697 results about "Sulfur oxide" patented technology

The invention discloses an instrument for detecting sulfur dioxide residue in traditional Chinese medicine, and relates to the technical field of traditional Chinese medicine detection, the instrument comprises a main machine, and also comprises a distillation flask arranged at the top of the main machine and used for containing a sample to be detected; the condensation assembly is arranged at the top of the distillation flask and comprises a condensation pipe and a sleeve, and the sleeve is fixedly arranged in the condensation pipe and divides the condensation pipe into a water passing cavity and a condensation cavity. The condensation cavity is divided into the upper condensation section and the lower condensation section through the separation part, heat can be effectively prevented from spreading to the whole condensation cavity, a certain temperature difference is kept between the upper condensation section and the lower condensation section, it is ensured that gas subjected to primary condensation can be effectively condensed on the upper condensation section, and therefore the condensation effect on distilled gas is improved; the hydrochloric acid component doped in the gas can be further reduced through twice condensation, the hydrochloric acid component is prevented from entering the absorption bottle along with nitrogen and sulfur dioxide to influence the absorption liquid, and the detection accuracy is improved.

The invention relates to the technical field of coal-fired power plant environmental protection, in particular to a coal-fired power plant intelligent environmental protection island control system based on multi-source data fusion. Comprising a multi-source data acquisition module, a data transmission module, a data preprocessing module, a multi-source data fusion module, an operation state analysis module, an intelligent control decision module, a control instruction execution module and a man-machine interaction module. According to the coal-fired power plant intelligent environmental protection island control system based on multi-source data fusion, equipment operation, environmental monitoring, power grid, fuel and meteorological data are widely acquired through the multi-source data acquisition module, the limitation of a single data source of a traditional system is broken through, a distributed Kalman filtering algorithm is combined with a neural network algorithm for data fusion, and the data fusion efficiency is improved. According to the method, the incidence relation between data can be deeply mined, temperature and pressure parameters of desulfurization equipment and flue gas sulfur dioxide concentration data are subjected to fusion analysis, the reason of desulfurization efficiency reduction can be accurately positioned, and compared with traditional single data source judgment, the fault diagnosis accuracy is improved.

The invention discloses a method for preparing high-purity manganese sulfate and co-producing manganese dioxide for a battery by reducing manganese oxide ore with sulfur dioxide, metal smelting SO2-containing flue gas or sulfur acid-making industry SO2 gas is used as a reducing agent, discharged tail gas after absorption can be as low as 30 mg / m < 3 > or below, and the leaching rate of manganese element can reach 98% or above. By adopting the technical scheme of the process, the comprehensive recovery rate of manganese is easy to achieve more than 95%, and two high-value products of high-purity MnSO4 and MnO2 for batteries are produced; s2O6 < 2-> is decomposed and removed in the same reaction kettle by adopting a high-temperature oxidation process to obtain a manganese sulfate solution and co-produce a high-quality MnO2 product suitable for batteries; a speed-controlled crystallization method is adopted for high-temperature crystallization, the one-time crystallization separation and purification rate of impurity ions such as magnesium, calcium, potassium and sodium is stably increased from 70-80% to 90% or above, and the purpose of obtaining a battery-grade high-purity manganese sulfate product through two times of recrystallization is achieved.

The invention belongs to the technical field of masonry cement, and particularly discloses all-solid-waste low-carbon-emission masonry cement and a preparation method thereof. Comprising the following steps: 1, finely grinding iron tailings, carbide slag, fly ash and silica fume, and proportioning according to a design to obtain a cement raw material; 2, agglomerating or pelletizing the cement raw material, and calcining according to a designed temperature to obtain a cement clinker; and 3, mixing the cement clinker with a certain proportion of gypsum, and grinding to the target fineness to obtain the masonry cement. The masonry cement is prepared from all solid wastes, meanwhile, a calcium source is mainly provided by the carbide slag with low carbon emission, compared with cement fired by calcium carbonate calcium sources, the carbon emission is greatly reduced, the goal of high-valued and green utilization of various solid wastes including iron tailings is achieved, and the method is suitable for industrial production. The compressive strength, the sulfur trioxide content and the screen residue of the prepared masonry cement meet the national standard requirements of masonry cement. In addition, the masonry cement is prepared from all solid waste raw materials, so that the preparation cost of the masonry cement is reduced.

