Partially divided fiber bundle and manufacturing method thereof, fiber-reinforced resin molding material and manufacturing method thereof
A fiber-reinforced resin and a technology for a manufacturing method, which are applied in the fields of partially split fiber bundles and their manufacturing, as well as fiber-reinforced resin molding materials and their manufacturing fields, to achieve the effects of productivity, continuous and stable cutting, and efficient manufacturing
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Embodiment 1
[0149] The fiber bundle [A-1] was unwound at a constant speed of 10 m / min using a winder, widened by a vibrating widening roll vibrating in the axial direction at 10 Hz, and passed through a width limiting roll of 60 mm width, This results in a widened fiber bundle with a width of up to 60 mm.
[0150] The obtained widened fiber bundles were continuously immersed in a sizing agent treatment liquid (which was obtained by diluting the sizing agent [S-1] with purified water), and the sizing agent was applied to the widened fiber bundles, and then heated to 150°C The widened fiber bundle coated with the sizing agent was supplied to a heated roll and a drying oven at 200° C., and dried to remove water. The resulting widened fiber bundle after the application of the sizing agent was calculated based on the measurement method of the aforementioned sizing agent adhesion amount, and it was 3.2%. In addition, this is the total adhesion amount including the sizing agent provided to the ...
Embodiment 2
[0157] The fiber bundle [A-1] was unwound at a constant speed of 10 m / min using a winder, widened by a vibrating widening roll vibrating in the axial direction at 10 Hz, and passed through a width limiting roll of 60 mm width, In this way, a widened fiber bundle widened to 60 mm was obtained, and the widened fiber bundle was subjected to a split treatment to obtain a partially split fiber bundle, and then the sizing agent was applied, and the evaluation was performed in the same manner as in Example 1. As a result, the sizing agent adhesion amount was 3.3%, the bending strength was 430 MPa, the bending elastic modulus was 27 GPa, and the CV8% of the bending elastic modulus.
Embodiment 3
[0159] The fiber bundle [A-1] was unwound at a constant speed of 10 m / min using a winder, dipped in the sizing agent treatment solution, and passed through a vibrating widening roll vibrating in the axial direction at 5 Hz to obtain a sizing agent coating After the completion of the widened fiber bundles, the widened fiber bundles after the sizing agent coating is completed are subjected to fiber splitting, so as to make part of the fiber bundles after the sizing agent coating is completed, and the resulting sizing agent coating is completed. Evaluation was carried out in the same manner as in Example 1 except that a part of the split fiber bundle was subjected to a drying step to obtain a part of the split fiber bundle. As a result, the sizing agent adhesion amount was 3.2%, the bending strength was 435 MPa, the bending elastic modulus was 28 GPa, and the CV of the bending elastic modulus was 7%.
[0160]As described above, it was confirmed that in any of Examples 1 to 3, exc...
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