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A kind of bio-based polyethylene/starch blend modified blown film material and preparation method thereof

A blending modification and bio-based technology, which is applied in the field of bio-based polyethylene/starch blended modified blown film materials and its preparation, can solve the problem of mechanical performance degradation, low bio-based content of starch/polyethylene plastic materials, unfavorable Problems such as popularization and application, to achieve the effect of lowering melt index, improving production performance and reducing pollution

Active Publication Date: 2021-09-28
SHENZHEN HONGCAI NEW MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are certain defects in the above-mentioned patented technical method, which are mainly manifested in the low bio-based content of the prepared starch / polyethylene plastic material, and when the starch content in the starch / polyethylene plastic material increases slightly, the mechanical properties of the system will decrease significantly , which is not conducive to the promotion and application of the current industry

Method used

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  • A kind of bio-based polyethylene/starch blend modified blown film material and preparation method thereof
  • A kind of bio-based polyethylene/starch blend modified blown film material and preparation method thereof
  • A kind of bio-based polyethylene/starch blend modified blown film material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-5

[0030] Example 1-5 Components of polyethylene / thermoplastic starch blended modified blown film material and its preparation

[0031] Examples 1-5, the components of polyethylene / thermoplastic starch blended modified blown film materials are shown in the table below.

[0032] Table 1

[0033]

[0034]

[0035] Embodiment 1-5, the preparation method of polyethylene / thermoplastic starch blended modified blown film material, the steps are as follows:

[0036] S1. First add starch into the reaction kettle, set the temperature to 150°C, turn on the stirring shaft, rotate at 800rpm / min, and take 30min to control the moisture content of the starch within 0.5%, and then add plasticizer through the solid feeding port at the upper end of the reaction kettle , The accelerator continued to mix for 25 minutes to obtain thermoplastic starch;

[0037]S2. Then add bio-based low-density polyethylene, bio-based high-density polyethylene, and ethylene ethyl acrylate to the reactor and mix...

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PUM

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Abstract

The invention belongs to the field of plastic preparation, and in particular relates to a bio-based polyethylene / starch blend modified blown film material and a preparation method thereof. The bio-based polyethylene / starch blended modified blown film material includes the following components in parts by weight: 25-45 parts of bio-based low-density polyethylene, 5-25 parts of bio-based high-density polyethylene, ethylene 4-20 parts of ethyl acrylate, 1-8 parts of compatibilizer, 30-65 parts of starch, 3-19.5 parts of plasticizer, 1-8 parts of dispersant, and 1-8 parts of accelerator. The blown film material provided by the invention has the advantages of high bio-based content, low melt index, good processing performance and strong mechanical performance, and is beneficial to popularization and utilization in the industry.

Description

technical field [0001] The invention belongs to the field of plastic preparation, and in particular relates to a bio-based polyethylene / starch blend modified blown film material and a preparation method thereof. Background technique [0002] Due to the impact of environmental pollution and resource shortage, biodegradable polymer materials have become a research hotspot. As a green, renewable and biodegradable substance, starch is widely used in the preparation of biodegradable polymer materials. Native starch granules are composed of double helical structures of amylose and amylopectin, which have crystalline regions and non-crystalline regions. Natural starch does not have thermoplastic processing properties due to the existence of crystalline regions in the granules, and generally it will be modified. It can destroy the crystallization area in it, so that it can meet the requirements of processing performance. This kind of starch has thermoplasticity, which is called the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L3/02C08L23/06C08L23/08C08L51/06C08L91/00C08L23/30C08L71/02C08K5/11C08K5/098C08K5/47C08K5/40C08J5/18
CPCC08J5/18C08J2303/02C08J2423/06C08J2423/08C08J2423/30C08J2451/06C08J2471/02C08J2491/00C08K5/098C08K5/11C08K5/40C08K5/47
Inventor 李积迁陈晓江郭健杨宏李建平
Owner SHENZHEN HONGCAI NEW MATERIAL TECH