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A two-stage low-concentration voc catalytic degradation method

A catalytic degradation and low-concentration technology, applied in the field of environmental purification, can solve problems such as complex operation, low efficiency, and low catalytic effect, and achieve the effect of simple process route, low equipment requirements, and strong versatility

Active Publication Date: 2022-03-22
北京市生态环境保护科学研究院 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the composite catalyst prepared according to the traditional method may not be able to perfectly combine the advantages of each catalyst, and even the catalytic effect of the composite catalyst may be lower than that of a single component catalyst; moreover, the design process of the composite catalyst needs to control the composite ratio, reaction temperature, Synthetic conditions such as preparation atmosphere, the operation is very complicated, the efficiency is low, and the result is often half the result with half the effort

Method used

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  • A two-stage low-concentration voc catalytic degradation method
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  • A two-stage low-concentration voc catalytic degradation method

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Embodiment approach

[0056] According to a preferred embodiment of the present invention, the low-concentration VOC is that the concentration is lower than 200mg"m -3 VOC, preferably a concentration of less than 150mg〃m -3 VOC, more preferably the concentration is lower than 100mg〃m -3 VOCs.

[0057] In a further preferred embodiment, the VOC is one or more of alkanes, alkenes, alkynes, aromatic hydrocarbons, halogenated hydrocarbons, oxygen-containing organic compounds, nitrogen-containing compounds or sulfur-containing compounds.

[0058] In a further preferred embodiment, the VOC is one or more of alkanes, alkenes, alkynes, aromatic hydrocarbons or halogenated hydrocarbons.

[0059]Preferably, the VOC is one or more of alkanes, alkenes or chlorinated hydrocarbons.

[0060] In the present invention, the enrichment and preliminary catalytic degradation of the low-concentration VOC are carried out under the action of the first catalyst.

[0061] According to a preferred embodiment of the prese...

Embodiment 1

[0157] Adopt toluene content as 90mg〃m -3 Toluene-containing exhaust gas simulates low-concentration VOC, using figure 1 The system shown is connected to the first air inlet, and the exhaust gas is discharged from the outlet. Among them, the first-stage catalytic degradation reactor and the second-stage catalytic degradation reactor are all stainless steel tubes with an inner diameter of 20mm, and the first support plate The first catalyst stacked is Al / δ-MnO 2 ; The second catalyst stacked on the second support plate is Cu / δ-MnO 2 ; The first heater and the second heater are electric heating wires, and the first temperature measuring device and the second temperature measuring device are both temperature measuring thermocouples.

[0158] Wherein, the first catalyst is prepared according to the following steps:

[0159] (i) Potassium permanganate and acetylene black are added in methanol, the mass ratio is 10:1:32, dispersed to form a gel;

[0160] Suction filter the gel, an...

Embodiment 2

[0176] This embodiment is similar to embodiment 1, the difference is that the Al / δ-MnO 2 The filling volume is 25mL (the waste gas reaction volume space velocity is 20000h -1 );

[0177] The Cu / δ-MnO 2 The filling volume of the tank is 27.8mL (the reaction volume space velocity of exhaust gas is 18000h -1 ).

[0178] Detect the toluene content in the final exhaust exhaust gas at the exhaust gas outlet, and the result shows that the content is 9mg〃m -3 , up to emission standards.

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Abstract

The invention discloses a two-stage low-concentration VOC catalytic degradation method, which comprises the following steps: step 1, enriching low-concentration VOC and performing preliminary catalytic degradation to obtain small molecule VOC substances; The degraded small molecule VOC substances are catalyzed and degraded again, so that the products can be discharged up to the standard. According to the method of the present invention, the low-concentration VOC is sequentially passed into the first-stage catalytic degradation reactor and the second-stage catalytic degradation reactor arranged in series, so that the low-concentration VOC is divided into two stages of degradation, and the first stage of degradation utilizes a catalyst with a large specific surface area. The characteristics of low-concentration VOC are enriched and initially catalytically degraded into small molecular substances; the second stage of degradation utilizes the efficient degradation of the catalyst to deeply mineralize small molecule VOC substances into carbon dioxide and water, and achieve the final discharge of exhaust gas up to the standard. The process route is simple, the conditions are easy to control, the requirements for equipment are low, and the versatility is strong, which can catalyze the degradation of various exhaust gas pollutants.

Description

technical field [0001] The invention belongs to the field of environmental purification, and in particular relates to a two-stage low-concentration VOC catalytic degradation method. Background technique [0002] Many volatile organic compounds—VOCs have potential carcinogenic effects on humans, and some VOCs are listed as key pollution by domestic and foreign environmental protection departments (Ministry of Ecology and Environment (MEE), US Environmental Protection Agency (EPA) and European Commission (EC)) and subject to strict supervision and control. Therefore, in recent years, the development of effective VOC treatment technology has attracted widespread attention at home and abroad. [0003] At present, the treatment technology of VOC pollutants mainly involves adsorption and catalytic degradation. Among them, the adsorption method can only absorb the pollutants from the gas phase, and only completes the transfer of the pollutants, but cannot really eliminate the pol...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/72B01J23/34B01J23/889
CPCB01D53/8668B01J23/8892B01J23/34
Inventor 李珊珊江磊谭杰张婷婷陈鹏张月
Owner 北京市生态环境保护科学研究院