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An improved lens of diethyle glycol bis allyl carbonate CR-39 and a process for preparation thereof

A technology of CR-39 and toluene diisocyanate is applied in the field of improved lenses of diethylene glycol bisallyl carbonate CR-39 and its preparation, and can solve the problems of time-consuming and the like

Inactive Publication Date: 2008-05-14
SHRIRAM INST FOR INDAL RES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] As this method of making lenses, it is known in the art that CR-39 resin is polymerized for a period of 17-20 hours in the presence of diisopropyl peroxide (DIPP), which is time-consuming

Method used

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Examples

Experimental program
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Effect test

Embodiment

[0035] For lens preparation, 7 gm polythiol was mixed with 0.04 gm DBTDL and degassed for 1 hour at a temperature of 60° C. and a pressure of 2 mm Hg. It was cooled at room temperature, ie 30°C, and 3 gm of CR-39 was added, and a degassing step was performed at a temperature of 30°C and a pressure of 2 mm Hg for 10 minutes. 8 gm of TDI was added thereto, and further degassed at a temperature of 25° C. and a pressure of 2 mm Hg for 10 minutes.

[0036] The mixture thus obtained is injected into a glass blank fitted with a rubber gasket. The blank filled with this mixture was placed in a hot air oven at 50°C for 12 hours. It was then removed for curing in the same oven for 3 hours.

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PUM

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Abstract

An improved lens comprising CR-39 and polytoiol in the ratio of 30-50% of CR-39, 70-50% of polythiol and total weight of TDI and CR-39 is 25-50% by weight of the total material and wherein CR-39, Polythiol and TDI is present preferably in the ratio of 31-32%, 31-32% and 36-38% respectively wherein the Refractive Index of the lens is in the order of 1.59-1.65.

Description

technical field [0001] The present invention relates to an improved lens of diethylene glycol bisallyl carbonate CR-39 and its preparation method. Background technique [0002] Plastic lenses are classified based on their index of refraction, and the index of refraction determines the light intensity of the lens. Therefore, if a lens with a low refractive index is used for higher light intensities, the lens needs to have a substandard thickness, which increases the wearer's discomfort due to the weight of this lens. In this case, the preferred touse is a lens with a high refractive index. [0003] Lenses with a high refractive index of 1.6 and above have generally been produced hitherto from polythiols. The process involves first preparing a diol from mercaptoth, ethanol and epichlorohydrin in the presence of triethylamine as a catalyst. The ratio of catalyst to active ingredient is 1:1, and the reaction is carried out at a temperature above 40°C. [0004] The diol is th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B1/04
CPCC08G18/3855C08G18/7621G02B1/041C08G18/246
Inventor R·K·坎达尔G·塞沙德里G·杰哈
Owner SHRIRAM INST FOR INDAL RES
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