The invention relates to a device and a method of a high-sensitivity suspension single-droplet sensor for monitoring PM2.5 pollution, belongs to the technical field of aerosol microdroplet spectrum trace analysis, and solves the problem that ppb-magnitude gas cannot be monitored in the prior art. The method comprises the following steps: pumping aerosol into a sample cell of a droplet suspension system in a single droplet form; introducing required reaction gas into the sample pool through an atmosphere control system; scattered light signals of the single liquid drops are respectively input into the dynamic signal processing system and the microdroplet imaging system; acquiring the characteristic peak displacement change of the metal ion sensing microdroplet; establishing a gas particle distribution Mie scattering inversion model based on micro-droplet dynamic response; inverting the radius of the liquid drop according to the stimulated Raman scattering / stimulated elastic scattering signal; according to the quantitative relationship of the reaction, calculating the generation of sulfate by the droplet suspension system (sensor); and judging which gas in the actual atmosphere is a main oxidation pathway for oxidizing sulfur dioxide to generate sulfate pollutants according to a calculation result.

The present invention provides a ship exhaust gas desulfurization device and a desulfurization method, which include a sulfur-containing ship exhaust gas pretreatment system, a seawater pretreatment system, a membrane contactor, and a seawater post-treatment system; the outlet end of the sulfur-containing ship exhaust gas pretreatment system is connected to the shell-side inlet end of the membrane contactor for sending the dust- and oil-removed exhaust gas into the shell side of the membrane contactor; the outlet end of the seawater pretreatment system is connected to the tube-side inlet end of the membrane contactor for sending the pretreated seawater into the tube side of the membrane contactor; the membrane contactor is a membrane contactor filled with polytetrafluoroethylene hollow fiber hydrophobic microporous membranes; the inlet end of the seawater post-treatment system is connected to the tube-side outlet end of the membrane contactor for post-treating the seawater after absorbing sulfur dioxide and oxidizing sulfite into sulfate. The ship exhaust gas desulfurization device described in the present invention has a high integration degree, a compact volume, and a high desulfurization efficiency, can achieve efficient desulfurization of ship exhaust gas, and has good application prospects.

The invention discloses a coal bunker mixed gas concentration detection method based on a BSA algorithm and a BP neural network, and belongs to the technical field of gas detection. The coal bunker mixed gas concentration detection method based on the BSA algorithm and the BP neural network comprises the following steps: collecting gases including carbon monoxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide and methane, and constructing the BP neural network by taking normalized gas data as an input layer; and optimizing BP neural network parameters by using a BSA bird flock algorithm, carrying out network training by using a back propagation algorithm, and inputting gas concentration data collected in real time into the trained neural network in real time to obtain a predicted value of the gas concentration. According to the method, the parameters of the BP neural network are optimized through the BSA algorithm, the accuracy of network prediction is greatly improved, the gas concentration in the coal storage bunker can be monitored in real time, and once it is detected that the hazardous gas concentration exceeds the standard, quick response can be made and corresponding measures can be taken, so that potential safety risks are reduced.

The invention relates to the technical field of industrial waste gas treatment, in particular to a waste gas treatment system and method based on wet desulphurization. The system comprises a waste gas pretreatment unit, a composite absorption reaction unit, a gas-liquid separation unit, an absorption liquid circulation system, an intelligent control system and a waste liquid treatment unit, wherein each unit is communicated with a shielding signal line through a corrosion-resistant pipeline to form a closed-loop operation system; industrial waste gas is subjected to pre-dedusting and cooling through the waste gas pretreatment unit and then enters the composite absorption reaction unit to be in countercurrent contact with a composite absorbent to achieve sulfur dioxide removal, a gas-liquid mixture obtained after reaction is separated through the gas-liquid separation unit, purified gas is directly discharged, and absorption liquid enters the absorption liquid circulation system to be recycled. And the saturated absorption liquid with the density of 1.15-1.25 g / cm < 3 > is conveyed to a waste liquid treatment unit for treatment. According to the invention, sulfur dioxide in waste gas can be efficiently removed through synergistic absorption and intelligent control, the operation cost is reduced, and equipment corrosion is reduced.

