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A method for treating acid-containing waste water produced in the production process of acidified oil

A technology of production process and treatment method, applied in the field of wastewater treatment, can solve the problems of no treatment process, miscellaneous salts, difficult treatment, etc., and achieve the effect of easy post-treatment

Active Publication Date: 2020-08-04
铁岭金铎科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The acid-containing wastewater produced in the production process of acidified oil has the characteristics of "four highs" of high salt, high acid, high COD (chemical oxygen demand), and high color. Therefore, there is no mature treatment process at present, and most enterprises cannot handle it. , only a small number of enterprises try to use the method of MVR concentration and evaporation and the method of cultivating salt-tolerant bacteria for a small amount of treatment
Among them, the main problem in the process of MVR concentration and evaporation is that there is a lot of concentrated liquid, and the concentrated liquid belongs to saturated salt solution, and it is miscellaneous salt, which is very difficult to handle.

Method used

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  • A method for treating acid-containing waste water produced in the production process of acidified oil

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] The acid-containing wastewater produced in the production process of acidified oil is subjected to oil-separation treatment to obtain the oil-separated wastewater; the temperature of the oil-separated wastewater is adjusted to 26°C, and the mass concentration is 10% calcium oxide suspension for neutralization for 1 hour , adjust the pH of the neutralized sewage to 9, and then filter through the plate and frame filter press. After the filter, the filtrate passes through the concentrated evaporator and runs for 45 days. The treated water volume is 6.5m 3 / h (without pretreatment, the processing capacity is 6m 3 / h), the current of the forced circulation pump is kept at 133-135A, and the COD of the distillate after evaporation is 700-770mg / L. The concentrated evaporated distillate enters the aerobic tank for aerobic treatment. After two days of testing, it reaches the emission standard. The COD is 25-30mg / L, the total phosphorus (TP) is 0.3mg / L, and the SO 4- It is 12-20m...

Embodiment 2

[0061] The acid-containing wastewater produced in the production process of acidified oil is subjected to oil-separation treatment to obtain the oil-separated wastewater; the temperature of the oil-separated wastewater is adjusted to 30°C, and the pH is adjusted to 8.5 through 10% calcium oxide suspension, and stirred for half an hour , add 10% polyaluminum chloride solution, the addition amount is 5% of the sewage, stir at a slow speed for half an hour, press filter through a plate and frame filter press, and evaporate the filtrate through a concentrated evaporator, and the COD of the distillate after evaporation is 700 ~750mg / L, running for 50 days, the water treatment volume per hour is 6.5m 3 , Forced circulation pump current is 132 ~ 133A. The concentrated evaporated distillate enters the aerobic tank for aerobic treatment. After two days of testing, it reaches the emission standard. The COD is 25-30mg / L, the total phosphorus (TP) is 0.1-0.3mg / L, and the SO 4- The concen...

Embodiment 3

[0063] The acid-containing wastewater produced in the production process of acidified oil is subjected to oil-separation treatment to obtain oil-separated wastewater; the temperature of the oil-separated wastewater is adjusted to 22°C, and the pH is adjusted to 8.2-8.8 through 12% calcium oxide suspension, and stirred Half an hour, add mass concentration and be 5% polyaluminum chloride solution, the addition is 5% of sewage quality, stir at a slow speed for half an hour, then add the PAM solution that mass concentration is 2‰, addition is 1% of sewage quality, Continue to stir at a slow speed for 20 minutes, press filter through a plate and frame filter press, and evaporate the filtrate through a concentrated evaporator. 3 , Forced circulation pump current is 132 ~ 133A. The concentrated evaporated distillate enters the aerobic tank for aerobic treatment. After two days of testing, it reaches the emission standard. The COD is 20-25mg / L, the total phosphorus (TP) is 0.1-0.2mg / L...

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Abstract

The invention provides a treatment method of acid-containing wastewater generated in a production process of acidic oil and belongs to the technical field of treatment of sewage. The treatment methodcomprises the following steps: introducing wastewater generated by production of acidic oil into an oil separation tank and separating out an oil layer to obtain the wastewater after oil separation; adjusting the pH value of the wastewater after oil separation to be 8-10 by using a calcium oxide suspension solution, and neutralizing and flocculating to obtain neutralized and flocculated wastewater; concentrating and evaporating the neutralized and flocculated wastewater to obtain distillation liquid; and carrying out aerobic treatment of the distillation liquid to obtain liquid which reaches the discharge standard. According to the treatment method, a process of neutralizing and flocculating the wastewater through the calcium oxide suspension solution is adopted before evaporating the wastewater, so that the organic matters and the salts in the wastewater entering a forced-circulation evaporator are obviously reduced; compared with the untreated wastewater, the concentrated liquid of the treated wastewater is obviously reduced.

Description

technical field [0001] The invention relates to the technical field of sewage treatment, in particular to a treatment method for waste water produced in the production process of acidified oil. Background technique [0002] Acidified oil refers to the oil obtained by acidifying the by-product soapstock produced in oil refineries. Acidified oils are essentially fatty acids that contain pigments as well as unacidified triglycerides, diglycerides, and monoglycerides (neutral oils). [0003] The acid-containing wastewater produced in the production process of acidified oil has the characteristics of "four highs" of high salt, high acid, high COD (chemical oxygen demand), and high color. Therefore, there is no mature treatment process at present, and most enterprises cannot handle it. , only a small number of enterprises try to use the method of MVR concentration and evaporation and the method of cultivating salt-tolerant bacteria for a small amount of treatment. Among them, th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/14C02F101/10C02F101/30C02F101/34C02F103/36
CPCC02F1/04C02F1/40C02F1/5236C02F1/56C02F1/66C02F3/02C02F9/00C02F2101/101C02F2101/105C02F2101/30C02F2101/34C02F2103/36
Inventor 程娟张宝玉马献力陈刘杨高峰
Owner 铁岭金铎科技股份有限公司