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61results about How to "Excellent boiling water resistance" patented technology

Method for synthesizing unsaturated polyester resin for artificial marble

ActiveCN102212173ACuring at room temperature with gentle exothermCuring shrinkage is smallWater dischargeAlcohol
The invention provides a method for synthesizing unsaturated polyester resin for artificial marble, which mainly comprises the following steps of: (A) putting unsaturated dibasic acid, unsaturated dibasic acid anhydride, dicyclopentadiene and partial dihydric alcohol in a reaction kettle, heating and performing reflux reaction under the protection of nitrogen, and then heating and performing reflux reaction until a certain acid value is reached; (B) changing the state of the system to a distillation state, adding the residual dihydric alcohol to perform polycondensation reaction, and evacuating to discharge water forcibly when the water discharge quantity reaches 85% to 90% of a theoretical quantity, so that the reaction continues to be below the certain acid value; and (C) lowering the temperature and adding a polymerization inhibitor, diluting with styrene, and cooling and filtering to obtain the finished unsaturated polyester resin. The method provided by the invention is steady and controllable in the reaction process, fast in polycondensation reaction and small in quantity of generated waste water, and the obtained product has the characteristics of steady and slow curing and heat release at normal temperature, small rate of curing shrinkage, excellent boiling water resistance and the like, and can meet the quality demand of the artificial marble.
Owner:ZHAOQING FUTIAN CHEM IND

Self-crosslinking water-borne wood paint emulsion and synthetic method thereof

The invention provides a self-crosslinking water-borne wood paint emulsion and a synthetic method thereof, relating to the technical field of coatings. The self-crosslinking water-borne wood paint emulsion contains the following raw materials in percentage by weight: 25%-60% of an acrylic emulsion, 2%-6% of isophorone diisocyanate, 2%-7% of glyceryl triacetate, 10%-45% of acrylic monomers, 20%-50%of a waterborne polyurethane resin emulsion, 0.2%-2% of an emulsifying agent, 3%-6% of nano-crystalline cellulose, 0.2%-1.5% of a defoaming agent and the balance of deionized water. By taking the self-crosslinking acrylic emulsion as a main raw material and utilizing the self-crosslinking acrylic monomers, isophorone diisocyanate, the waterborne polyurethane resin emulsion, glyceryl triacetate and nano-crystalline cellulose and other raw materials, the prepared self-crosslinking water-borne wood paint emulsion has relatively high crosslinking density, the hardness, boiling water resistance, solvent resistance, light remaining property, color remaining property and impact resistance of a coating film are relatively excellent, and the content of volatile organic compounds is low, so that the environmental pollution is avoided, and the human healthy is guaranteed.
Owner:GUANGDONG VALSPAR CHEM IND

Ultraviolet cured organic/inorganic hybrid super-hydrophilic coating and method for preparing same

The invention discloses an ultraviolet cured organic/inorganic hybrid super-hydrophilic coating and a method for preparing the same. The method includes carrying out sulfhydryl-alkene reaction on mercaptan compounds and acrylic ester compounds under the catalytic effects of amine catalysts to prepare hydrophilic oligomers; uniformly mixing the hydrophilic oligomers, mesoporous silicon dioxide, cross-linking agents and photoinitiators in methanol with one another to obtain solution; spraying the uniformly mixed solution on the surfaces of base materials and forming the organic/inorganic hybrid super-hydrophilic coating on the surfaces of the base materials by means of ultraviolet curing. Two ends of each mercaptan compound carry sulfhydryl, each of two ends of each acrylic ester compound carry C=C double bonds, and each of two ends of each hydrophilic oligomer carry C=C double bonds. The ultraviolet cured organic/inorganic hybrid super-hydrophilic coating and the method have the advantages that the method includes simple processes, water contact angles of the organic/inorganic hybrid super-hydrophilic coating prepared by the aid of the method can be reduced and are smaller than 5 degrees in 0.24 s, and the ultraviolet cured organic/inorganic hybrid super-hydrophilic coating is excellent in acid resistance, boiling water resistance and mechanical property.
Owner:SOUTH CHINA UNIV OF TECH

