Method for preparing transparent hardening coat on surface of plastic plate

A technology for hardening coatings and plastic plates, applied in coatings and other directions, can solve the problems of excessive coating waste, unavoidable surface defects, and large energy consumption, and achieve simple methods, low equipment and technical requirements, and high transmittance. Effect

Inactive Publication Date: 2009-12-09
杭州博纳特光电科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hardened coatings are mainly divided into heat-cured silicone resins and UV-cured polyacrylate resins. The former will affect printing performance due to its low surface energy. Therefore, most of the above-mentioned application fields use UV-cured hardening methods. The method of coating pre-treats the surface of the plastic sheet, but the equipment investment is large, the paint is wasted, the energy consumption is large, and various surface defects of the product are difficult to avoid, and the relevant technical requirements are relatively high.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Polyurethane acrylate (6196 resin, produced by Changxing Chemical Industry) 10g, epoxy acrylate (621 resin, produced by Changxing Chemical Industry) 7g, organic-inorganic hybrid acrylate (601C resin, produced by Changxing Chemical Industry) 3g, bifunctional Acrylate monomer HDDA (1,6-ethylene glycol diacrylate) 5g, ethyl acetate 34g, butyl acetate 25g, ether 5g, isopropanol 5g, 184 photoinitiator 5.65g, modified polysiloxane Mix and stir 0.35 g of alkanes leveling agent (432, produced by Deqian Chemical Co., Ltd.) evenly, and prepare a solid content of 20%, a viscosity of 11 seconds, and a density of 0.89 g / cm 3 light-cured coatings;

[0023] (2) Clean the surface of the transparent PMMA sheet, eliminate the static electricity on the surface of the sheet, and blow off the pollutants;

[0024] (3) The light-curing coating is flow-coated on the PMMA plate, and the flow rate of the coating is 6L / min;

[0025] (4) Level the wet film on the plastic plate naturally for ...

Embodiment 2

[0029] (1) Polyurethane acrylate (6193 resin, produced by Changxing Chemical Industry) 15g, epoxy acrylate (621 resin, produced by Changxing Chemical Industry) 10g, organic-inorganic hybrid acrylate (601C resin, produced by Changxing Chemical Industry) 5g, ethyl acetate 30g of ester, 25g of butyl acetate, 5g of acetone, 5g of ether, 2g of 184 photoinitiator, 2.25g of 1173 photoinitiator, 0.75g of acrylic acid ester leveling agent (835, produced by Deqian Chemical Industry) were mixed and stirred evenly, and prepared into a solid The content is 30%, the viscosity is 13 seconds, and the density is 0.95g / cm 3 light-cured coatings;

[0030] (2) Clean the surface of the transparent PMMA sheet, eliminate the static electricity on the surface of the sheet, and blow off the pollutants;

[0031] (3) The light-curing coating is flow-coated on the PMMA plate, and the flow rate of the coating is 3L / min;

[0032] (4) Level the wet film on the plastic plate for 3 minutes, bake at 45°C for...

Embodiment 3

[0036] (1) Polyurethane acrylate (9013 resin, produced by Sartomer Company) 10g, epoxy acrylate (CN104 resin, produced by Sartomer Company) 6g, pure acrylate (6532 resin, produced by Changxing Chemical Industry) 5g, monofunctional Acrylate monomer (EM70, produced by Changxing Chemical Industry) 2g, trifunctional acrylate monomer (EM231, produced by Changxing Chemical Industry) 2g, multifunctional acrylate monomer (EM265, produced by Changxing Chemical Industry) 1g, ethyl acetate 35g, butyl acetate 33.5g of ester, 2.5g of 1173 photoinitiator, 1.5g of BP photoinitiator, 1g of TPO photoinitiator, 0.5g of acrylic acid ester leveling agent (835, produced by Deqian Chemical Co., Ltd.) were mixed and stirred evenly, and the solid content was prepared to be 26 %, viscosity is 12.5 seconds, density is 0.93g / cm 3 light-cured coatings;

[0037] (2) Clean the surface of the transparent PMMA sheet, eliminate the static electricity on the surface of the sheet, and blow off the pollutants; ...

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Abstract

The invention discloses a method for preparing a transparent hardening coat on the surface of a plastic plate, using curtaining film making and UV radiation curing method, the steps are as follows: using acrylate oligomers, acrylic acid ester monomer and organic solvent, photoinitiator and auxiliary agent to prepare photo-cured coating; cleaning the surface of the plastic sheet; curtaining the photo-cured coating on the surface of the plastic sheet; naturally levelling the wet film on the plastic plate, then roasting and cooling; and curing the wet film on the plastic plate by UV to form transparent hardening coat. The method of the invention is simple, uses the curtaining method to form film, has low requirements on equipment and technology, and can be easily achieved on various plastic base materials, therefore, the surface of the obtained coat is transparent and smooth, the penetration is high, and the hardness can be enhanced by 6-8 levels than original sheets. The obtained hardening coat has excellent performances of impressionability, engravable and processable properties, film coating property, and the like, thereby being benefit for better protecting plastic base materials, and being adapted to the new developments of electronic products, electrical appliances and digital products.

Description

technical field [0001] The invention relates to a method for preparing a hardened coating, in particular to a method for preparing a transparent hardened coating on the surface of a plastic plate. Background technique [0002] Transparent plastic materials, such as polycarbonate (PC), polymethyl methacrylate (PMMA), polyxylylene glycol ester (PET), polystyrene (PS) because of their excellent light transmission and processability , Toughness, has been widely used in various industries and fields, such as display screens, windows and touch screens of digital products (mobile phones, LCD monitors, digital cameras, MP3 / MP4, digital photo frames, game consoles), household, medical or industrial appliances, Instrument control panels and nameplates, display windows, cabinets, billboards, glasses lenses, reflectors, diffusers, light guide plates for optical instruments, etc. [0003] However, plastic materials have some major defects, namely low surface hardness, poor wear resistan...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/06C09D4/02
Inventor 高基伟闫欣刘光平阮一清宋利权赵斌通
Owner 杭州博纳特光电科技有限公司
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