Method for disrupting reproductive performance of arthropods
An arthropod, capable technology, applied in the fields of botanical equipment and methods, animal repellents, chemicals for biological control, etc., can solve problems such as pheromone instability, complex formulations and release methods, etc.
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Embodiment approach 1
[0022] Embodiment 1. The method described in the Summary of the Invention wherein the carboxamide arthropodicide is selected from the group consisting of anthranilamides of Formula 1, N-oxides and salts thereof,
[0023]
[0024] in
[0025] X is N, CF, CCl, CBr or CI;
[0026] R 1 is CH 3 , Cl, Br or F;
[0027] R 2 is H, F, Cl, Br or CN;
[0028] R 3 is F, Cl, Br, C 1 -C 4 Haloalkyl or C 1 -C 4 Haloalkoxy;
[0029] R 4a is H, C 1 -C 4 Alkyl, cyclopropylmethyl or 1-cyclopropylethyl;
[0030] R 4b is H or CH 3 ;
[0031] R 5 is H, F, Cl or Br; and
[0032] R 6 is H, F, Cl or Br.
[0033] Embodiment 1A. The method of Embodiment 1, wherein X is N; R 1 is CH 3 ; 2 is Cl or CN; R 3 is Cl, Br or CF 3 ; 4a is C 1 -C 4 Alkyl; R 4b is H; R 5 is Cl; and R 6 It is H.
[0034] Embodiment 1B. The method of embodiment 1, wherein X is N; R 1 is CH 3 ; 2 is Cl or CN; R 3 is Cl, Br or CF 3 ;4a is Me or CH(CH 3 ) 2 ; 4b is H; R 5 is Cl; and R 6 It ...
Embodiment approach 1C
[0035] Embodiment 1C. The method of Embodiment 1 wherein the carboxamide arthropodicide is selected from the group consisting of:
[0036] N-[4-chloro-2-methyl-6-[[(1-methylethyl)amino]carbonyl]phenyl]-1-(3-chloro-2-pyridyl)-3-(trifluoro Methyl)-1H-pyrazole-5-carboxamide,
[0037] N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridyl)-3-(trifluoromethyl)-1H- pyrazole-5-carboxamide,
[0038] 3-Bromo-N-[4-chloro-2-methyl-6-[[(1-methylethyl)amino]carbonyl]phenyl]-1-(3-chloro-2-pyridyl)-1H -pyrazole-5-carboxamide,
[0039] 3-Bromo-N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridyl)-1H-pyrazole-5- carboxamide,
[0040] 3-Bromo-1-(3-chloro-2-pyridyl)-N-[4-cyano-2-methyl-6-[(methylamino)carbonyl]phenyl]-1H-pyrazole-5 -carboxamide,
[0041] 1-(3-Chloro-2-pyridyl)-N-[4-cyano-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-(trifluoromethyl)-1H -pyrazole-5-carboxamide,
[0042] 3-Bromo-1-(2-chlorophenyl)-N-[4-cyano-2-methyl-6-[[(1-methy...
Embodiment approach 2
[0049] Embodiment 2. The method described in the Summary of the Invention wherein the carboxamide arthropodicide is selected from the group consisting of phthalamides and salts thereof of Formula 2,
[0050]
[0051] in,
[0052] R 11 is CH 3 , Cl, Br or I;
[0053] R 12 is CH 3 or Cl;
[0054] R 13 is C 1 -C 3 Fluoroalkyl;
[0055] R 14 is H or CH 3 ;
[0056] R 15 is H or CH 3 ;
[0057] R 16 is C 1 -C 2 alkyl; and
[0058] n is 0, 1 or 2.
[0059] Embodiment 2B. The method of embodiment 2, wherein R 11 is Cl, Br or I; R 12 is CH 3 ; 13 is CF 3 、CF 2 CF 3 or CF(CF 3 ) 2 ; 14 is H or CH 3 ; 15 is H or CH 3 ; 16 is CH 3 ; and n is 0, 1 or 2.
[0060] Embodiment 2C. The method of Embodiment 2 wherein the carboxamide arthropodicide is N 2 -[1,1-Dimethyl-2-(methylsulfonyl)ethyl]-3-iodo-N 1 -[2-Methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-1,2-benzenedicarboxamide.
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