Semi-conductive PC black master batch and preparation method thereof

A black masterbatch and semi-conductive technology, which is applied in the field of semi-conductive PC black masterbatch and its preparation, can solve the problems of non-permanent semi-conductivity, poor electrostatic adsorption effect, and reduced impact strength, and achieve good permanent semi-conductive performance, Good antistatic effect, simple production process

Inactive Publication Date: 2020-10-30
余姚市和众塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the PC black masterbatches on the market are mainly general-purpose PE carrier black masterbatches and PC carrier black masterbatches. The former is poorly compatible with PC materials, and its impact strength drops rapidly, resulting in brittle products.
The latter has good compatibility with PC materials and can keep the physical properties of PC materials to a greater extent. Chinese invention patent (CN104761858B) discloses a solid-color PC masterbatch with a toughening effect. Although the masterbatch It has good impact resistance, but the products produced by it have poor electrostatic adsorption effect and do not have permanent semi-conductive function

Method used

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  • Semi-conductive PC black master batch and preparation method thereof
  • Semi-conductive PC black master batch and preparation method thereof
  • Semi-conductive PC black master batch and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Weigh the following raw material components by mass percentage PC50%, acrylic rubber copolymer 8%, conductive carbon black 20%, solvent red 4%, solvent yellow 3%, solvent blue 2%, ethylene-vinyl acetate copolymer EVA wax 1.5%, polyethylene wax 8.5%, calcium stearate 1%, barium stearate 1%, antioxidant 1076 0.5%, antioxidant 168 1.0%, pentaerythritol distearyl diphosphite 0.5%, spare;

[0027] Put each raw material component into a high-speed mixer with a speed of 1200r / min for mixing, and release the material when the temperature of the mixer is 140°C;

[0028] The mixed material is transferred to a twin-screw extruder for extrusion and water-cooled granulation;

[0029] Mix the color masterbatch obtained from granulation, and dry it at 100°C to obtain the finished color masterbatch.

Embodiment 2

[0031] Weigh the following raw material components by mass percentage: 30% PC, 10% core-shell acrylate, 30% conductive carbon black, 7% solvent red, 5% solvent yellow, 3% solvent blue, ethylene-vinyl acetate copolymer EVA wax 5%, ethylene bisstearamide 5%, calcium stearate 1%, barium stearate 0.5%, pentaerythritol distearyl diphosphite 3.5%, spare;

[0032] Put each raw material component into a high-speed mixer with a speed of 900r / min for mixing, and release the material when the temperature of the mixer is 120°C;

[0033] The mixed material is transferred to a twin-screw extruder for extrusion and water-cooled granulation;

[0034] Mix the color masterbatch obtained from granulation, and dry it at 80°C to obtain the finished color masterbatch.

Embodiment 3

[0036] Weigh the following raw material components by mass percentage PC60%, acrylic rubber copolymer 2%, core-shell acrylate 3%, conductive carbon black 15%, solvent red 5.5%, solvent yellow 3%, solvent blue 1.5%, Polyethylene wax 5%, silicone oil 4.5%, calcium stearate 0.15%, barium stearate 0.15%, antioxidant 1076 0.2%, spare;

[0037] Put each raw material component into a high-speed mixer with a speed of 1500r / min for mixing, and release the material when the temperature of the mixer is 160°C;

[0038] The mixed material is transferred to a twin-screw extruder for extrusion and water-cooled granulation;

[0039] Mix the color masterbatch obtained from granulation, and dry it at 120°C to obtain the finished color masterbatch.

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Abstract

The invention belongs to the technical field of high polymer materials, and particularly relates to a semi-conductive PC black master batch and a preparation method thereof. The semiconductive PC black master batch is prepared from the following raw materials in percentage by weight: 30-60% of PC, 5-10% of an impact modifier, 15-30% of conductive carbon black, 5-15% of a colorant, 1-10% of a dispersant, and 0.5-5% of a processing aid. The PC color master batch which is high in blackness, good in toughness, capable of eliminating static electricity and permanently semi-conductive and capable ofkeeping physical properties of a PC material to the maximum extent is finally prepared by compounding a dispersing agent, adding a processing aid, a color master carrier, an impact modifier, conductive carbon black and a coloring agent and processing by a specific processing method.

Description

technical field [0001] The invention relates to the technical field of semiconductive polymer materials, in particular to a semiconductive PC black masterbatch and a preparation method thereof. Background technique [0002] At present, the PC black masterbatches on the market are mainly general-purpose PE carrier black masterbatches and PC carrier black masterbatches. The former is poorly compatible with PC materials, and its impact strength drops rapidly, resulting in brittle products. The latter has good compatibility with PC materials and can keep the physical properties of PC materials to a greater extent. Chinese invention patent (CN104761858B) discloses a solid-color PC masterbatch with a toughening effect. Although the masterbatch It has good impact resistance, but the products produced by it have poor electrostatic adsorption effect and do not have permanent semi-conductive function. In order to expand the application range of masterbatches and meet the various need...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C08L69/00C08L33/00C08L23/08C08L23/06C08L83/04C08K13/02C08K3/04C08K5/098C08K5/134C08K5/526C08K5/524C08K5/20C08K5/103C08J3/22
CPCC08J3/226C08J2369/00C08J2469/00C08J2433/00C08J2423/08C08J2423/06C08J2483/04C08K13/02C08K3/04C08K5/098C08K5/1345C08K5/526C08K5/524C08K5/20C08K5/103C08K2201/001C08K2201/014
Inventor钟升楼旭虎
Owner余姚市和众塑料有限公司