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A kind of treatment method of steel mill dry desulfurization ash

A dry desulfurization ash and treatment method technology, which is applied in the field of solid waste treatment, can solve the problems of high moisture content of products and low oxidation efficiency of calcium sulfite, and achieve the effects of improving oxidation efficiency and shortening drying time

Active Publication Date: 2022-03-04
XUZHOU ZHONGLIAN CONCRETE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the embodiments of the present invention is to provide a treatment method for dry desulfurization ash in steel mills, aiming to solve the problems that the oxidation efficiency of calcium sulfite is not high and the moisture content of the product is high in the existing dry desulfurization ash treatment method question

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  • A kind of treatment method of steel mill dry desulfurization ash
  • A kind of treatment method of steel mill dry desulfurization ash
  • A kind of treatment method of steel mill dry desulfurization ash

Examples

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Effect test

Embodiment 1

[0028] Mix dry desulfurization ash from steel mills (dry desulfurization ash from steel mills comes from sintering machines in iron and steel enterprises) and washed stone chips with a particle size of about 4mm at a mixing mass ratio of 5:1, and stir evenly;

[0029] Inject SPM waste acid into the mixture of dry desulfurization ash and water-washed stone chips (SPM waste acid comes from the semiconductor cleaning process, the main components are sulfuric acid and hydrogen peroxide), keep stirring at a stirring speed of 100rpm, and add to the above mixture Introduce oxygen-containing gas, wherein the mixing mass ratio of SPM waste acid and dry desulfurization ash is controlled to be 1:3;

[0030] After reacting for 30 minutes, screen the modified dry desulfurization ash material, separate the remaining water-washed stone chips, and put the semi-dry state modified dry desulfurization ash material into the drying equipment, and dry it at 60°C for 1.5h After the dried product is ...

Embodiment 2

[0033] Mix dry desulfurization ash from steel mills (dry desulfurization ash from steel mills comes from sintering machines in iron and steel enterprises) and washed stone chips with a particle size of about 3mm at a mixing mass ratio of 6:1, and stir evenly;

[0034] Inject SPM waste acid into the mixture of dry desulfurization ash and water-washed stone chips (SPM waste acid comes from the semiconductor cleaning process, the main components are sulfuric acid and hydrogen peroxide), keep stirring at a stirring speed of 80rpm, and add to the above mixture Introduce oxygen-containing gas, wherein the mixing mass ratio of SPM waste acid and dry desulfurization ash is controlled to be 1:2;

[0035]After reacting for 20 minutes, screen the modified dry-process desulfurization ash material, separate the remaining water-washed stone chips, and put the semi-dry state modified dry-process desulfurization ash material into the drying equipment, and dry it at 60°C for 2 hours. After the...

Embodiment 3

[0038] Mix dry desulfurization ash from steel mills (dry desulfurization ash from steel mills comes from sintering machines in iron and steel enterprises) and washed stone chips with a particle size of about 5mm at a mixing mass ratio of 4:1, and stir evenly;

[0039] Inject SPM waste acid into the mixture of dry desulfurization ash and water-washed stone chips (SPM waste acid comes from the semiconductor cleaning process, the main components are sulfuric acid and hydrogen peroxide), keep stirring at a stirring speed of 120rpm, and add to the above mixture Introduce oxygen-containing gas, wherein the mixing mass ratio of SPM waste acid and dry desulfurization ash is controlled to be 1:4;

[0040] After reacting for 40 minutes, sieve the modified dry desulfurization ash material, separate the remaining water-washed stone chips, put the semi-dry state modified dry desulfurization ash material into the drying equipment, and dry it at 60°C for 1 hour. After the dried product is co...

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Abstract

The present invention is applicable to the technical field of solid waste treatment, and provides a treatment method for dry desulfurization ash of steel mills. The method includes: injecting SPM waste acid into dry desulfurization ash of steel mills, and continuing to stir until the reaction is completed to obtain Modified dry desulfurization ash material in a semi-dry state, wherein the mixing mass ratio of the SPM waste acid to the steel mill dry desulfurization ash is 1:2-4. In the steel mill dry desulfurization ash treatment method provided by the embodiment of the invention, by injecting SPM waste acid into the steel mill dry desulfurization ash, the hydrogen peroxide therein will generate peroxymonosulfuric acid (Caro's acid) in a sulfuric acid environment, which can Quickly oxidize calcium sulfite to calcium sulfate; at the same time, by controlling the mixing mass ratio of SPM waste acid and steel plant dry desulfurization ash to 1:2~4, the amount of waste acid is reduced, so that the final product can still be half The dry state effectively improves the oxidation efficiency of calcium sulfite and reduces the moisture content of the product.

Description

technical field [0001] The invention belongs to the technical field of solid waste treatment, and in particular relates to a treatment method for dry desulfurization ash in steel mills. Background technique [0002] In recent years, dry desulfurization process has become the mainstream desulfurization method in iron and steel enterprises. The main component of desulfurization ash produced by limestone dry desulfurization is calcium sulfite, and calcium sulfite will affect the gelation of desulfurization ash as a gypsum-based cementitious material. Performance, as well as affecting the setting time of desulfurization ash as a cement settling agent, etc., limit the comprehensive utilization of desulfurization ash. [0003] The existing dry desulfurization ash treatment method is mainly to add sulfuric acid whose mass is 1 to 3 times that of the dry desulfurization ash to the desulfurization ash to convert calcium sulfite into calcium sulfate. However, the oxidizing property o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B11/26C04B22/14C04B7/12
CPCC04B11/264C04B22/145C04B7/12
Inventor 陈琴朱丽丽祖庆贺缪志勇陈庭臧军
Owner XUZHOU ZHONGLIAN CONCRETE CO LTD