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Carbon-coated ternary positive electrode material and preparation method thereof

A cathode material and carbon coating technology, which is applied in the field of preparation of carbon-coated ternary cathode materials, can solve the problems of affecting the electrochemical performance of lithium ion batteries and the high deposition temperature, achieve excellent electrochemical performance, improve surface chemistry, improve The effect of poor conductivity

Inactive Publication Date: 2021-02-09
SHANDONG FENGYUAN CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the preparation process of chemical vapor deposition, the deposition temperature is usually high, and the excessively high deposition temperature will cause redox reaction of the carbon-coated ternary positive electrode material, and then generate impurity phases, which will eventually affect the electrochemical performance of lithium-ion batteries.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The present invention provides a carbon-coated ternary positive electrode material, including a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, wherein 0

[0028] The present invention also provides a method for preparing a carbon-coated ternary positive electrode material, the specific steps are as follows:

[0029] S1: ultrasonically disperse the submicron ternary positive electrode material in deionized water, the ultrasonic frequency is 30-40kHz, and the time is 1-2h, adding citric acid as a carbon source to obtain a precursor solution, the citric acid and the submicron ternary The mass ratio of the positive electrode material is 0.09:1;

[0030] S2: Oxidize the ternary cathode material solution in an oxidizing atmosphere and stir to obtain a ternary cathode material wrapped in carbon dioxide after washing;

[0031] S3: In a vacuum environment, filter and dry the carbon oxide-wrapped t...

Embodiment 2

[0043] The present invention provides a carbon-coated ternary positive electrode material, including a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, wherein 0

[0044] The present invention also provides a method for preparing a carbon-coated ternary positive electrode material, the specific steps are as follows:

[0045]S1: ultrasonically disperse the submicron ternary positive electrode material in deionized water, the ultrasonic frequency is 30-40kHz, and the time is 1-2h, adding citric acid as a carbon source to obtain a precursor solution, the citric acid and the submicron ternary The mass ratio of the positive electrode material is 0.1:1;

[0046] S2: Oxidize the ternary cathode material solution in an oxidizing atmosphere and stir to obtain a ternary cathode material wrapped in carbon dioxide after washing;

[0047] S3: In a vacuum environment, filter and dry the carbon oxide-wrapped ter...

Embodiment 3

[0059] The present invention provides a carbon-coated ternary positive electrode material, including a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, wherein 0

[0060] The present invention also provides a method for preparing a carbon-coated ternary positive electrode material, the specific steps are as follows:

[0061] S1: ultrasonically disperse the submicron ternary positive electrode material in deionized water, the ultrasonic frequency is 30-40kHz, and the time is 1-2h, adding citric acid as a carbon source to obtain a precursor solution, the citric acid and the submicron ternary The mass ratio of the positive electrode material is 0.11:1;

[0062] S2: Oxidize the ternary cathode material solution in an oxidizing atmosphere and stir to obtain a ternary cathode material wrapped in carbon dioxide after washing;

[0063] S3: In a vacuum environment, filter and dry the carbon oxide-wrapped t...

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PUM

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Abstract

The invention discloses a carbon-coated ternary positive electrode material which comprises a ternary positive electrode material, the ternary positive electrode material is LinNi1-x-yCoxMnyO2, x is more than 0 and less than 0.5, y is more than 0 and less than 0.5, and n is more than 0.9 and less than 1.5; the invention also provides a preparation method of the carbon-coated ternary positive electrode material, the method can improve the electronic conductivity of the carbon-coated layer, and the material shows excellent electrochemical performance when being used as the positive electrode material of the lithium ion battery; the carbon material has the advantages of excellent electrical conductivity, ultrahigh chemical and electrochemical stability, unique physical properties, low cost and the like, the problem of poor electrical conductivity of the carbon-coated lithium ion positive electrode material can be improved by adopting the carbon-coated lithium ion positive electrode material, the electrical conductivity of the carbon material can be effectively improved, and the electrical conductivity of the carbon-coated ternary positive electrode material is further improved; and furthermore, the electrochemical performance of the positive electrode material is improved.

Description

technical field [0001] The invention belongs to the technical field of carbon-coated ternary cathode materials, and more specifically relates to a carbon-coated ternary cathode material and a method for preparing the carbon-coated ternary cathode material. Background technique [0002] At present, as a green new energy product, lithium-ion batteries have very important and broad application prospects. The positive electrode material determines the energy density, service life and safety performance of lithium-ion batteries. Therefore, cathode materials play an important role in lithium-ion batteries. Moreover, the electrochemical performance of the positive electrode material can be effectively improved by coating the carbon layer on the surface of the positive electrode material, and finally the performance of the lithium ion battery can be improved. [0003] Existing chemical vapor deposition method is used to prepare carbon-coated ternary cathode materials. However, in...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/505H01M4/525H01M4/62H01M10/0525C01B32/05C01G53/00
CPCC01G53/44C01B32/05H01M4/366H01M4/505H01M4/525H01M4/625H01M4/628H01M10/0525H01M2004/021H01M2004/028Y02E60/10
Inventor 赵光辉
Owner SHANDONG FENGYUAN CHEM CO LTD
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