Single-component reaction type hot melt adhesives and steel plate composite material using the same

A technology of hot-melt adhesives and composite materials, which is applied in the field of steel plate composite materials to achieve the effects of excellent boiling water resistance, long coating life and excellent impact resistance

Inactive Publication Date: 2011-05-25
NANTONG GAOMENG NEW MATERIAL
View PDF0 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Therefore, there is currently no adhesive that is suitable for bonding polyester film or polyvinyl chloride film to steel plates, and polyester film and polyvinyl chloride film do not stick when winding, and have excellent performances such as boiling water resistance and impact resistance. and steel plate composites made from it

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Single-component reaction type hot melt adhesives and steel plate composite material using the same
  • Single-component reaction type hot melt adhesives and steel plate composite material using the same
  • Single-component reaction type hot melt adhesives and steel plate composite material using the same

Examples

Experimental program
Comparison scheme
Effect test

Synthetic example 1

[0022] Synthesis Example 1 Synthesis Example of Polyester Resin

[0023] In a reaction kettle equipped with a stirrer, a thermometer, and a distillation condenser, add dibasic acid and dibasic alcohol according to the ratio of raw materials listed in Table 1, and carry out esterification reaction at 160°C to 230°C for 3 hours. Then, the pressure was reduced to 5 mmHg at 260° C. for 30 minutes, followed by polycondensation under high vacuum greater than 0.3 mmHg for 45 minutes to form an intermediate product. Then, return to normal pressure by introducing nitrogen gas. When the temperature of the reaction system drops to 210°C, add trimellitic anhydride and react for another 30 minutes. When the temperature of the reaction system drops to 110°C, add A-LinkTM35 according to the ratio in the table and react for 30 minutes. , to obtain polyester resins (A-1) to (A-5). The mass parts of their composition raw material consumption and the number average molecular weight of the polye...

Synthetic example 2

[0028] Synthesis Example 2 Synthesis Comparative Example of Polyester Resin

[0029] In a reaction kettle equipped with a stirrer, a thermometer, and a distillation condenser, add dibasic acid and dibasic alcohol according to the ratio of raw materials listed in Table 2, and carry out esterification reaction at 160° C. to 230° C. for 3 hours. Thereafter, the pressure was reduced to 5 mmHg at 260° C. over 30 minutes, followed by polycondensation under a high vacuum of 0.3 mmHg or less for 45 minutes to form an intermediate product. Then, nitrogen was introduced to return to normal pressure. When the temperature of the reaction system dropped to 210°C, trimellitic anhydride was added and reacted for another 30 minutes. When the temperature of the reaction system dropped to 110°C, A-LinkTM35 was added in proportion and reacted for 30 minutes to prepare Polyester resins (B-1) to (B-4) were obtained. The mass parts of their raw material consumption and the number average molecular...

Embodiment 1

[0034] Dissolve 100 parts of polyester resin (A-1) in 35 parts of ethyl acetate, 5 parts of butyl acetate, 25 parts of methyl ethyl ketone, 15 parts of toluene, 10 parts of isopropanol, 5 parts of ethylene glycol monomethyl In the mixed solvent of ether and 5 parts of ethylene glycol monobutyl ether, epoxy resin, curing agent and chloroacetic acid resin were added according to the quantities listed in Table 3. After fully mixing, they were coated on 25 μm polyester film, polychloride On the corona-treated surface of the vinyl film, the film thickness after drying was about 3 μm. Dry with hot air at 100°C for 2 minutes to remove the solvent, laminate the adhesive surfaces of the polyester film and the polyvinyl chloride film with the steel plates heated at 170°C in advance, and press them with a hot roller at 200°C to obtain polyvinyl chloride films respectively. Ester film, PVC composite steel plate. The obtained composite steel plate material was subjected to various perform...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
epoxy equivalentaaaaaaaaaa
epoxy equivalentaaaaaaaaaa
Login to view more

Abstract

The invention discloses a monocomponent reaction type hot-melt adhesive and steel composite material using the hot-melt adhesive, belonging to the steel composite material technical field, in order to satisfy the requirement of adhesive which is suitable for bonding with polyvinyl chloride film, polyester film and steet plate and not accretionary on rolling and steel composite material using the hot-melt adhesive. The hot-melt adhesive comprises 100 mass portion of polyester resin, 2-12 mass portion of epoxy resin, 0.08-0.8 mass portion of curing agent and 5-25 mass portion of chloroacetic acid. The steel composite material has excellent impact resistance and boiling water resistance. The adhesive can firmly be bonded with the polyvinyl chloride film, polyester film and steet plate, and the polyester film and polyvinyl chloride film coated with the adhesive are not accretionary and the coating life is long.

Description

technical field [0001] The present invention relates to an adhesive for a steel plate composite material and a steel plate composite material, more specifically, the present invention relates to a one-component reactive adhesive for a steel plate composite material and a steel plate composite material using the same. Background technique [0002] Decorative steel plate composite materials for home appliances, building materials, utensils, etc. are made by laminating plastic film (one of polyester film and polyvinyl chloride film) and steel plate with adhesive. In the past, polyvinyl chloride film was mostly used in the past. In recent years, there has been a trend of using polyester film to gradually replace polyvinyl chloride film to produce steel plate composite materials. [0003] The production of steel plate composite materials usually pre-coats the adhesive on the plastic film, winds it up, and finally heat-compresses it with the steel plate. Therefore, it is required...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09J167/03B32B7/12B32B15/09B32B15/085C09J163/00C09J127/14
Inventor 冯祎沈峰
Owner NANTONG GAOMENG NEW MATERIAL
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap