A kind of all-liquid phase organ chip and preparation method thereof
An organ chip and liquid phase technology, applied in the field of biochip and its preparation, can solve the problems of inability to simulate the dynamic changes of human tissue, complex system, difficult to change the structure, etc. Effect
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Embodiment 1
[0034] The process of preparing an all-liquid phase organ chip in this embodiment is as follows: figure 1 shown, including the following steps:
[0035] (1) Preparation of surface-modified glass with double bonds
[0036] Add 30 μL of 3-(methacryloyloxy)propyltrimethoxysilane solution to the overlapping gap between the two pretreated hydroxy glasses, so that the solution can completely infiltrate the surface of the overlapping glass while ensuring no bubbles, and react for 1 h , respectively, washed several times with water and ethanol, and dried to obtain a glass slide with surface modified double bonds;
[0037] The mass concentration of 3-(methacryloyloxy)propyltrimethoxysilane in the 3-(methacryloyloxy)propyltrimethoxysilane solution is 20 wt %, and the solvent is ethanol.
[0038] (2) Preparation of polymer layer porous membrane
[0039] Prepare the prepolymer mixture: The prepolymer mixture solution includes the following components by volume percentage: 12vol% HEMA (...
Embodiment 2
[0051] (1) Preparation of surface-modified double bond substrates
[0052] This step is basically the same as Example 1, except that the mass concentration of 3-(methacryloyloxy)propyltrimethoxysilane in the 3-(methacryloyloxy)propyltrimethoxysilane solution is 10wt%, The solvent is ethanol.
[0053] Wherein, the substrate is plastic, and the plastic substrate is pretreated with oxygen plasma to make it hydrophilic, and then the same steps as in Example 1 are used to modify the substrate.
[0054] (2) Preparation of polymer layer porous membrane
[0055] The polymer layer porous film prepared in this step is basically the same as that in Example 1, except that the prepolymer mixture solution includes 15vol% HEMA (monomer), 6vol% EDMA (crosslinking agent), 50vol% cyclohexanol ( porogen), 29vol% n-decanol (porogen), and benzoin dimethyl ether (DMPA) is used as the photoinitiator, and the addition of the photoinitiator accounts for the concentration of the mixture to be 0.5mg / m...
Embodiment 3
[0065] (1) Preparation of surface-modified glass with double bonds
[0066] This step is basically the same as Example 1, except that the mass concentration of 3-(methacryloyloxy)propyltrimethoxysilane in the 3-(methacryloyloxy)propyltrimethoxysilane solution is 25wt%, The solvent is ethanol.
[0067] (2) Preparation of polymer layer porous membrane
[0068] The polymer layer porous film prepared in this step is basically the same as that in Example 1, except that the prepolymer mixture solution includes 16vol% HEMA (monomer), 4vol% EDMA (crosslinking agent), 40vol% cyclohexanol ( porogen), 40vol% n-decanol (porogen), and benzoin dimethyl ether (DMPA) is used as the photoinitiator, and the addition of the photoinitiator accounts for 4mg / mL of the mixture;
[0069] (3) Preparation of hydrophobic polymer layer porous membrane
[0070] In a fume hood environment, 40 mL of dichloromethane (DCM), 80 μL of 4-pentynoic acid and 100 μL of N,N′-diisopropylcarbodiimide (DIC) were add...
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