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A preparation method of cigarette paper with combustion-supporting and CO emission-reducing functions

A technology of cigarette paper and combustion enhancer, which is applied in special paper, textiles, papermaking, papermaking, etc. It can solve the problems of dim color of ash and high CO emissions, and achieve fast smoldering speed, reduced CO emissions, and good appearance

Active Publication Date: 2020-04-21
QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cigarette paper obtained in the above-mentioned prior art still has problems such as high CO emission, dim color of ashes after burning, etc.

Method used

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  • A preparation method of cigarette paper with combustion-supporting and CO emission-reducing functions
  • A preparation method of cigarette paper with combustion-supporting and CO emission-reducing functions
  • A preparation method of cigarette paper with combustion-supporting and CO emission-reducing functions

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preparation example Construction

[0035] In step 3) of the preparation method according to the present invention, the pure plant nano-combustible agent dispersion liquid prepared in step 2) is added to the slurry for making cigarette paper to make cigarette paper, and the consumption of pure plant nano-combustible agent is absolutely 0.01%-8% of the dry pulp mass, preferably 1-3%. If the dosage is too low, the effect will not be obvious. If the dosage is too high, the retention rate of the nanofiber combustion accelerant will be reduced, and the air permeability of the cigarette paper made will be too low, which will affect the combustion and increase the CO emission. This may be because, if the amount is too much, there will be too much negative charge in the pulp, which will make it difficult for the nano-combustion aid to stay on the pulp. A part of the loss leads to a corresponding decrease in the retention rate.

[0036] In step 4) of the preparation method according to the present invention, the pure pl...

Embodiment 1

[0040] 1 g of bleached softwood pulp was added to 50 mL of 64 wt % concentrated sulfuric acid, and reacted at 45° C. for 1 hour. After the reaction is over, put the reaction container in an ice bath to terminate the reaction, then transfer the mixed solution into a centrifuge tube, centrifuge at 8000rpm for 5min and wash it repeatedly for 6 times, then use dialysis to remove the residual acid, and prepare it after the pH value is constant. Obtain pure plant nano-combustion-supporting agent, then it is formulated into 0.6wt% dispersion liquid. On the coating machine, the dispersion liquid prepared for cigarette paper papermaking is carried out on one side (coating amount is 0.4g / m 2 ), followed by vacuum drying to obtain a modified cigarette paper product. The strength of the cigarette paper prepared by the method in this example increased from 1.09kN / m of the blank sample to 1.21kN / m, the smoldering speed of 10cm decreased from 61.25s to 49.35s, and the strength of the treate...

Embodiment 2

[0042] 1 g of bleached hardwood pulp was added to 75 mL of 80 wt % citric acid solution, and stirred and reacted at 150° C. for 3 hours. After the reaction, the reaction mixture was centrifuged at 8000 rpm for 8 min and washed with water three times repeatedly, and the washed mixture was further removed by dialysis to remove water-soluble residues. After dialysis, the solid-liquid mixture was homogenized under 60Mpa high pressure for 10 times to further improve the stability of its aqueous suspension and the uniformity of nanofibers, thereby obtaining a nanofiber combustion accelerant, which was then formulated into a 0.8wt% dispersion. On the coating machine, the dispersion liquid prepared for cigarette paper papermaking is carried out on one side (coating amount is 0.5g / m 2 ), followed by vacuum drying to obtain a modified cigarette paper product. The strength of the cigarette paper treated by the method in this example increased from 1.08kN / m of the blank sample to 1.16kN / ...

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Abstract

The invention relates to a preparation method for cigarette paper with functions of supporting combustion and reducing a CO emission amount. The preparation method comprises the following steps: processing a cellulose raw material by combining a chemical method and a high-pressure homogenizing method to prepare a pure plant nano-fibre combustion supporting agent (functional nano-fibres); then, mixing the obtained nano-fibre combustion supporting agent and pulp of papermaking cigarette paper, or performing coating / sizing the nano-fibre combustion supporting agent dispersing solution on the surface of commercial cigarette paper to prepare nano-fibre combustion supporting agent-modified cigarette paper. The cigarette paper which is modified through the pure plant nano-fibre combustion supporting agent provided by the invention has good functions of supporting the combustion and reducing the CO emission amount; the prepared cigarette paper has higher smoldering velocity compared with thatof common cigarette paper; the CO emission amount is remarkably reduced; combusted ash is grey; the cigarette paper is good in appearance, can be used producing high-quality cigarette, and can reducethe damage to human body health.

Description

technical field [0001] The invention relates to the field of special paper production, in particular to a method for preparing cigarette paper with the functions of supporting combustion and reducing CO emissions. Background technique [0002] In recent years, people have paid great attention to the impact of smoking on their health, and improving the safety of smoking has become a global concern. Cigarettes include shredded tobacco and cigarette paper, and the temperature in the high-temperature zone of combustion is about 700-900°C (Carbohydrate Polymers, 2014, 101, 769-775). During the burning process of cigarettes, a series of chemical reactions such as oxidation, pyrolysis, and polymerization will occur, and the incomplete combustion and dry distillation of its organic components will form tar and other harmful substances (such as CO, etc.) (BioResources, 2013, 8, 1517- 1519). Therefore, the composition and content of cigarette smoke are not only closely related to th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H27/00D21F1/00D21H23/04D21H23/22D21H21/06
CPCD21F1/00D21H21/06D21H23/04D21H23/22D21H27/00
Inventor 李滨刘超牟新东张跃冬于光
Owner QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI