Carbon-coated ternary positive electrode material and preparation method thereof
A cathode material and carbon coating technology, which is applied in the field of preparation of carbon-coated ternary cathode materials, can solve the problems of affecting the electrochemical performance of lithium ion batteries and the high deposition temperature, achieve excellent electrochemical performance, improve surface chemistry, improve The effect of poor conductivity
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Embodiment 1
[0027] The present invention provides a carbon-coated ternary positive electrode material, including a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, wherein 0
[0028] The present invention also provides a method for preparing a carbon-coated ternary positive electrode material, the specific steps are as follows:
[0029] S1: ultrasonically disperse the submicron ternary positive electrode material in deionized water, the ultrasonic frequency is 30-40kHz, and the time is 1-2h, adding citric acid as a carbon source to obtain a precursor solution, the citric acid and the submicron ternary The mass ratio of the positive electrode material is 0.09:1;
[0030] S2: Oxidize the ternary cathode material solution in an oxidizing atmosphere and stir to obtain a ternary cathode material wrapped in carbon dioxide after washing;
[0031] S3: In a vacuum environment, filter and dry the carbon oxide-wrapped t...
Embodiment 2
[0043] The present invention provides a carbon-coated ternary positive electrode material, including a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, wherein 0
[0044] The present invention also provides a method for preparing a carbon-coated ternary positive electrode material, the specific steps are as follows:
[0045]S1: ultrasonically disperse the submicron ternary positive electrode material in deionized water, the ultrasonic frequency is 30-40kHz, and the time is 1-2h, adding citric acid as a carbon source to obtain a precursor solution, the citric acid and the submicron ternary The mass ratio of the positive electrode material is 0.1:1;
[0046] S2: Oxidize the ternary cathode material solution in an oxidizing atmosphere and stir to obtain a ternary cathode material wrapped in carbon dioxide after washing;
[0047] S3: In a vacuum environment, filter and dry the carbon oxide-wrapped ter...
Embodiment 3
[0059] The present invention provides a carbon-coated ternary positive electrode material, including a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, wherein 0
[0060] The present invention also provides a method for preparing a carbon-coated ternary positive electrode material, the specific steps are as follows:
[0061] S1: ultrasonically disperse the submicron ternary positive electrode material in deionized water, the ultrasonic frequency is 30-40kHz, and the time is 1-2h, adding citric acid as a carbon source to obtain a precursor solution, the citric acid and the submicron ternary The mass ratio of the positive electrode material is 0.11:1;
[0062] S2: Oxidize the ternary cathode material solution in an oxidizing atmosphere and stir to obtain a ternary cathode material wrapped in carbon dioxide after washing;
[0063] S3: In a vacuum environment, filter and dry the carbon oxide-wrapped t...
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