polysaccharide; (5) modifying with acetate fiber. The cigarette filter prepared herein is capable of significantly lowering tar to decease damage and improving cigarette quality, can provide mellow taste, allows the benzene-ring harmful substances in smoke, such as 3,4- benzopyrene and phenols to be decreased by 45-65%, and enables the harm of the substances to be further lowered based on existing cigarette quality.

Description

technical field [0001] The invention belongs to a cigarette filter material, and in particular relates to a graphene polysaccharide modified cigarette filter which selectively intercepts benzene ring harmful substances and a preparation method thereof. Background technique [0002] In recent years, under the active promotion of the World Health Organization (WHO), many national governments and various anti-smoking groups, the global anti-smoking movement has been rising day by day, and the tobacco industry has been under increasing social pressure. The Framework Convention on Tobacco Control formulated by WHO and signed by governments of member states not only stipulates that governments should take and implement effective legislative, administrative and other measures to prevent and reduce tobacco consumption, nicotine addiction and exposure to tobacco smoke, etc. , but also requires restrictions on the content of tobacco products. At present, some major developed countrie...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A24D3/14
CPCA24D3/14
Inventor 黄乐平王罗新赵瑾朝
Owner 湖北特斯特乐新材料科技有限责任公司
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