Cross-flow mobile device and method for continuous production of sulfur from sulfur dioxide
A sulfur dioxide and mobile device technology, applied in chemical instruments and methods, preparation/purification of sulfur, inorganic chemistry, etc., can solve problems such as the difficulty in realizing the industrial production of sulfur dioxide from sulfur dioxide, achieve easy industrial implementation, continuous separation, and reduce airflow resistance Effect
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Embodiment 1
[0046] use figure 1 The shown device performs catalytic reduction reaction in the way of sulfur dioxide-containing flue gas and reducing gas in cross-flow contact with the catalyst, and continuously separates sulfur-containing gas from the catalyst while the catalytic reduction reaction proceeds to obtain sulfur.
[0047] The main components of sulfur dioxide-containing flue gas are shown in Table 1.
[0048] Table 1
[0049] components water vapor carbon dioxide sulfur dioxide weight percentage 22.5% 15% 5%
[0050] The catalyst is a commercial shaped block activated carbon, the residence time of the flue gas containing sulfur dioxide in the reaction zone 16 is 4-6s, and the continuous slow moving speed of the catalyst is 0.1-0.5m / s; the catalyst inlet 03 and the catalyst outlet 05 Nitrogen protection is used; the reaction temperature in the reaction zone 16 is 650-700°C; the thickness of the catalyst along the flow direction of sulfur dioxide-co...
Embodiment 2
[0053] The residence time of the sulfur dioxide-containing flue gas in the reaction zone 16 is 7-10 s, and the flow resistance of the sulfur dioxide-containing flue gas is between 100-600 Pa. Others are the same as in Embodiment 1. The concentration of sulfur dioxide at the outlet was detected by a gas chromatography-mass spectrometer, and the conversion rate of sulfur dioxide was calculated to be 84%.
Embodiment 3
[0055] The residence time of the sulfur dioxide-containing flue gas in the reaction zone 16 is 12-15 s, the flow resistance of the sulfur dioxide-containing flue gas is between 100-400 Pa, and the others are the same as in Embodiment 1. The concentration of sulfur dioxide at the outlet was detected by a gas chromatography-mass spectrometer, and the conversion rate of sulfur dioxide was calculated to be 86%.
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