Organic compound and application of organic compound in organic electronic device
A technology of organic compounds and atoms, applied in the field of electroluminescent devices, in the field of organic compounds, can solve the problems of device performance and lifespan to be improved, and achieve the effect of improving electroluminescence efficiency and device life, close stacking, and effective transmission Effect
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Synthetic example 1
[0107] Synthesis Example 1: Synthesis of Compound 1
[0108]
[0109] Materials 1-1 (6.56g, 20mmol), 1-2 (5.3g, 20mmol), Pd(dba) 2 (0.345g, 0.6mmol), sodium tert-butoxide (5.76g, 60mmol) and tri-tert-butylphosphine (mass ratio 10%, 3.5ml) were placed in a 1000ml two-necked flask, anhydrous toluene 100mL was added under nitrogen protection, and 90 Celsius, and stir overnight. Cooled to room temperature, washed with water, dried, and purified by column chromatography to obtain compound 1 (7.8 g, 70%).
Synthetic example 2
[0110] Synthesis Example 2: Synthesis of Compound 2
[0111]
[0112] The raw material 2-1 (6.56g, 20mmol), 2-2 (6.8g, 20mmol), Pd (dba) 2 (0.345g, 0.6mmol), sodium tert-butoxide (5.76g, 60mmol) and tri-tert-butylphosphine (mass ratio 10%, 3.5ml) were placed in a 1000ml two-necked flask, anhydrous toluene 100mL was added under nitrogen protection, and 90 Celsius, and stir overnight. Cooled to room temperature, washed with water, dried, and purified by column chromatography to obtain compound 2 (8.9 g, 70%).
Synthetic example 3
[0113] Synthesis Example 3: Synthesis of Compound 3
[0114]
[0115] The raw material 3-1 (6.56g, 20mmol), 3-2 (7.76g, 20mmol), Pd(dba) 2 (0.345g, 0.6mmol), sodium tert-butoxide (5.76g, 60mmol) and tri-tert-butylphosphine (mass ratio 10%, 3.5ml) were placed in a 1000ml two-necked flask, anhydrous toluene 100mL was added under nitrogen protection, and 90 Celsius, and stir overnight. Cooled to room temperature, washed with water, dried, and purified by column chromatography to obtain compound 3 (8.9 g, 70%).
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