Large-size silicon carbide aerogel and preparation method thereof

A silicon carbide and aerogel technology, which is applied in the field of silicon carbide aerogel preparation, can solve the problems of complex preparation process, high cost, brittleness and the like, and achieves the effects of simple process, low equipment requirements and high purity

Active Publication Date: 2019-04-16
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented new type of material called Silicon Carbon Aerocrystal was developed by researcher Daniel Kistler who discovered that it had many benefits such as being highly thermally conductive but also having excellent properties like waterproofness and durability over longer periods than existing products made up entirely of ceramics. These improvements led to its use in various industries including thermal insulating systems, electronic devices, fuel cells, filters, batteries, and more.

Problems solved by technology

Technological Problem addressed in this patents relates to finding new types of thermally stable and highly resistive materials called carbon Aerogels (CN). These materials offer advantages like superior durability under extreme temperatures while also being able to maintain their strength when exposed to severe environmental factors like water vapor. However, current techniques often result in fragile ceramia products containing residual volatile gases during storage and use. Silicon dioxanes (Si02a) were proposed as alternative filler options without causing these issues.

Method used

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  • Large-size silicon carbide aerogel and preparation method thereof
  • Large-size silicon carbide aerogel and preparation method thereof
  • Large-size silicon carbide aerogel and preparation method thereof

Examples

Experimental program
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Embodiment 1

[0043] This embodiment has prepared the density is 2mg / cm 3 Silicon carbide airgel, the specific steps are as follows:

[0044] 1) Using dimethyldimethoxysilane (mass fraction 10wt.%) as a sol raw material, water as a crosslinking agent (mass fraction 10wt.%) and absolute ethanol as a solvent (mass fraction 80wt.%) to prepare silicon Oxygen sol;

[0045] 2) Disperse 2g of chopped carbon fibers (length about 1mm, mass fraction 1wt.%) in 100ml of silica sol, and perform mechanical stirring for 10min, so that the chopped carbon fibers are uniformly dispersed in the siloxane sol;

[0046] 3) The method of vacuum filtration is adopted to make the carbon fibers dispersed in the sol overlap each other into a three-dimensional structure block;

[0047] 4) Heating to the curing temperature (100°C) in the air, and heat preservation for 4 hours;

[0048] 5) The temperature is raised to 1200°C in argon with a pressure of 0.1Mpa, and the temperature is kept for 2 hours, and the gel is c...

Embodiment 2

[0051] This embodiment prepared 4mg / cm 3 Silicon carbide airgel, the specific steps are as follows:

[0052] 1) Using methyltrimethoxysilane (mass fraction 10wt.%) sol as raw material, water as crosslinking agent (mass fraction 70wt.%) and absolute ethanol as solvent (mass fraction 20wt.%) to prepare siloxane sol ;

[0053] 2) Disperse 2g of chopped carbon fibers (length about 1mm, mass fraction 2wt.%) in 100ml of silica sol, and perform ultrasonication for 15min, so that the chopped carbon fibers are uniformly dispersed in the siloxane sol;

[0054] 3) Using the method of vacuum filtration, the chopped carbon fibers dispersed in the sol are overlapped to form a three-dimensional block;

[0055] 4) Heating to the curing temperature (100°C) in the air, and heat preservation for 4 hours;

[0056] 5) The temperature is raised to 1500° C. in argon with a pressure of 0.1 MPa, and the temperature is kept for 2 hours, and the gel is cracked to form silicon carbide nanowires;

[0...

Embodiment 3

[0059] This embodiment prepared 15mg / cm 3 Silicon carbide airgel, the specific steps are as follows:

[0060] 1) Using methyltrimethoxysilane (mass fraction 40wt.%) sol as raw material, water as crosslinking agent (mass fraction 50wt.%) and absolute ethanol as solvent (mass fraction 10wt.%) to prepare siloxane sol ;

[0061] 2) Disperse 2g of chopped carbon fibers (length about 1mm, mass fraction 2wt.%) in 100ml of silica sol, and perform ultrasonication for 15min, so that the chopped carbon fibers are uniformly dispersed in the siloxane sol;

[0062] 3) Using the method of vacuum filtration, the chopped carbon fibers dispersed in the sol are overlapped to form a three-dimensional block;

[0063] 4) Apply a pressure of 10kPa to the block;

[0064] 5) Heating to the curing temperature (100°C) in the air, and heat preservation treatment for 4 hours;

[0065] 6) In argon with a pressure of 0.25 MPa, the temperature is raised to 1550 ° C, and the temperature is kept for 2 hour...

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Abstract

The invention discloses large-size silicon carbide aerogel and a preparation method thereof, and belongs to the technical field of preparation silicon carbide aerogel. The silicon carbide aerogel hasa three-dimensional multi-space network microstructure constructed by carbide aerogel nanowires with the size from the nanometer order (the diameter ranges from 20 nm to 100 nm) to the submicron order(the diameter ranges from 0.1 micrometer to 0.5 micrometer), the silicon carbide aerogel has the practical size, and industrial large-scale production can be achieved easily. The prepared silicon carbide aerogel has the ultrahigh porosity (larger than 90%), and is suitable for being used as a heat insulation and preparation material, a catalyst carrier, a filtering material, an energy storage material and other materials. The preparation method of the large-size silicon carbide aerogel is simple in process, the high cost and time-consuming drying equipment and processes referred in the traditional aerogel preparation technology are not needed, the requirement on equipment is low, the preparation efficiency is high, the silicon carbide aerogel with the practical size can be prepared, and industrial large-scale production can be achieved easily.

Description

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Claims

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Application Information

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Owner XI AN JIAOTONG UNIV
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