A two-stage low-concentration voc catalytic degradation method
A catalytic degradation and low-concentration technology, applied in the field of environmental purification, can solve problems such as complex operation, low efficiency, and low catalytic effect, and achieve the effect of simple process route, low equipment requirements, and strong versatility
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[0056] According to a preferred embodiment of the present invention, the low-concentration VOC is that the concentration is lower than 200mg"m -3 VOC, preferably a concentration of less than 150mg〃m -3 VOC, more preferably the concentration is lower than 100mg〃m -3 VOCs.
[0057] In a further preferred embodiment, the VOC is one or more of alkanes, alkenes, alkynes, aromatic hydrocarbons, halogenated hydrocarbons, oxygen-containing organic compounds, nitrogen-containing compounds or sulfur-containing compounds.
[0058] In a further preferred embodiment, the VOC is one or more of alkanes, alkenes, alkynes, aromatic hydrocarbons or halogenated hydrocarbons.
[0059]Preferably, the VOC is one or more of alkanes, alkenes or chlorinated hydrocarbons.
[0060] In the present invention, the enrichment and preliminary catalytic degradation of the low-concentration VOC are carried out under the action of the first catalyst.
[0061] According to a preferred embodiment of the prese...
Embodiment 1
[0157] Adopt toluene content as 90mg〃m -3 Toluene-containing exhaust gas simulates low-concentration VOC, using figure 1 The system shown is connected to the first air inlet, and the exhaust gas is discharged from the outlet. Among them, the first-stage catalytic degradation reactor and the second-stage catalytic degradation reactor are all stainless steel tubes with an inner diameter of 20mm, and the first support plate The first catalyst stacked is Al / δ-MnO 2 ; The second catalyst stacked on the second support plate is Cu / δ-MnO 2 ; The first heater and the second heater are electric heating wires, and the first temperature measuring device and the second temperature measuring device are both temperature measuring thermocouples.
[0158] Wherein, the first catalyst is prepared according to the following steps:
[0159] (i) Potassium permanganate and acetylene black are added in methanol, the mass ratio is 10:1:32, dispersed to form a gel;
[0160] Suction filter the gel, an...
Embodiment 2
[0176] This embodiment is similar to embodiment 1, the difference is that the Al / δ-MnO 2 The filling volume is 25mL (the waste gas reaction volume space velocity is 20000h -1 );
[0177] The Cu / δ-MnO 2 The filling volume of the tank is 27.8mL (the reaction volume space velocity of exhaust gas is 18000h -1 ).
[0178] Detect the toluene content in the final exhaust exhaust gas at the exhaust gas outlet, and the result shows that the content is 9mg〃m -3 , up to emission standards.
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