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High strength starch-based degrading and environment-protecting material and preparation method

An environmentally friendly material and starch-based technology, applied in the field of rapidly degradable raw materials, can solve problems such as product quality not meeting requirements, environmental and health damage, and environmental white pollution, so as to improve product quality, control degradation cycle, and reduce production costs. Effect

Inactive Publication Date: 2008-11-26
季国良
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, disposable foamed plastic tableware is widely used. Although it brings convenience to people's life, it also causes serious white pollution to the environment. After burning, it can produce carcinogens such as dioxins. Foam tableware will produce toxins at a temperature of 60°C, which shows how much damage it does to people's living environment and health.
Although some starch-based degradable materials that have emerged in recent years have solved the problem of white pollution caused by foamed plastics, due to poor mechanical strength and poor plasticity, these degradable materials require two sets of mixing devices in production, and it is not easy to keep warm during the production process. , complex process lines, high production costs, and product quality that does not meet the requirements, so it cannot be widely used

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A high-strength starch-based degradable environmental protection material, its composition includes: starch, polyvinyl alcohol, plant pond, plasticizer, degradation control agent, polycaprolactone and polyhydroxybutyrate copolymer, hexabutyl hexabutyl Sugar, the parts by weight of the starch are 51-80, the parts by weight of the polyvinyl alcohol are 12-20, the parts by weight of the plant sugar are 2-10.5, the parts by weight of the plasticizer The parts by weight of the degradation control agent are 2.5-8, the parts by weight of the degradation control agent are 0.2-1, the parts by weight of the polycaprolactone and polyhydroxybutyrate copolymer are 5-9, the parts by weight of the The parts by weight of the hexabutyl-hexetan are 0.2-0.5.

Embodiment 2

[0025] A high-strength starch-based degradable environmental protection material, its preparation process is: take 51kg of natural polymer starch, 12kg of polyvinyl alcohol, 2kg of plant sugar, 2.5kg of plasticizer, 0.2kg of degradation control agent, 5kg of Copolymer of polycaprolactone and polyhydroxybutyrate, 0.2kg of hexabutyl hexetan, the raw materials are subjected to polymerization reaction, blending and copolymerization modification, the equipment used is an oil heating high mixing and cold mixing machine, the temperature Add natural polymer starch and polyvinyl alcohol polyvinyl alcohol at 70°C and mix at high speed, then add polycaprolactone and polyhydroxybutyrate copolymer at 80°C and mix at high speed, continue heating to 100°C for 2 times Add plant sugar (xylose, maltose or starch sugar), plasticizer (salad oil), degradation control agent and hexabutyl chitosan, and carry out polymerization reaction, blending and copolymerization modification, the temperature is 1...

Embodiment 3

[0027] A high-strength starch-based degradable environmental protection material, its preparation process is: take 60kg of natural polymer starch, 18kg of polyvinyl alcohol, 8kg of plant sugar, 6kg of plasticizer, 0.8kg of degradation control agent, 8kg of polyvinyl alcohol Caprolactone and polyhydroxybutyrate copolymer, 0.4kg of hexabutyl hexetan, the raw materials are subjected to polymerization reaction blending copolymerization modification, the equipment used is an oil heating high mixing and cold mixing machine, the temperature is at Add natural polymer starch and polyvinyl alcohol polyvinyl alcohol at 80°C, and mix at high speed, then add polycaprolactone and polyhydroxybutyrate copolymer at 100°C, and mix at high speed, continue heating to 110°C and mix three times Plant sugar (xylose, maltose or starch sugar), plasticizer (salad oil), degradation control agent and hexabutyl chitosan are added, and the polymerization reaction is carried out for blending and copolymeriza...

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PUM

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Abstract

The invention provides a high-intensity starch-based degradation environmental protection material and a manufacturing method thereof, which relates to a rapid degradation raw material used for manufacturing disposable tableware and disposable wrappage and the manufacturing method thereof. The present disposable foaming plastic tableware has the disadvantages of hard heat insulation, complicated process line, high production cost, undesirable production quality and white pollution. The components of the product include macromolecular natural starch, polyvinyl alcohol, plant sugar, polyvinyl alcohol, a degradation control agent, a multipolymer of polycaprolactone and poly-beta-hydroxybutyrate and hexa-butyl ester hexa-butyl glycan; wherein, the starch is 51-80 weight portions, the polyvinyl alcohol is 12-20 weight portions, the plant sugar is 2-10.5 weight portions, plasticizer is 2.5-8 weight portions, the degradation control agent is 0.2-1 weight portions, the multipolymer of polycaprolactone and poly-beta-hydroxybutyrate is 5-9 weight portions and the hexa-butyl ester hexa-butyl glycan is 0.2-0.5 weight portions. The high-intensity starch-based degradation environmental protection material of the invention is used for manufacturing the disposable tableware and the disposable warppage.

Description

Technical field: [0001] The invention relates to a rapidly degradable raw material for manufacturing disposable tableware and disposable packaging and a manufacturing method thereof. Background technique: [0002] At present, disposable foamed plastic tableware is widely used. Although it brings convenience to people's life, it also causes serious white pollution to the environment. If it is degraded, it can also produce carcinogens such as dioxins after burning. Foam tableware will produce toxins at a temperature of 60°C, which shows how much damage it does to people's living environment and health. Although some starch-based degradable materials that have emerged in recent years have solved the problem of white pollution caused by foamed plastics, due to poor mechanical strength and poor plasticity, these degradable materials require two sets of mixing devices in production, and it is not easy to keep warm during the production process. , complex process lines, high produ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L3/02B29C47/40C08L29/04C08L67/00C08L91/00
Inventor 季国良马跃东陈鲁安双宝
Owner 季国良
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