The invention relates to the technical field of atmospheric science and remote sensing, in particular to a volcanic sulfur dioxide vertical section inversion method based on a Lagrange diffusion model, and the method comprises the steps: obtaining volcanic eruption total mass constraint, satellite sulfur dioxide column concentration and effective pixels, three-dimensional meteorological driving data and chemical clearing parameters; calculating a vertical weighting function by utilizing a radiation transmission mode, and generating initial vertical distribution by combining with a column concentration layering ratio; constructing a diffusion model to simulate an air mass backward track and match observation pixels to obtain attribution air mass distribution; optimizing a volcanic sulfur dioxide vertical emission profile time sequence based on attribution distribution and total mass constraint; and inputting the sequence into a diffusion model for forward simulation, comparing satellite observation data to calculate a verification index, correcting a diffusion coefficient according to a threshold value, and outputting a target vertical emission profile time sequence. According to the method, through backward trajectory attribution and forward verification closed-loop optimization, the volcanic sulfur dioxide vertical distribution inversion precision is remarkably improved.

The system comprises a mixed gas pipeline, a heat exchanger a, a heat exchanger b, a heat exchanger c and a multi-stage refrigerating unit, the heat exchanger a, the heat exchanger b and the heat exchanger c are sequentially connected in series, the multi-stage refrigerating unit feeds cold media into the heat exchanger a, the heat exchanger b and the heat exchanger c for heat exchange, and the mixed gas pipeline is communicated with the heat exchanger a; and the output ends of the heat exchanger a, the heat exchanger b and the heat exchanger c are respectively provided with a gas-liquid separation tank a, a gas-liquid separation tank b and a gas-liquid separation tank c. According to the system and the method for separating and purifying the ammonium sulfate in the electrolytic manganese residues, gaseous sulfuric acid, sulfur dioxide, ammonia gas and nitrogen in mixed gas are respectively condensed and gradually recovered by utilizing the characteristic that the boiling points of the gaseous sulfuric acid, the sulfur dioxide, the ammonia gas and the nitrogen are different, components are used for recovering the ammonium sulfate and the nitrogen, and the sulfur dioxide is separated out; the ammonium sulfate recovery efficiency reduction caused by sulfur dioxide influence is avoided.

The invention discloses a platinum chemical plating solution and a preparation method and application thereof in semiconductors, the platinum chemical plating solution comprises the following raw materials: 0.5-10.0 g / L of platinum salt PEP, 2.1-10.0 g / L of ethylenediamine sulfate, 1.2-8.9 g / L of malonic acid, 5-50 g / L of ammonium acetate, 1.2-9.2 g / L of thiourea dioxide, and the balance of ultrapure water and ammonia water; and the pH value of the solution is adjusted to 7.0 by ammonia water. The platinum chemical plating solution disclosed by the invention is suitable for nano precision manufacturing and processing on the surface of an electronic element product of a semiconductor device, and a formed platinum metal film has excellent uniform distribution, compactness and high wear resistance; a semiconductor electronic component product with excellent plugging performance, corrosion resistance, high-precision conductivity and high-quality electronic signal transmission performance is obtained.

The invention discloses a continuous preparation method of sodium tanshinone IIA sulfonate based on a single-tube thin-layer liquid membrane reactor. Comprising the following steps: (1) dissolving tanshinone IIA in an organic solvent as a feed liquid; (2) reacting gas-phase sulfur dioxide with air, and cooling to obtain sulfur trioxide mixed gas; (3) enabling the feed liquid and sulfur trioxide mixed gas to enter a single-tube thin-layer liquid membrane reactor in a parallel flow or reverse flow manner, and carrying out continuous sulfonation reaction to obtain reaction liquid; and (4) adding a sodium salt aqueous solution into the reaction solution to carry out salt forming reaction, centrifuging, drying and purifying to obtain the tanshinone IIA sodium sulfonate. According to the invention, a novel method is adopted to carry out sulfonation reaction on tanshinone IIA, and sulfur trioxide is basically completely consumed after the reaction is finished, so that the generation of waste acid is greatly reduced, and the method has important significance on environmental protection and cost reduction. The green, safe, efficient and continuous preparation of the high-purity tanshinone IIA sodium sulfonate is realized.

