An electrolytic membrane valve and its manufacturing method
A manufacturing method and electrolytic membrane technology, applied in valve devices, mechanical equipment, engine components, etc., can solve problems such as interference with the passage efficiency of electrolytic microchannels, and achieve the effect of ensuring passage efficiency and avoiding air bubbles
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Embodiment 1
[0038] Such as Figure 5 Shown, the effect of voltage on the rupture of 400nm Au films in different conductive media.
[0039]A gold film with a thickness of 400 nm and a diameter of 1.4 mm was used as a valve film in conjunction with an electrode with a mixture of silver and carbon ink (50% w / w). Prepare NaCl conductive media by adding 0.4 M NaCl to PBS buffer. Prepare CsCl conductive media by adding 0.4 M CsCl to PBS buffer. Different voltages of 3, 4 and 5 volts were applied across electrodes consisting of 50% carbon ink. In the presence of each conductive medium, 50% silver ink corroded the gold film, and the average time for film rupture of each conductive medium was measured.
[0040] As a result, as shown in Table 1 below, when the concentration of sodium or cesium ions was increased, the corrosion of the conductive film was improved. At 3 volts, the effect of both ions was similar, however, the accelerated corrosion of the film was more pronounced for cesium as hig...
Embodiment 2
[0044] Such as Figure 6 Shown, the effect of applied voltage on the rupture of 7.2 μm Al film in different conductive media.
[0045] An aluminum film with a thickness of 7.2 μm and a diameter of 1.4 mm was used as a valve film in conjunction with an electrode composed of a mixture of silver and carbon ink (50% w / w). Prepare NaCl conductive media by adding 0.4 M NaCl to PBS buffer. Prepare CsCl conductive media by adding 0.4 M CsCl to PBS buffer. In the presence of each conductive medium, different voltages of 3, 4, and 5 volts were applied through the electrodes to etch the aluminum film, and the average time for film rupture of each conductive medium was measured. The results are shown in Table 2 below.
[0046] Voltage (V) CsC(min) NaCl(min) PBS 3 7.4 7.6 12 4 3.01 4.31 6 5 1.01 2.53 4
[0047] Table 2
[0048] From the results, it can be seen that increasing the concentration of sodium or cesium ions shows improved film corros...
Embodiment 3
[0050] Such as Figure 7 Shown, at 4V, the effect of CsCl concentration on the rupture of 7.2μm Al and 400nm Au films.
[0051] An aluminum film with a thickness of 7.2 μm and a gold film with a thickness of 400 nm each having a diameter of 1.4 mm were used as a conductive film in combination with an electrode comprising screen-printed carbon ink for aluminum and silver and carbon for gold Mixture for screen printing of ink (50% w / w). Conductive CsCl media with different ionic strengths were prepared by adding 0.2 M to 0.6 M CsCl to PBS buffer. In the presence of the conductive medium at each different CsCl concentration, a fixed voltage of 4 volts was applied across the electrodes to etch the film, and the average time to film rupture was measured. The results are shown in Table 3 below.
[0052] Au Al CsCl concentration (M) Burst time (min) Burst time (min) 0.2 3.51 1.6 0.4 1.84 1.19 0.6 1.68 1.18
[0053] table 3
[0054] Fro...
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