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Simultaneous formation of cathode interfacial layer and active layer and its application in reverse non-fullerene organic solar cells

A cathode interface layer, solar cell technology, applied in the field of solar cells

Active Publication Date: 2021-01-26
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the one-step preparation of interfacial layer and active layer has not been studied in the field of non-fullerene OSCs.

Method used

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  • Simultaneous formation of cathode interfacial layer and active layer and its application in reverse non-fullerene organic solar cells
  • Simultaneous formation of cathode interfacial layer and active layer and its application in reverse non-fullerene organic solar cells
  • Simultaneous formation of cathode interfacial layer and active layer and its application in reverse non-fullerene organic solar cells

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] In this example, reverse non-fullerene organic solar cells were prepared according to the following method:

[0039] Add 10 mg of polyvinylpyrrolidone (molecular weight: 3500) into 1 mL of chlorobenzene, and stir overnight at 40° C. to obtain a PVP solution. Add 10mg PBDB-T and 10mg IT-M to 1mL chlorobenzene, stir at 40°C for 8h, then add 0.01mL (0.5% by mass) of the above PVP solution and 0.005mL diiodooctane, and continue stirring at 40°C for 30min, that is to obtain a mixture.

[0040] The above mixed solution was spin-coated on the glass covered with ITO, and then annealed at 100° C. for 10 min. at about 10 - 4 Under the pressure of Pa, 10nm molybdenum trioxide and 100nm aluminum electrode are evaporated to obtain a solar cell, and the structural diagram of the cell is as follows figure 1 Shown in a.

Embodiment 2

[0048] In this example, reverse non-fullerene organic solar cells were prepared according to the following method:

[0049] Add 10 mg of polyvinylpyrrolidone (molecular weight: 3500) into 1 mL of chlorobenzene, and stir overnight at 40° C. to obtain a PVP solution. Add 10mg PBDB-TF and 10mg IT-4F to 1mL chlorobenzene, stir at 40°C for 8h, then add 0.005mL (0.25% by mass) of the above PVP solution and 0.005mL diiodooctane, and continue stirring at 40°C for 30min, that is to obtain a mixture.

[0050] The above mixed solution was spin-coated on the glass covered with ITO, and then annealed at 100° C. for 10 min. at about 10 - 4 Under the pressure of Pa, 10nm molybdenum trioxide and 100nm aluminum electrode are evaporated to obtain a solar cell, and the structural diagram of the cell is as follows figure 1 As shown in c.

Embodiment 3

[0058] In this example, reverse non-fullerene organic solar cells were prepared according to the following method:

[0059] Add 10 mg of polyvinylpyrrolidone (molecular weight: 3500) into 1 mL of chlorobenzene, and stir overnight at 40° C. to obtain a PVP solution. Add 10mg PBDB-TCl and 10mg IT-4F to 1mL chlorobenzene, stir at 40°C for 8h, then add 0.005mL (0.25% by mass) of the above PVP solution and 0.005mL diiodooctane, and continue stirring at 40°C for 30min, that is to obtain a mixture.

[0060] The above mixed solution was spin-coated on the glass covered with ITO, and then annealed at 100° C. for 10 min. at about 10 - 4 Under the pressure of Pa, 10nm molybdenum trioxide and 100nm aluminum electrode are evaporated to obtain a solar cell, and the structural diagram of the cell is as follows figure 1 Shown in e.

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Abstract

The present invention proposes a method for simultaneously forming the cathode interface layer and the active layer. The method includes: using a mixed solution to prepare a film on a substrate containing a cathode so as to simultaneously form a cathode interface layer and an active layer, wherein the cathode interface layer is formed on the surface of the cathode, and the active layer is formed on the On the surface of the cathode interface layer, the mixed solution includes: polyvinylpyrrolidone; and an active layer solution. Thus, the reverse non-fullerene organic solar cell containing the cathode interface layer and active layer obtained by the method of the present invention has better photovoltaic performance, such as high energy conversion efficiency, and the method is easy to operate and suitable for large-scale chemical production.

Description

technical field [0001] The invention relates to the field of solar cells. Specifically, the present invention relates to a method for simultaneously forming a cathode interface layer and an active layer and its application in reverse non-fullerene organic solar cells. Background technique [0002] An inverted organic solar cell (OSC) sequentially consists of a substrate, a cathode, a cathode interfacial layer, an active layer, an anode interfacial layer, and an anode. The use of the cathode interfacial layer can effectively improve the photovoltaic performance of the device. The traditional reverse OSCs preparation process needs to prepare the cathode interface layer and the active layer separately, including two film-forming processes, and the operation is complicated. Moreover, when prepared by large-area printing technology, the thickness of the printed film is inevitably polydisperse, which limits the practical application of cathode interface layer materials whose ele...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/42H01L51/44H01L51/46H01L51/48
CPCH10K71/12H10K85/141H10K30/20H10K30/81Y02E10/549
Inventor 侯剑辉杨蓓
Owner INST OF CHEM CHINESE ACAD OF SCI