Methods and associated production plants are disclosed for producing concentrated oleum or sulfur trioxide therefrom with high purity, and particularly with minimal sulfur dioxide. The methods involve use of a single contact, single absorption sulfuric acid plant operating under an unconventional set of parameters including: reacting sulfur and high purity oxygen in a combustion reactor to form sulfur dioxide at a concentration between 11.5 and 20% by volume and with an atypical oxygen to sulfur dioxide molar ratio ≥ 1; atypically catalytically converting > 96% by volume of the sulfur dioxide to sulfur trioxide in a contact apparatus; and atypically recycling > 95% by volume of the total gases from an absorption apparatus to the combustion reactor. Concentrated oleum with < 300 ppm dissolved sulfur dioxide can desirably be produced with sulfur utilization ≥ 80% using a smaller, cost-effective sulfuric acid plant. The co-production of unnecessary sulfuric acid can also be reduced.

The invention discloses a desulfurizing agent for a cement kiln as well as a production method and application of the desulfurizing agent. The desulfurizing agent is prepared from the following raw material components in percentage by weight: 88-96 wt% of limestone; 2-6 wt% of an iron raw material; 1-6 wt% of gypsum; and 0-4 wt% of a silicon-aluminum material. The desulfurizer is produced by utilizing a kiln line of a cement enterprise, is dried and ground with raw materials according to a mass ratio of 1: 100 to 3: 100, and then is put into a cement kiln system for cement clinker production, so that the emission concentration of sulfur oxides in kiln tail flue gas produced by sulphoaluminate cement clinker can be reduced from more than 2000mg / Nm < 3 > to less than 35mg / Nm < 3 >; and for other types of cement clinker, the content of the cement clinker can be reduced from 1000 mg / Nm < 3 > or above to 35 mg / Nm < 3 > or below, the desulfurization effect is stable, and the environment-friendly emission requirement can be continuously met.

The invention relates to the field of carbon dioxide capture and utilization, in particular to a method and system for producing formate through synergistic capture and conversion of flue gas carbon dioxide, formate is obtained through electrochemical conversion of carbon-rich capture liquid, capture liquid is generated, the capture liquid directly captures flue gas carbon dioxide, and the carbon-rich capture liquid is obtained again. And the carbon-rich trapping liquid is continuously recycled for electrochemical conversion. The carbon-rich capture liquid electrochemical conversion process and the flue gas carbon dioxide capture process do not need to be alternately carried out step by step, but are synchronously and continuously carried out in the same system, the whole process does not need to pre-treat a small amount of oxygen and trace nitrogen oxide and sulfur oxide gas impurities in the flue gas, and a high-energy-consumption carbon dioxide gas regeneration step is avoided; the method overcomes the defect of low single conversion rate of electrochemical conversion of carbon dioxide gas, realizes collaborative capture and conversion of flue gas carbon dioxide to produce formate, and finally realizes direct conversion and utilization of carbon dioxide from flue gas to a high-value product formate.

The invention belongs to the technical field of catalysts, and provides an oxygen-doped carbon nitride catalyst and a preparation method and application thereof.The preparation method comprises the steps that melamine, a hydrogen peroxide aqueous solution and acetonitrile are mixed and subjected to a hydrothermal reaction, and a precursor material is obtained; and calcining the precursor material to obtain the oxygen-doped carbon nitride catalyst. The method has the following advantages: (1) the synthesis process of the catalyst is simple, the raw materials for synthesizing the catalyst are cheap and easily available, the equipment requirement for synthesizing the catalyst is simple and convenient, and the operation is easy; and (2) the catalyst has excellent reaction catalytic performance for selective oxidation of sulfides, has good substrate adaptability, is easy to recycle and reuse, and still has high yield after being used for many times. And (3) the adaptability of photocatalytic heterogeneous oxidation to substrate expansion in drug molecules is rarely reported at present, and the invention provides an application method of a metal-free photocatalyst for efficiently and selectively oxidizing sulfide under the condition of no additional additive.