Preparation of urea-melamine-formaldehyde resin adhesive for E0 floor

InactiveCN101481593AReduce the content of ether linkagesReduce releaseAldehyde/ketone condensation polymer adhesivesUreaUrea melamine formaldehyde
The invention discloses a method for preparing a urea-melamine-formaldehyde resin adhesive for an E0-level floor. In the first step, formaldehyde solution, melamine and urea are mixed, the pH value of the mixture is regulated, the temperature is raised to 80-95 DEG C, and the reaction lasts 40-60 minutes, wherein, the mol ratio between formaldehyde and the total amount of the urea and the melamine is 2.05-2.12 : 1; in the second step, the pH value is regulated to be 5.0-6.0, and the reaction is underway till the turbidity point; in the third step, the pH value is regulated to be 6.0-6.9, the urea and the melamine are added, and the mol ratio between the formaldehyde and the total amount of the urea and the melamine which are added in the first step and the second step is 1.48-1.74 : 1, and the reaction lasts 30-70 min at a temperature of 90 DEG C; in the fourth step, the pH value is regulated to be 7.5-9.0, the melamine is added, and the reaction lasts 20-80 min at a temperature of 80-90 DEG C; and in the fifth step, the urea is added, the mol ratio between the formaldehyde and the total amount of all the urea and all the melamine is 1.02-1.30 : 1, and the material is cooled and discharged after the reaction is finished. A veneer formed by pressing the resin adhesive has good boiled-water resistance and low formaldehyde release, and the reaction is gentle and also easy to control.
Owner:INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY

Preparation method of furan-modified cashew phenolic resin

ActiveCN103289035AImprove boiling water resistanceExcellent resistance to boiling waterHeat transfer tubeSeawater
The invention provides a preparation method of furan-modified cashew phenolic resin. The preparation method comprises the following steps of: selecting the following raw materials in parts by weight: 100-140 parts of cardanol, 32-54 parts of formaldehyde, 10-23 parts of furfuryl alcohol, 80-120 parts of dimethyl benzene and 8-10 parts of catalyst; adding the cardanol, the formaldehyde and the catalyst into a reaction kettle in proportion, reacting for 1 hour to 2 hours at 70 DEG C-80 DEG C; adding the furfuryl alcohol, and reacting for 1 hour to 2 hours at 90 DEG C-100 DEG C; adding the 80-120 parts of dimethyl benzene, heating up, separating the water by adopting an oil-water separating device until the temperature reaches 155 DEG C-160 DEG C, and performing heat preservation for 1 hour to 2 hours to obtain the furan-modified cashew phenolic resin. The preparation method of the furan-modified cashew phenolic resin has the beneficial effects of remarkably improving boiling water resistance and heat resistance of the resin, having a practical application meaning in corrosion resistance and scaling prevention of a distillation-process seawater desalting heat transfer tube as well as steam blowing resistance of a heat exchanger tube bundle of a petrifaction system, and being applicable to paint base preparation of industrial heavy-duty anticorrosive coating.
Owner:天津市中海科技有限公司

Fireproof door middle seam provided with flame-retardant straw fire prevention boards

The invention discloses a fireproof door middle seam provided with flame-retardant straw fire prevention boards. The fireproof door middle seam comprises a door frame, door leaves and hinges, wherein the door leaves are connected with the door frame by the hinges; a face exposed to fire and a face unexposed to fire are respectively formed at the two sides of each door leaf; a middle seam is formed by the contact surfaces of the left door leaf and the right door leaf; the left door leaf and the right door leaf are respectively formed by two parts, wherein the four flame-retardant straw fire prevention boards are arranged in the parts at the sides close to the middle seam, and the other parts connected with the flame-retardant straw fire prevention boards are made from steel section; a seam cover plate is also arranged in the fireproof door middle seam and is formed by cutting the flame-retardant straw fire prevention board. The fireproof door middle seam creatively overcomes the defect that a middle seam of the traditional steel or wooden fireproof door is easily deformed in the event of high temperature of a fire; the flame-retardant straw fire prevention boards are set as the parts, close to the middle seam, of the door leaves and the seam cover plate, so that the effects of fire prevention, flame retardance and smoke suppression are effectively achieved; the fireproof door middle seam guarantees the stability of a framework structure of the fireproof door when the fireproof door is in a fire; the middle seam is non-deformable and fireproof.
Owner:石植

