Method for extracting scandium from red mud

A technology for red mud and scandium oxide is applied in the field of red mud extraction, which can solve the problems of polluting the environment, poisoning water quality, and red mud flowing into rivers and lakes.

Inactive Publication Date: 2006-10-11
汪友华
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Such a large amount of red mud has not been effectively and fully utilized, which has brought quite complicated social and economic problems: the construction of red mud storage yards occupies a large area of ​​land, which increases infrastructure investment; red mud contains alkali and a small amount of radioactive substances, and long-term storage After being dried, the dust will fly, seriously polluting the atmosphere and the environment; the wind and rain will cause the red mud to flow into rivers and lakes, poisoning the water quality, causing many social ecological environmental problems and economic benefit problems, and becoming an important source of environmental pollution

Method used

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  • Method for extracting scandium from red mud

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Effect test

Embodiment

[0045] Take 5 tons of red mud (dry material), and extract scandium according to the following steps:

[0046] 1. Leaching of scandium

[0047] Add 300L of hydrochloric acid with an acidity of 24% into the acid-resistant reaction tank, then add 50kg of red mud, heat to 70°C, react for 1 hour and filter to obtain 260L of scandium-containing leachate with a scandium content of 14.3mg / L, and the leaching rate is 90.7% .

[0048] 2. Extraction of Scandium

[0049] Prepare the extraction agent (organic phase) by P204, 2-octanol, and aviation kerosene in proportions of 8%, 4%, and 88%, and react with the scandium-containing leaching solution of step 1 in the extraction box to transfer scandium to the extraction agent; Press H 2 o 2 :H 2 SO 4 :H 2 O=1:3.5:20 to prepare acid washing, react with scandium-containing organic phase in the extraction box to remove impurities; then use NaOH with a concentration of 2.5mol / L as stripping solution to extract the scandium contained in the...

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Abstract

The invention relate to a method of extracting scandium from red mud, the method utilize the red mud that come from the process of producing aluminum oxide from alumyte, in accordance with specific characteristics of red mud, applying hydrochloric acid leach, P204 abstraction, acid-washing edulcoration, sodium-hydroxide back extraction, ammonia modifier hydrolytic decomposition zirconium and titanate in hydrochloric acid solution, oxalic acid precipitating scandium and medium temperature calcining technique, the purity of final production Sc2O3 is 99.9%. Extracting scandium from red mud change refuse into available material, save mineral resources, benefiting environmental conservation. The invention also fills up the study vacant of isolation technique in high-strength zirconium titanate and scandium.

Description

technical field [0001] The invention belongs to rare earth metal hydrometallurgy technology, in particular to a method for extracting scandium from red mud. Background technique [0002] Scandium is a very active scattered metal element. It is very similar to the lanthanide element in its electronic layer structure and chemical properties, so it is usually listed as a rare earth element. The excellent properties of scandium make it widely used in electric light source, aerospace, electronics industry, nuclear technology, superconducting technology and other important fields. [0003] Scandium exists widely in nature, and there are more than 800 kinds of scandium-containing minerals, but the independent mineral resources of scandium are few and small-scale, and cannot become an industrial source of scandium. Therefore, the industrial acquisition of scandium is achieved through the recovery of the associated element scandium during the comprehensive treatment of non-ferrous m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/00C22B3/10C22B3/26C22B59/00
CPCY02P10/20
Inventor 汪友华
Owner 汪友华
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