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Fluidized bed reactor

An ebullating bed reactor and reactor technology, applied in the field of improved three-phase ebullating bed reactor, can solve the problems of high maintenance cost of circulating oil pump, low utilization rate of reactor space, sinking and accumulation of catalyst, etc., and shorten the residence time time, avoid a large amount of carrying out, and prevent the effects of condensation and coking reactions

Active Publication Date: 2012-02-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] US Re 25,770 describes a typical fluidized bed process, which adopts the operation mode of circulating oil pump, but this process method has the following shortcomings in practical application: less catalyst storage in the reactor, low space utilization of the reactor; circulating oil pump maintenance The maintenance cost is high, and once the circulating oil pump is malfunctioning or damaged, it will cause the catalyst to sink and accumulate, resulting in the forced shutdown of the device; It is easy to carry out secondary thermal cracking reaction coking and reduce product quality
The difference in flow rate increases with the diameter of the reactor, which may lead to coalescence of bubbles, formation of large bubbles, insufficient contact between gas and liquid phases, and poor fluidization

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment -1

[0035] According to the structure of the ebullating bed hydrogenation reactor of the present invention, the cold model test of the three-phase separator ebullating bed medium-sized reactor has been carried out. The height of the straight section of the shell = 3000mm, and the effective volume of the shell is 60L. The height of the three-phase separator = 500mm, the diameter of the minimum diameter of the inner cylinder of the separator = 135mm, the diameter of the tapered opening at the lower part of the inner cylinder = 190mm, the height of the lower cone of the inner cylinder = 35mm, the diameter of the smallest diameter of the outer cylinder = 160mm, The opening diameter of the lower section of the outer cylinder = 285mm, the height of the lower section of the outer cylinder = 30mm, the upper opening of the outer cylinder is higher than the upper opening of the inner cylinder, and the bottom position of the lower tapered opening of the outer cylinder is higher than the botto...

Embodiment -2

[0038] On the basis of the cold model test, a hydrodemetallization test of an island atmospheric residue was carried out on a 60L medium-sized unit. Wherein the size of the reactor is the same as in Example 1, and the test conditions and results are shown in Table 2.

Embodiment -3

[0046] The operating conditions are the same as in Example-1. A material distributor is provided in the middle of the straight section of the ebullated bed reactor. The material distributor is a circular secondary distribution plate with a certain opening ratio, and the area of ​​the distribution plate accounts for 0.6% of the cross-sectional area of ​​the reactor. , the opening ratio is 0.5, and the diameter is smaller than the diameter of the reactor, which promotes the distribution of the continuous phase and the dispersed phase, inhibits the formation and coalescence of large bubbles, improves the fluidization quality, and makes the radial velocity distribution of the fluid more uniform. Interference is carried out to improve the mass and heat transfer efficiency and strengthen the process. It can be seen that the mass transfer rate increases when there are internal components, and the fluidization quality is better improved.

[0047] Table 3 Comparison results with and wi...

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Abstract

The invention discloses a fluidized bed reactor which comprises a reactor shell and a three-phase separator, the three-phase separator is arranged at the upper part inside the reactor shell and is of a sleeve structure comprising an inner sleeve and an outer sleeve, the upper ends and lower ends of the inner sleeve and the outer sleeve are both of opening structures, the inner sleeve and the outer sleeve are respectively composed of an upper section and a lower section, the upper sections of the inner sleeve and the outer sleeve are in reverse frustum structures, and the lower sections of theinner sleeve and the outer sleeve are in frustum structures. By designing a novel three-phase separating structure, the invention can further improve separating effect, reduce catalyst carrying-out amount, and enhance the operation elasticity of the three-phase separator. The reactor is mainly applicable to chemical reactions between liquid and gas substances of different types and solid particles under contact condition, and has the advantages of large catalyst inventory, high reactor use ratio, simple structure, easy operation and the like.

Description

technical field [0001] The present invention relates to a gas-liquid-solid three-phase ebullating bed reactor, in particular to an improved three-phase ebullating bed reactor for chemical or physical reactions when liquid and gas substances flow upward and contact with solid particles . Background technique [0002] The heavy oil fluidized bed hydrogenation reactor belongs to the gas, liquid and solid three-phase fluidized bed reactor, which can process heavy and low-quality raw material oil with high metal and high asphaltene content, and has the advantages of small pressure drop, uniform temperature distribution, and can maintain the whole operation The catalyst activity in the periodic reactor is uniform, and fresh catalyst can be added and spent catalyst can be taken out during operation. [0003] US Re 25,770 describes a typical fluidized bed process, which adopts the operation mode of circulating oil pump, but this process method has the following shortcomings in prac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/22
Inventor 刘建锟杨涛贾丽胡长禄蒋立敬陈涛
Owner CHINA PETROLEUM & CHEM CORP
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