Multiple element composite metal oxidate arsenic removal settling agent and use method thereof

A composite metal and hydrated manganese oxide technology, which is applied in chemical instruments and methods, water/sludge/sewage treatment, water/sewage treatment, etc., can solve the problems of insufficient adsorption reaction time, high cost, and high hydraulic conditions. problems, to achieve good arsenic removal effect, easy to use and operate, and excellent arsenic removal performance

Active Publication Date: 2009-05-06
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] For the sedimentation and removal of arsenic in lakes, reservoirs, rivers and other water bodies, although the above-mentioned adsorption materials used to remove arsenic in drinking water have the ability to adsorb arsenic, they often have low equilibrium adsorption capacity, too fast sedimentation speed, and insufficient adsorption reaction time. , Lack of suitable mixing and other environmental hydraulic conditions, so it is difficult to have obvious arsenic removal effect
The iron-manganese composite oxide/diatomite arsenic-removing adsorption material developed by the applicant in the previous research has effectively improved the adsorption capacity of the material and the kinetic reaction speed of arsenic adsorption, but it is still difficult to effectively settle and remove arsenic in water due to its rapid s

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] Material preparation: Multi-element composite metal oxide sedimentation agent for arsenic removal was prepared by ex-situ method. Configuration is made up of ferric chloride, aluminum trichloride, ferrous sulfate solution A (concentration of ferric chloride, aluminum trichloride, ferrous sulfate is 2g / L); Configure permanganate solution as Mixed solution B (concentration of permanganate is 1g / L). Add mixed solution A to mixed solution B, and stir for 10 minutes.

[0058] Applied to the purification of water containing arsenic: the concentration of arsenic in arsenic-polluted water is 0.20mg / L. The multi-element composite metal oxide arsenic-removing sedimentation agent obtained after the mixed reaction is evenly sprayed on the surface of the water to be purified polluted by arsenic, and the dosage of the multi-element composite metal oxide arsenic-removal sedimentation agent is 10mg / L. The concentration of arsenic in the treated water meets the requirements for the co...

Embodiment 2

[0060] Material preparation: Multi-element composite metal oxide sedimentation agent for arsenic removal was prepared by ex-situ method. Configure mixed solution A consisting of aluminum trichloride and ferrous sulfate solution (the concentrations of aluminum trichloride and ferrous sulfate are both 2g / L); configure mixed solution B composed of ferric chloride and permanganate solution (Concentration of ferric chloride is 2g / L, concentration of permanganate is 1g / L). Add the mixed solution B into the mixed solution A, stir and mix for 120min.

[0061] Applied to the purification of arsenic-containing water: the concentration of arsenic in arsenic-polluted water is 0.20mg / L. The multi-element composite metal oxide arsenic-removing sedimentation agent obtained after the mixed reaction is evenly sprayed on the surface of the water to be purified polluted by arsenic, and the dosage of the multi-element composite metal oxide arsenic-removal sedimentation agent is 10mg / L. The conc...

Embodiment 3

[0063] Material preparation: Multi-element composite metal oxide sedimentation agent for arsenic removal was prepared by ex-situ method. Configure ferrous sulfate solution and use it as mixed solution A (concentration of ferrous sulfate is 2g / L); configure mixed solution B (trichloro The concentrations of aluminum chloride and ferric chloride are both 2g / L, and the concentration of permanganate is 1g / L). Add mixed solution A and mixed solution B into the container at the same time, stir and mix for 4h.

[0064] Applied to the purification of arsenic-containing water: the concentration of arsenic in arsenic-polluted water is 0.50mg / L. The multi-element composite metal oxide arsenic-removing sedimentation agent obtained after the mixed reaction is evenly sprayed on the surface of the water to be purified polluted by arsenic, and the dosage of the multi-element composite metal oxide arsenic-removal sedimentation agent is 200mg / L. The concentration of arsenic in the treated wate...

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PUM

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Abstract

The invention belongs to the material field for removing the arsenic in water by settlement, more particularly relates to polyelement composite metal oxide arsenic removal settlement agent and an application method thereof based on iron oxide, manganese oxide, and aluminum oxide. The invention uses an ectopic preparation method or situ preparation method for preparing and obtaining polyelement composite metal oxide arsenic removal settlement agent which comprises hydrated iron oxide, hydroxyl-hydrated ferric hydroxide, hydrated aluminum oxide, hydroxyl-hydrated alumina, hydrated manganese oxide and the like. The polyelement composite metal oxide arsenic removal settlement agent can be used for removing the arsenic pollutants in water bodies such as lakes, reservoirs, rivers, groundwater, drinking water, industrial waste water, and the like; in addition, the settlement agent can also be used for removing the heavy metals such as copper, chromium, cadmium, lead, and the like, and the pollutants such as iron, manganese, phosphates, and the like in water by settlement.

Description

technical field [0001] The invention belongs to the field of materials for sedimentation and removal of arsenic and other pollutants in water such as lakes and reservoirs, and particularly relates to a multi-component composite metal oxide sedimentation agent for removing arsenic based on iron oxide, manganese oxide and aluminum oxide and an application method. Background technique [0002] Arsenic is a highly toxic heavy metal element, and its presence in the environment will have a serious impact on the human body, aquatic animals and plants. In addition, if arsenic-containing water is used for agricultural irrigation, fishery, landscape and other functional needs, it may also enter the human body indirectly through the enrichment of the food chain and pose a threat to human health. In order to control the risk of arsenic exposure to the human body caused by drinking water, food, vegetables, fruits, aquatic animals (such as fish), etc., my country has strictly regulated th...

Claims

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Application Information

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IPC IPC(8): C02F1/58
Inventor 曲久辉王洪杰刘锐平刘会娟兰华春
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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