Alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification and production method and application thereof

A carbon-based catalyst, desulfurization and denitrification technology, applied in the direction of catalyst activation/preparation, metal/metal oxide/metal hydroxide catalyst, chemical instruments and methods, etc., can solve the problems of easy agglomeration, uneven dispersion of active coke, and lack of dispersion Measures and other issues to achieve the effect of avoiding agglomeration, improving reactivity and stability

Active Publication Date: 2019-05-07
SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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  • Description
  • Claims
  • Application Information

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Problems solved by technology

This method can improve the wear resistance and catalytic activity stability of the modified active coke, but due to the lack of effective dispersion measures, the active components such as vanadium are not uniformly dispersed in the active coke, and are easy to agglomerate in the regeneration high temperature, which makes the bulk phase meth

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  • Alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification and production method and application thereof
  • Alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification and production method and application thereof
  • Alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification and production method and application thereof

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[0031] The technical solution of the present invention and its effects will be further described below through specific examples. The following examples are only used to illustrate the content of the present invention, and are not intended to limit the protection scope of the present invention. Applying the idea of ​​the present invention to make simple changes to the present invention is within the scope of protection of the present invention.

[0032] The preparation method of the desulfurization and denitration carbon-based catalyst of embodiment 1-7 is as follows:

[0033] (1) Preparation of coal powder: coking coal, coke powder, and dry asphalt are crushed, mixed and pulverized to a particle size of 200 mesh;

[0034] (2) Manufacture of coal paste: Add the prepared coal powder, coal tar, vanadium-containing salt and alkali metal salt solution into a kneader, stir and knead evenly to make coal paste.

[0035] (4) Forming and granulation: forming and granulating the coal ...

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Abstract

The invention discloses an alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification. The alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification comprises a carbon material, an active component vanadium and a modifier alkali metal, wherein according to weight percentages of the carbon material, the active component vanadium and the modifier alkali metal, the metal vanadium, on the basis of V2O5, accounts for 0.5%-10% of the catalyst in percentage by weight, the alkali metal accounts for 0.1%-0.5% of the catalyst in percentage byweight, and the rest is the carbon material. The alkali-metal-modified carbon-based catalyst used for desulfurization and denitrification has the advantages that a production method is simple and convenient, the active component is evenly distributed, and the sulfur capacity and the denitrification activity are significantly improved along with a regeneration process.

Description

technical field [0001] The invention relates to a catalyst and a preparation method, in particular to an alkali metal-modified carbon-based catalyst for desulfurization and denitrification, a preparation method and application thereof. technical background [0002] SO emissions from fossil fuel combustion 2 Nitrogen and nitrogen oxides (NOx) are the main causes of acid rain and photochemical smog, and their emissions have seriously exceeded the carrying limit of the atmospheric environment, causing serious damage to the ecological environment and bringing huge economic losses to human beings. Since the 1970s, on the basis of many years of research on the control technology of flue gas pollutants emitted by fossil fuel combustion, researchers have begun to study SO in industrial flue gas. 2 and NOx simultaneous removal technology research. [0003] Synergistic removal of multiple pollutants in flue gas by activated coke dry method can achieve SO 2 Resource utilization, no ...

Claims

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Application Information

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IPC IPC(8): B01J23/22B01J23/92B01J37/08B01D53/86B01D53/60
CPCY02A50/20
Inventor 黄张根曾泽泉宁卫云韩小金郭士杰
Owner SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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