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A device and method for air flotation to strengthen multi-stage fiber coalescence and oil removal

A coalescence and fiber technology, which is applied in the field of air flotation enhanced multi-stage fiber coalescence and oil removal methods and devices, can solve the problems of high operating pressure drop, low separation efficiency, and poor demulsification effect, so as to reduce the pressure drop of the device, Uniform distribution and improved coalescence efficiency

Active Publication Date: 2022-03-15
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a new type of demulsification layer, coalescing layer and drainage layer using an aeration device to solve the problems of poor demulsification effect, high operating pressure drop and low separation efficiency in the existing oil-water separation method and device. The method and device for separating oil and water in a three-stage fiber bed in a liquid layer enable the device to achieve deep demulsification of oily sewage, improve coalescence efficiency, and reduce the overall pressure drop of the device at low operating costs

Method used

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  • A device and method for air flotation to strengthen multi-stage fiber coalescence and oil removal
  • A device and method for air flotation to strengthen multi-stage fiber coalescence and oil removal
  • A device and method for air flotation to strengthen multi-stage fiber coalescence and oil removal

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] In this example, the emulsion to be separated comes from a laboratory-made emulsion. In the experiment, a peristaltic pump and a metering pump were used to transport diesel oil and tap water to the emulsification tank in proportion, and the emulsification tank was continuously stirred at a speed of 900 rpm for 45 minutes to obtain an emulsion with uniform droplet size distribution.

[0056] The particle size distribution of emulsified droplets was measured by optical microscope and Image-Pro Plus software. The measurement results show that the average diameter of the oil droplets at the inlet of the coalescer is 10.8 μm, and more than 85% of the oil droplets have a diameter in the range of 3.0 to 15.0 μm. In the experiment, the oil concentration at the inlet of the coalescer was kept at 600mg / L, and the oil concentration in the water was measured with an infrared spectrometer according to the national environmental protection standard HJ 637-2012.

[0057] In the exper...

Embodiment 2

[0059] In this example, the emulsion to be separated comes from a laboratory-made emulsion, and the particle size and concentration detection methods are the same as those in Example 1. Isooctane and tap water are sent in parallel to a static mixer through a peristaltic pump and a metering pump to prepare an O / W emulsion. After the oil-water two-phase passes through the mixer, the oil phase forms an average particle size of about 10 μm (> 85%) in water. of emulsion.

[0060] In the experiment, the oil concentration at the inlet of the coalescer was kept at 300mg / L, and the gas flow rate in the first aeration zone was 5*10 -4 L / s, the diameter of the control bubble is 20μm; the gas flow rate of the second aeration zone is 1*10 -5 L / s, the diameter of the control bubble is 10μm; the oily sewage flows through the rectification plate, demulsification layer, coalescing layer and drainage layer in sequence at a superficial velocity of 0.01m / s; 0.8; ε in the coalescing layer 1 is ...

Embodiment 3

[0062] In this embodiment, the liquid to be separated is taken from the oily sewage in the 908# sewage pool of a domestic organic silicon production enterprise. Since the sample is taken from the settling tank after the sedimentation treatment, the maximum concentration of petroleum in the sewage is no more than 600 mg / L. However, its concentration fluctuates greatly, and its dispersed particle size is very small, which belongs to a highly emulsified state. Table 1 shows the basic characteristics of this organic wastewater.

[0063] Table 1 Basic characteristics of organic silicon process wastewater

[0064]

[0065] When the oil concentration at the inlet of the coalescer is 236mg / L, the gas flow rate in the first aeration zone is 5*10 -4 L / s, the diameter of the control bubble is 20μm; the gas flow rate of the second aeration zone is 1*10-5 L / s, the diameter of the control bubble is 10μm; the oily sewage flows through the rectification plate, demulsification layer, coales...

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Abstract

Provided are an air flotation-enhanced multi-stage fiber coalescence degreasing method and device. The method includes: passing the oily sewage rectified by the rectifying plate through the oleophobic fiber demulsification layer to realize the physical demulsification of the emulsion; the demulsified fluid enters the lipophilic fiber coalescing layer, so that tiny oil droplets are deposited in the coalescing layer Wetting and coalescence; the oil phase from the coalescence layer moves upwards driven by buoyancy and air bubbles, and at the same time, driven by the air bubbles, small oil droplets further coalesce and grow up, and are discharged through the outlet of the first oil phase, and the other oil phases Enter the drainage layer; relying on the capillary repulsion of the oleophobic fiber drainage layer, the front end of the drainage layer can capture the oil phase droplets, and at the same time, the coalescing oil droplets are easier to move to the upper end of the drainage layer under the action of buoyancy and air bubbles. The oil phase distribution of the liquid drainage layer is improved, and the oil phase is promoted to flow out through the second oil phase discharge port. The method and device of the invention can realize deep demulsification, coalescence and separation of oily sewage, and realize efficient and clean treatment of oily sewage.

Description

technical field [0001] The invention belongs to the technical field of heterogeneous phase separation. The invention specifically relates to an air flotation-enhanced multi-stage fiber coalescence degreasing method and device. A three-stage fiber bed realizes efficient demulsification and coalescence separation of the emulsified oil phase in oily sewage. Background technique [0002] In recent years, with the increasingly prominent problems of water resource shortage and water environment destruction in my country and the vigorous development of the petrochemical industry, water pollution control, reduction of water waste, and efficient treatment of oily sewage are one of the important tasks of environmental protection in my country. Slick oil (above 100μm in particle size) and dispersed oil (20-100μm in particle size) can be effectively separated by simple mechanical means such as standing because of their large particle size. Emulsified oil (particle size 0.1-20 μm) is di...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/24C02F1/40
CPCC02F1/24C02F1/40
Inventor 白志山吕福炜鲁朝金
Owner EAST CHINA UNIV OF SCI & TECH