The application provides a preparation method of ergothioneine and application of a mercapto compound in the method. The method comprises the following steps: in the presence of a catalyst system, a sulfur oxide is reacted to generate ergothioneine. The catalyst system comprises a first catalyst and a second catalyst. The first catalyst is ergothioneine synthase, and the second catalyst is one or more of a mercapto-containing amino acid and a mercapto-containing polypeptide. The preparation method of ergothioneine provided by the application does not need to use a large amount of a chemical mercaptan reagent with a foul smell, has the advantages of high efficiency, green environmental protection, and friendly production scene, and is beneficial to industrial production of ergothioneine.

The invention belongs to the field of medicine, health and health, and particularly relates to a preparation method for controllably synthesizing polysulfonic acid mucopolysaccharide with different molecular weights, which comprises the following steps: reaction, acid-base neutralization, formamide removal by alcohol precipitation, desalting and freeze-drying. Wherein the reaction process comprises the following steps: adding sodium chondroitin sulfate and a pyridine sulfur trioxide complex into a mixed solvent of N, N-dimethylformamide and dimethyl sulfoxide, and heating for reaction to obtain a reaction mixture; the volume fraction of the dimethyl sulfoxide in the mixed solvent is 0-80%. According to the method, the low-price pyridine sulfur trioxide complex (about 150 yuan / 500g) is used, and the ratio of N, N-dimethylformamide to dimethyl sulfoxide in the mixed solvent is adjusted, so that the solubility of the chondroitin sulfate sodium and the pyridine sulfur trioxide complex is changed, and the polysulfonic acid mucopolysaccharide with molecular weights in different ranges can be regulated and generated.

The present invention provides a coal-saving, desulfurization, and decoking catalyst for boilers and an application method thereof. Through the synergistic effect of multiple components, the catalyst can simultaneously achieve coal-saving, desulfurization, decoking, corrosion protection, and ash cleaning functions during boiler operation, effectively solving the problems of single function, low desulfurization efficiency, poor decoking effect, and insufficient adaptability in the prior art. The desulfurization catalyst neutralizes sulfur oxides in flue gas, reducing low-temperature slagging. The temperature-sensitive expansion particles dynamically expand and peel off hard coke. The porous carrier particles adsorb ash and complex salts. The high-temperature retention loosening agent and the catalyst work together to prevent secondary accumulation, improve heat transfer conditions, and increase boiler thermal efficiency. The coal-saving agent reduces fuel consumption. The metal protective agent forms an anti-corrosion film on the heated surface, extending the life of the equipment and significantly improving the economic efficiency of boiler operation.

The invention provides a prebaked anode flue gas carbon capture integrated system which comprises an integrated purification unit, a pollutant removal unit and a pressure swing adsorption carbon capture unit which are sequentially connected through a pipeline, flue gas is subjected to dust pre-removal and organic pollutant adsorption of the integrated purification unit and deep treatment of nitrogen and sulfur oxides of the pollutant removal unit, and the flue gas is subjected to carbon capture and carbon capture. According to the invention, the flue gas enters the pressure swing adsorption unit and then is efficiently captured by the pressure swing adsorption unit, and a continuous and synergistic treatment chain is formed in the whole process, so that the heat loss of the flue gas transmitted among the units is obviously reduced, and the energy waste caused by equipment dispersion in the traditional system is avoided; meanwhile, in the aspect of equipment layout, the modular integrated design greatly compresses the occupied area, efficient utilization of an industrial site is achieved, the flue gas treatment cost is reduced, and the flue gas treatment reliability is improved.

The utility model relates to the technical field of environmental protection, in particular to a down-flow type peculiar smell purification system for a pot-type calcining furnace. Comprising a down-flow pot-type calcining furnace, the air outlet end of the down-flow pot-type calcining furnace is connected with a dust remover, and the dust remover is connected with an exhaust chimney through an exhaust pipe; a gate valve is arranged on the exhaust pipe; an induced draft fan is arranged on the exhaust pipe between the gate valve and the dust remover; the lower end of the gate valve is connected with a drainage pipeline; the drainage pipeline is connected with a return flue gas conveying pipeline; and the return flue gas conveying pipeline is connected with an air door of the downstream pot-type calcining furnace through a branch pipeline. A down-flow pot-type calcining furnace peculiar smell purification system is the earliest attempt in the same industry of carbon; the harm of poisonous and harmful gases such as sulfur dioxide, sulfur trioxide, nitrogen oxide, dust, carbon monoxide and carbon dioxide in the flue gas of the dust remover of the calcining furnace to post staff is solved.