Waterproof polyamide-based adhesive and preparation method thereof

The invention discloses a waterproof polyamide-based adhesive and a preparation method thereof, and relates to an adhesive and a preparation method thereof. The invention aims to solve the technical problems of high cost and non-ideal water resistance of the formaldehyde-free adhesive for an artificial board. A method for preparing a dispersing agent comprises the following steps: stirring and heating adipic acid or an adipic acid/organic binary anhydride mixture and a polyamine compound, adding water, adding epoxy chloropropane, heating, and reacting to obtain the dispersing agent. The adhesive is prepared by uniformly stirring a polyamide-based aqueous cross-linking dispersant, water, polymethylene polyphenyl polyisocyanate (PMDI) and an inorganic filler at room temperature in parts by weight. According to the polyamide-based water-based polymer composite adhesive, the PMDI dosage can be reduced by 33%, the adhesive cost is reduced, the working life is long, and formaldehyde and an organic solvent are not used in the preparation process. The product can effectively solve the problem of high cost of the existing formaldehyde-free soybean adhesive for artificial boards, and has theadvantages of excellent boiling water resistance and environment friendliness. The invention belongs to the technical field of adhesives.
Owner:NORTHEAST FORESTRY UNIVERSITY

A kind of manufacturing process of environmental protection flame retardant straw board

ActiveCN107127841BNo emissionsOvercome the defect of high formaldehyde contentWood treatment detailsLaminationManufacturing technologyCarbonization
The invention discloses a manufacturing technology of an environment-friendly anti-flaming straw board. The manufacturing technology comprises the following steps that (1) crop straws are impurity-removed and smashed; (2) measurement and sub-package are conducted; (3) pavement and mould-entering are conducted; (4) pre-pressing formation is conducted; (5) sizing and cold-pressing are conducted; (6) mould-locking is conducted; (7) maintenance and mould-releasing are conducted; (8) drying is conducted; (9) final trimming of a semi-finished product is conducted; (10) sanding is conducted; and (11) packaging and storehouse-entering are conducted. The manufacturing technology adopts a normal-temperature cold-pressing technology, the method is simple, high-temperature heating is not needed, and gluing can be completed in a normal-temperature state; a slab is dried only in a drying step by adopting a microwave technology, solid fuel is not consumed, no chimney exists in a factory, and the whole process is green and environmentally friendly; and in addition, the straws are principal raw materials matched with an inorganic flame retardant and an inorganic binder which have excellent performances, the obtained straw board cannot be carbonized and deformed in the anti-flaming process at a high temperature of above 1200 DEG C, no harmful smoke and gas is generated, the straw board does not conduct heat at a high temperature and does not swell when encountering water, and the comprehensive performance is quite excellent.
Owner:石植

Wool felt-resistant two-component water-based paint and preparation method thereof

The invention provides a wool felt-resistant two-component water-based paint and a preparation method thereof. The raw materials comprise component A: acrylic resin I, acrylic resin II, polyurethane resin, a base material wetting agent, an antifoaming agent, a dispersing agent, a delustering agent, a coalescing agent, a leveling agent, a wear-resistant additive, deionized water, water-based resin-free color paste and a thickener; and component B: aliphatic isocyanate. The preparation method comprises the following steps: uniformly dispersing the acrylic resin I, the acrylic resin II and the polyurethane resin, adding the base material wetting agent, the defoamer, the dispersant, the coalescing agent and the deionized water, uniformly dispersing, adding the delustering agent, dispersing until the fineness is qualified, adding the leveling agent, the deionized water, the wear-resistant aid, the thickener and the color paste, and uniformly dispersing; and discharging to obtain the component A, and uniformly mixing the component A with the component B aliphatic isocyanate to obtain the wool felt-resistant double-component water-based paint. The preparation method is simple, and the coating has excellent wear resistance, chemical resistance and the like.
Owner:卡秀万辉(无锡)高新材料有限公司
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