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Ruthenium palladium alloy electroless plating solution and its plating method and application

A technology of chemical plating solution and palladium alloy, applied in the field of chemical plating, can solve the problems of difficult control of reaction rate, poor solderability of pure ruthenium layer, inability to realize ruthenium-palladium alloy plating, etc. mild effect

Active Publication Date: 2021-01-12
SHENZHEN BEIJIA ELECTRONICS MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the above-mentioned deficiencies of the prior art, provide a kind of ruthenium-palladium alloy electroless plating solution and its plating method and application, to solve the poor weldability and the existence of reaction rate of the pure ruthenium layer that existing electroless ruthenium plating solution generates It is difficult to control and the technical problem that the ruthenium-palladium mixed plating solution can hardly realize the ruthenium-palladium alloy coating

Method used

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  • Ruthenium palladium alloy electroless plating solution and its plating method and application
  • Ruthenium palladium alloy electroless plating solution and its plating method and application
  • Ruthenium palladium alloy electroless plating solution and its plating method and application

Examples

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Embodiment 1

[0024] This embodiment provides a palladium-ruthenium alloy electroless plating solution and a method for electroless plating a ruthenium-palladium alloy layer. The components contained in the palladium-ruthenium alloy electroless plating solution are shown in Table 1 below. Wherein, the plating method of described palladium-ruthenium alloy electroless plating solution or the method for electroless plating ruthenium-palladium alloy layer comprise the steps:

[0025] After the circuit board with nickel as the base pad is properly surface activated, the step of electroless palladium ruthenium alloy plating is performed. The composition and conditions of the electroless palladium ruthenium alloy plating solution are shown in Table 1. After the pH of the solution is adjusted to the set value with citric acid or ethylenediamine solution, it is heated to the plating temperature of 65°C. After 5 minutes of electroless plating, the plated parts are taken out, cleaned and dried, and an...

Embodiment 2

[0029] This embodiment provides a palladium-ruthenium alloy electroless plating solution and a method for electroless plating a ruthenium-palladium alloy layer. The components contained in the palladium-ruthenium alloy electroless plating solution are shown in Table 2. Wherein, the plating method of described palladium-ruthenium alloy electroless plating solution or the method for electroless plating ruthenium-palladium alloy layer comprise the steps:

[0030] Plating was carried out with reference to the plating method of Example 1, wherein, except that the plating time was changed to 15 minutes, all other processing steps and the electroless plating process were the same as in Example 1. After the electroless plating is completed, the weldability is good through analysis and testing, the thickness of the palladium-ruthenium alloy layer increases to about 0.35 μm, the ruthenium content is about 60%, the palladium content is about 40%, and the plating solution remains stable dur...

Embodiment 3

[0034] This embodiment provides a palladium-ruthenium alloy electroless plating solution and a method for electroless plating a ruthenium-palladium alloy layer. The components contained in the palladium-ruthenium alloy electroless plating solution are shown in Table 3 below. Wherein, the plating method of described palladium-ruthenium alloy electroless plating solution or the method for electroless plating ruthenium-palladium alloy layer comprise the steps:

[0035] After proper surface activation of the copper-based device, a palladium-ruthenium alloy electroless plating step is performed. The composition and conditions of the electroless plating solution are shown in Table 3. After the pH of the solution is adjusted to the set value with citric acid or ethylenediamine solution, it is heated to a plating temperature of 60°C. After 20 minutes of electroless plating, the plated parts are taken out and cleaned and dried. After analysis and testing, the metal layer Strong bindin...

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Abstract

The invention discloses a ruthenium palladium alloy chemical plating solution and application thereof and a method for chemical plating of ruthenium palladium alloy layer. The ruthenium-palladium alloy chemical plating solution comprises a solvent and a concentration of 0. 1mmol / L to 10mmol / L of water-soluble ruthenium salt and 0.1mmol / L to 10mmol / L of water-soluble palladium salt and 1mmol / L to20mmol / L of complexing agent and 1mmol / L to 50mmol / L of an auxiliary agent and 1mmol / L to 20mmol / L of hydrazine hydrate and a pH regulator. The ruthenium palladium alloy chemical plating solution canbe applied to electronic devices and printed circuit boards, the method for chemical plating of the ruthenium palladium alloy layer comprises the step of placing the substrate in the ruthenium palladium alloy chemical plating solution for plating treatment, the ruthenium-palladium alloy chemical plating solution is good in stability and high in palladium ruthenium deposition rate, and controllable, the content of ruthenium in the coating is high, the quality of the coating is good, and the coating is well combined with the substrate and the subsequent coating, in addition, the chemical platingcondition of the ruthenium palladium alloy chemical plating solution is mild.

Description

technical field [0001] The invention relates to the technical field of electroless plating, in particular to a ruthenium-palladium alloy electroless plating solution and a plating method and application thereof. Background technique [0002] During the production of electronic devices and printed circuit boards, the surface of the pads of the devices or printed circuit boards needs to be treated to meet the corrosion resistance and solderability requirements of electronic devices and printed circuit boards. There are many types of traditional surface treatment methods: including electroplating and chemical plating, and the types of metals to be plated can also be divided into: tin, nickel, silver, palladium and gold. [0003] Metal palladium has the characteristics of high melting point and high hardness. It has high corrosion resistance and high wear resistance when used in the electronics industry. However, because the price of palladium is also high and is not constantly ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C18/48C23C18/42
CPCC23C18/42C23C18/48
Inventor 黎坊贤王予李荣
Owner SHENZHEN BEIJIA ELECTRONICS MATERIAL