In some embodiments, the present disclosure relates to a system. The system includes a substrate and a fluid trapping material formed on one or more surfaces of the substrate. The fluid capture material includes a sorbent material incorporating one or more fluids including water, carbon dioxide, sulfur oxides, alcohols, or a combination thereof. The fluid capture material also includes one or more binder materials, wherein the binder materials are optionally at least partially cross-linked. The fluid capture material includes at least one aperture.

The invention relates to the technical field of concentrated sulfuric acid production, and particularly discloses a sulfuric acid thickening device which comprises a waste acid regeneration unit for burning sulfur-containing waste acid and acid gas to produce sulfuric acid and a sulfuric acid thickening unit for thickening the sulfuric acid generated by the waste acid regeneration unit, the sulfuric acid thickening unit comprises a combustion chamber, and liquid sulfur is combusted in the combustion chamber to generate sulfur dioxide. A steam generating device is arranged in the combustion chamber, the combustion chamber is connected with the reactor through a process gas conveying pipe, sulfur dioxide is subjected to a catalytic reaction in the reactor to generate sulfur trioxide, and the reactor is connected with the absorption tower through a process gas discharging pipe; unqualified sulfuric acid and reflux sulfuric acid in the waste acid regeneration unit absorb sulfur trioxide in an absorption tower to generate sulfuric acid, and the sulfuric acid is thickened; the invention also provides a method for producing concentrated sulfuric acid by using the device. According to the device, sulfuric acid with the concentration lower than 98wt% can be prepared into concentrated sulfuric acid with the concentration higher than 98wt%, the product income is increased, meanwhile, steam is generated as a byproduct, and the benefits of the device are increased.

The invention relates to the technical field of chemical raw material preparation, and discloses a process and equipment for preparing liquid sulfur dioxide through pure oxygen incineration, the system deeply couples dynamic optimization of three high-energy-consumption links of waste heat recovery, combustion reaction and deep freezing through hardware collaboration and algorithm innovation, and compared with a traditional process, the comprehensive energy consumption of unit products is reduced by 35%, and the production cost is reduced. Meanwhile, the three technical problems of liquid sulfur solidification, furnace temperature out-of-control and non-condensable gas accumulation are solved.

The invention discloses a system and a method for measuring and calculating the emission amount of atmospheric pollutants of underground coal fire, and relates to a system for measuring and calculating the emission amount of atmospheric pollutants of underground coal fire. Comprising a power supply module, a methane emission monitoring module, a carbon oxide monitoring module, a nitrogen oxide monitoring module, a sulfur dioxide monitoring module, a black carbon emission monitoring module and an atmospheric pollutant emission flux calculation module. The environmental factor acquisition module, the methane emission monitoring module, the oxycarbide monitoring module, the nitrogen oxide monitoring module, the sulfur dioxide monitoring module, the black carbon emission monitoring module and the atmospheric pollutant emission flux calculation module are all connected with the power supply module; the measuring and calculating method of the underground coal fire atmospheric pollutant emission amount measuring and calculating system comprises the following steps: S1, placing the instrument at a proper position, and adjusting a proper sampling frequency; the problem that the atmospheric pollutant emission flux is difficult to measure and calculate due to intermittency and dispersity of underground coal fire combustion is solved.

The invention discloses a flue gas treatment device based on a noble metal catalyst, and relates to the technical field of flue gas treatment. An inner mounting frame is fixedly mounted on the inner surface wall of the treatment box, an annular outer frame is fixedly mounted on one side of the outer wall of the inner mounting frame, and a rotating groove is pre-formed in the annular outer frame. Through a multi-stage collaborative filtering mechanism, a clean reaction environment is provided for a noble metal catalyst: a linkage frame drives a filter plate to rotate, and large-particle impurities, sulfur oxides and chlorides are intercepted by utilizing centrifugal force and a composite filter material (a stainless steel filter screen and activated carbon); the guide vanes form spiral airflow, and fine impurities with the particle size larger than or equal to 1 micron are separated through centrifugal force; the metal filter pipe is combined with dynamic negative pressure adsorption, deep removal of residual dust and three-stage filtration, so that the impurity content in flue gas can be greatly reduced, catalyst poisoning, blockage or sintering are avoided, the service life of the catalyst is prolonged, and the replacement cost of precious metal is greatly reduced.

