A kind of graphene polysaccharide modified cigarette filter that selectively intercepts benzene ring harmful substances and preparation method thereof
A harmful substance and graphene technology, which is applied in the fields of e-liquid filter elements, tobacco, food science, etc., can solve the problems of affecting the adsorption performance of materials, poor water solubility, and easy aggregation of graphene/chitosan solutions
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Embodiment 1
[0031]Graphene oxide: the first step pre-oxidation, take 30g of concentrated sulfuric acid and add it to a 500g three-necked flask, then weigh 5g of potassium persulfate and slowly add it to the concentrated sulfuric acid, then add 5g of phosphorus pentoxide, and heat up to 80°C , then add 3g of graphite powder, react for 6h, filter and wash to neutrality after the reaction, and then bake in a vacuum drying oven at 60 °C for 3h to obtain pre-oxidized graphene; for secondary oxidation, measure 200g of concentrated sulfuric acid and add it to In a 500ml three-necked flask, place it in an ice bath at 0°C, slowly add pre-oxidized graphene, then add 30g of potassium permanganate, heat up to 35°C for 3h, then slowly add 250g of distilled water, and finally heat up to 95 ℃ Stir for 15min, then add the reaction solution and transfer it to a 1000ml beaker, then add 600g of deionized water, then add 6g of 30% hydrogen peroxide, then filter, wash with 10% hydrochloric acid and deionized w...
Embodiment 2
[0038] The reduced graphene oxide and water-soluble polysaccharide were prepared according to the method of Example 1.
[0039] The reduced graphene oxide was dispersed in water by ultrasonic method, and the concentration of reduced graphene oxide was 3 mg / ml to form a uniform and stable aqueous dispersion, and then 1000 g of water-soluble polysaccharide was added to the aqueous solution of oxidized 200 g of graphene. , the concentration of water-soluble polysaccharide is 2mg / ml, and after ultrasonic for a period of time, a stable and uniform graphene / water-soluble polysaccharide dispersion is formed.
[0040] The filter fiber was pre-treated, and then the filter fiber was soaked in the graphene / water-soluble polysaccharide dispersion. The soaking temperature was maintained at 50 °C for 2 hours. After soaking, the soaked filter fiber was placed After drying in a vacuum oven at 80°C for 8 h, filter fibers modified by graphene / water-soluble polysaccharide complexes were prepared...
Embodiment 3
[0043] The reduced graphene oxide and water-soluble polysaccharide were prepared according to the method of Example 1.
[0044] Disperse the reduced graphene oxide in water by ultrasonic method, the concentration of the reduced graphene oxide is 1 mg / ml to form a uniform and stable aqueous dispersion, and then add 1000 g of water-soluble polysaccharide to the aqueous solution of 200 g of graphene oxide , the concentration of water-soluble polysaccharide is 1 mg / ml, and after ultrasonic for a period of time, a stable and uniform graphene / water-soluble polysaccharide dispersion is formed.
[0045] The filter fiber was pre-treated, and then the filter fiber was soaked in the graphene / water-soluble polysaccharide dispersion. The soaking temperature was maintained at 50 °C for 2 hours. After soaking, the soaked filter fiber was placed After drying in a vacuum oven at 80°C for 8 h, filter fibers modified by graphene / water-soluble polysaccharide complexes were prepared.
[0046] A c...
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