Underwater adhesion anti-swelling hydrogel and flexible strain sensor

An anti-swelling and hydrogel technology, applied in the direction of electric/magnetic solid deformation measurement, electromagnetic measurement devices, etc., can solve the problems of poor conformal effect, decreased mechanical properties, and non-adhesion

Active Publication Date: 2022-06-03
NANJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a one-step gel method with low cost and good underwater adhesion for the disadvantages of hydrogel strain sensors, such as non-adhesion, poor conformal effect, water absorption swelling, and decreased mechanical properties, which are ubiquitous in the underwater environment. , anti-swelling hydrogel, and based on the hydrogel to make a flexible strain sensor, the flexible strain sensor has the advantages of wide application range, good durability, high sensitivity, excellent repeatability, etc., which can effectively expand the scope of flexible wearable devices practical application of

Method used

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  • Underwater adhesion anti-swelling hydrogel and flexible strain sensor
  • Underwater adhesion anti-swelling hydrogel and flexible strain sensor
  • Underwater adhesion anti-swelling hydrogel and flexible strain sensor

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Embodiment 1

[0047] Step (1), adding 0.934g of sodium chloride, 1.0224g of octadecyl acrylate and 9g of sodium dodecyl sulfate to 20mL of deionized water, and fully stirred at 50°C until clear, to obtain Precursor A;

[0048] Step (2), dissolve 0.081g ferric chloride hexahydrate in 0.5mL deionized water to prepare a ferric chloride solution, and add the ferric chloride solution dropwise to 1.046g dimethylaminoethyl methacrylate, 0.257g Precursor B was obtained by ultrasonic dispersion in a mixed solution of 2-hydroxyethyl acrylate and 0.003 g of methylenebisacrylamide;

[0049]Step (3), remove the bubbles in the precursor A by vacuum, take 1 mL of the precursor A (containing 0.05112g of octadecyl acrylate), mix it with the precursor B obtained in step (2), and then add ammonium persulfate solution ( Prepared by dissolving 0.05g ammonium persulfate in 0.5mL deionized water), disperse uniformly under ultrasonic (ultrasonic power 100W) for 90s at room temperature, and let stand for 1 minute t...

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Abstract

The underwater adhesion anti-swelling hydrogel is prepared by the following steps: stirring alkyl acrylate, a surfactant and sodium chloride in water until the mixture is clear to obtain a precursor A, dropwise adding a ferric trichloride solution into a mixed solution of dimethylaminoethyl methacrylate, 2-hydroxyethyl acrylate and a chemical cross-linking agent, and stirring to obtain a precursor B; and mixing the precursor A and the precursor B, which are subjected to bubble removal, under the action of an initiator, and adopting a one-step gel method to obtain the hydrogel capable of being adhered underwater and resisting swelling. According to the preparation method disclosed by the invention, a molecular bridge relation is established between the gel and a target interface underwater through cooperation of electrostatic interaction, metal coordination and hydrophobic association, adhesion is realized, and the surface water repellency of the gel is improved by introducing a hydrophobic group, so that the underwater stability of the gel is improved. The invention further discloses an underwater adhesion anti-swelling hydrogel flexible strain sensor, and the underwater adhesion anti-swelling hydrogel flexible strain sensor is a flexible strain sensor formed by installing the underwater adhesion anti-swelling hydrogel on the electrodes.

Description

technical field [0001] The invention relates to a preparation method of an underwater adhering and anti-swelling hydrogel, a flexible strain sensor prepared based on the underwater adhering and anti-swelling hydrogel, and the The application in the detection of tensile strain and external force frequency, specifically in the preparation of underwater real-time health monitoring equipment, underwater flexible robots, electronic skin, tensile strain detection equipment and many other applications. Background technique [0002] In recent years, flexible electronic devices have emerged in the fields of information, energy, medical care, and national defense due to their unique ductility, high-efficiency, and low-cost manufacturing processes. In order to better fit the skin and improve comfort during use, inspired by human skin, electronic skins that simulate various functions of the skin have developed rapidly in recent years. Hydrogel is a three-dimensional network structure g...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C08F220/34C08F220/18C08F220/20C08F222/38C08J3/075C08L33/14G01B7/16
CPCC08J3/075C08F220/34G01B7/18C08J2333/14C08F220/1818C08F220/20C08F222/385
Inventor董晓臣王倩王嗣颖邵进军
OwnerNANJING UNIV OF TECH