Provided herein are methods and systems for treating a sulfur dioxide-containing gaseous stream. The method includes combusting a tail gas in an excess of oxygen gas to yield a thermal oxidizer effluent containing sulfur dioxide and oxygen. The thermal oxidizer effluent is introduced to an oxidative catalytic converter to convert sulfur dioxide to sulfur trioxide, thereby forming an oxidized gas stream. The oxidized gas stream is routed to a quench tower and contacted with a dilute aqueous acid quench stream to yield sulfurous acid, hydrated sulfur dioxide, or both. The sulfurous acid or hydrated sulfur dioxide is oxidized with the excess of oxygen from the thermal oxidizer effluent to yield sulfuric acid.

The invention discloses a power generation system for fused salt energy storage by using biomass. According to the system, the purity of raw materials is remarkably improved through an intelligent sorting and impurity removing unit of the pretreatment and coupling module, the waste heat driving drying unit effectively recycles system waste heat to reduce energy consumption, the flexible forming unit generates biomass fuel with stable physical characteristics, and the nano-catalysis pretreatment unit optimizes the reaction activity of the fuel on the molecular level. The measures directly improve the integrity of biomass combustion and the heat energy conversion efficiency, so that the fuel of unit mass releases more effective heat in the fused salt combustor. Meanwhile, tar is decomposed from the source through catalytic pretreatment, generation of nitric oxide and sulfur oxide precursors is reduced, the treatment load of a follow-up flue gas purification system is greatly reduced, the whole system reduces dependence on external energy on the basis of ensuring stable power supply through collaborative optimization of fuel pretreatment, stored energy release and clean emission, and the energy-saving and environment-friendly effects are achieved. And a high-adaptability solution is provided for distributed energy supply.

The invention discloses a system and a method for absorbing sulfur dioxide in boiler flue gas. The system comprises a boiler induced draft fan outlet flue, a sulfur dioxide spraying and absorbing device and a flue gas discharging device, an outlet of the boiler induced draft fan outlet flue is connected with a first inlet of the sulfur dioxide spraying and absorbing device, and a first outlet of the sulfur dioxide spraying and absorbing device is connected with an inlet of the flue gas discharging device; the sulfur dioxide spraying absorption device is provided with a filler layer, a demisting device is arranged at a first outlet of the sulfur dioxide spraying absorption device, absorption liquid adopted by the sulfur dioxide spraying absorption device is a mixed solution of sulfuric acid, hydrogen iodide and iodine, and the mixed solution is located at the lower part of the sulfur dioxide spraying absorption device; a first inlet of the sulfur dioxide spraying and absorbing device is formed between the position above the liquid level of the mixed liquid and the filler layer; and flue gas from an outlet flue of the boiler induced draft fan passes through the filler layer and the demisting device to enter the flue gas emission device. The iodine solution is adopted to absorb sulfur dioxide in the boiler flue gas, and the atmospheric pollution gas sulfur dioxide is recycled.

A system is described that enables the purification of COx, SOx, NOx, dioxin and furan, and H2S gases using wet and dry filters in a single chimney, comprising: a nozzle system (2) that sprays a mixture consisting of water, micronized zeolite, ammonia, and boron mineral in fine droplets to perform the first purification of SOx (sulfur oxides), NOx (nitrogen oxides), and COx (carbon oxides) gases entering the chimney (1) from the combustion gas, a zeolite-based dry filter (3) that purifies the dioxin and furan components in the flue gas (B) rising after the first purification, a first continuous measurement system (4) that measures the values of the combustion gas at the entry point to the chimney (1), a second continuous measurement system (5) that measures the values of the combustion gas after the dry filter (3), an Al-supported processor (6) that adjusts the amount of the mixture to be sprayed from the nozzle system (2) based on the comparison of the first continuous measurement system (4) and the second continuous measurement system (5).